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SPIN TRANSITION IN HETEROANION COMPLEXES IN THE Fe2+-4-AMINO-1,2,4-TRIAZOLE–\(\text{NO}^{-}_3\)–\(\text{SO}^{2-}_4\) SYSTEM

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Abstract

Magnetic and thermodynamic properties of heteroanion complex compounds in the Fe2+–ATrz–\(\text{NO}^{-}_3\)–\(\text{SO}_4^{2-}\) (ATrz = 4-amino-1,2,4-triazole) system are studied. The Fe(ATrz)3(NO3)2(1–x)(SO4)x·nH2O phases are synthesized. According to magnetochemical and calorimetry data, Fe(ATrz)3(NO3)2(1–x)(SO4)x samples demonstrate a spin transition above room temperature while the compound′s color is changed from pink in the low-spin state to white in the high-spin state. According to calorimetry data, the spin transition in Fe(ATrz)3(NO3)2(1–x)(SO4)x·nH2O phases is a first-order phase transition with hysteresis effects. It is shown that the temperature and the nature of the spin transition can be fine-tuned by synthesizing heteroanion complexes.

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Funding

The study was financially supported by the Russian Science Foundation (project No. 18-73-00277).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    K. A. Vinogradova, A. Yu. Andreeva, D. P. Pishchur & M. B. Bushuev

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  1. K. A. Vinogradova
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  2. A. Yu. Andreeva
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  3. D. P. Pishchur
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  4. M. B. Bushuev
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Correspondence to K. A. Vinogradova.

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Vinogradova, K.A., Andreeva, A.Y., Pishchur, D.P. et al. SPIN TRANSITION IN HETEROANION COMPLEXES IN THE Fe2+-4-AMINO-1,2,4-TRIAZOLE–\(\text{NO}^{-}_3\)–\(\text{SO}^{2-}_4\) SYSTEM. J Struct Chem 61, 1380–1389 (2020). https://doi.org/10.1134/S0022476620090048

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