Abstract
Microwave dielectric ceramics in the Ca1-xSrxTiO3 (0 ≤ x ≤ 0.7) composition series were fabricated via conventional solid state, mixed oxides route. The structural, microstructural and microwave dielectric properties of the sintered samples were investigated. The XRD patterns revealed the formation of a single-phase perovskite-structured compositions calcined at 1000 °C for 3 h in air. The structure was observed to be transformed from noncentrosymmetric orthorhombic (Pnma) to centrosymmetric cubic (Pm3m) at 0.5 ≤ x. Microwave dielectric properties like relative permittivity (εr), quality factor (Qxf) and dielectric loss (tan δ) were measured at relatively lower frequency for millimeter (mm) wave wireless applications.
Similar content being viewed by others
References
Ali R, Yashima M (2005) Space group and crystal structure of the Perovskite CaTiO3 from 296 to 1720 K. J Solid State Chem 178:2867–2872
Bassoli M, Buscaglia MT, Bottino C, Buscaglia V, Molinari M, Maglia F, Parravicini G, Dapiaggi M (2008) Defect chemistry and dielectric properties of Yb3+:CaTiO3 perovskite. J Appl Phys 103:014104
Chen H, Tang B, Duan S, Yang H, Li Y, Li H, Zhang S (2015) Microstructure and microwave dielectric properties of Ba3.75Nd9.5Ti18−z (Mg1/3Nb2/3)z O54 ceramics. J Elec Mate 44:1081–1087
Cherdchom S, Rattanaphan T, Chanadee T (2019) calcium titanate from food waste: combustion synthesis, sintering, characterization, and properties. Adv Mate Sci Eng 1:1–9. https://doi.org/10.1155/2019/9639016
Drews AR, Wong-Ng W, Roth RS, Vanderah TA (1996) Preparation and crystal structure of Sr5TiNb4O17. Mater Res Bull 31:153–162
Fu D, Itoh M, Koshihara S (2010) Invariant lattice strain and polarization in BaTiO3–CaTiO3 ferroelectric alloys. J Phys Condens Matter 22:052204
Guevarra J, Schonleber A, Smaalen SV, Lichtenberg F (2007) Superspace description of the crystal structures of Can(Nb, Ti)nO3n+2 (n = 5 and 6) Act. Cryst B 63:183–189
Guo YY, Guo YJ, Liu JM (2012) Zn doping-induced enhanced dielectric response of quantum paraelectric SrTiO3. J Appl Phys 111:074108
Hao Z (2013) A review on the dielectric materials for high energy-storage application. J Adv Dielect 3:1330001
Howard CJ, Zhang Z (2003) Structures and phase transition in the layered perovskite La0.6Sr0.1TiO3: a new orthorhombic structure solved from high-resolution diffraction in combination with group theoretical analysis. J Phys Condens Matter 15:4543–4553
Hsu CH, Chang CH (2012) Microwave dielectric properties of new (Ca0.8Sr0.2)SnO3 ceramics. Ceram Inter 38:4411–4413
Iqbal Y, Manan A, Reaney IM (2011) Low loss Sr1−xCaxLa4Ti5O17 microwave dielectric ceramics. Mater Res Bull 46:1092–1096
Liao QW, Li LX, Zhang P, Ding X, Ren X, Zhang W (2011) A microwave dielectric material for microstrip patch antenna substrate. J Mater Res 26:2503–2510
Lin TN, Chu JP, Wang SF (2005) Structures and properties of Ba0.3Sr0.7TiO3: MgTiO3 ceramic composites. Mater Lett 59:2786–2789
Lu X, Li Q, Yang D (2005) Dielectric properties and sintering characteristics of CaTiO3-(Li1/2Nd1/2)TiO3 ceramics. J Electroceram 14:59–65
Moulson AJ, Herbert JM (1990) Electroceramics. Chapman and Hall, London, pp 300–308
Redfern SAT (1996) High-temperature structural phase transitions in perovskite (CaTiO3). J Phys Condens Matter 8:8267–8275
Richtmyer RD (1939) Dielectric resonators. J Appl Phys 10:391
Sebastian MT (2008) Dielectric Materials for Wireless communication, vol 1. Elsevier, Amsterdam, pp 10–50
Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Act Cryst A 32:751–767
Tang J, Yu X, Yang L, Zhou C, Peng X (2006) Preparation and Al3+ enhanced photoluminescence properties of CaTiO3:Pr3+. Mater Lett 60:326–329
Tohdo Y, Kakimoto K, Ohsato H, Yamada H, Okawa T (2006) Microwave dielectric properties and crystal structure of homologous compounds ALa4Ti4O15 (A = Ba, Sr and Ca) for base station applications. J Eur Ceram Soc 26:2039–2043
Yan K, Fuji M, Karaki T, Adachi M (2007) Microwave dielectric properties of Ca0.8Sr0.2TiO3–Li0.5Nd0.5TiO3 ceramics with near-Zero temperature coefficient of resonant frequency. Jpn J Appl Phys 46:7105–7107
Yoshida M, Hara N, Takada T, Seki A (1997) Structure and dielectric properties of (Ca1-xNd2x/3)TiO3. Jpn J Appl Phys 36:6818–6823
Zheng H, de Gyorgyfalva GDC, Reaney IM (2005) Microstructure and microwave properties of CaTiO3-LaGaO 3 solid solutions. J Mater Sci 40:5207–5214
Acknowledgments
The authors acknowledge the technical support provided by Materials Research Laboratory (MRL) and Centralized Research Laboratory (CRL), University of Peshawar, Pakistan.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zaman, A., Uddin, S. & Mehboob, N. Synthesis and Microwave Dielectric Characterization of Ca1-xSrxTiO3, Low-Loss Ceramics. Iran J Sci Technol Trans Sci 45, 367–371 (2021). https://doi.org/10.1007/s40995-020-00990-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40995-020-00990-5