Skip to main content
SpringerLink
Log in

ADDUCTS OF PLATINUM(IV) NITRATE COMPLEXES WITH 15-CROWN-5 ETHER

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

This article has been updated

Abstract

The possibility of isolating platinum(IV) nitrate complexes to the solid phase from a nitric acid solution of platinum in the form of adducts with dibenzo-18-crown-6, 15-crown-5, and 12-crown-4 ether is studied. It is found that when nitric acid solutions containing 15-crown-5 ether (15-C-5) are evaporated, a polycrystalline product consisting of mainly a mixture of phases with the compositions (H3O⊂15-C-5)2[Pt(NO3)6] (1), (H3O⊂15-C-5)2(15-C-5)[Pt(NO3)6]·2H2O (2), and (15-C-5)[Pt4(μ3-OH)2(μ2-OH)4(NO3)10]·3H2O (3) is formed. The structure of the mentioned compounds is established by single crystal X-ray diffraction. In the case of dibenzo-18-crown-6 ether, the interaction with a nitric acid solution of platinum results in the formation of a poorly soluble tetranitro derivative of macrocyclic ether. Evaporation of nitric acid solutions of platinum containing 12-crown-4 ether does not allow the preparation of a solid crystalline phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

Change history

  • 28 October 2020

    Added ESM information into HTML version of the Article.

REFERENCES

  1. G. Spezzati, A. Benavidez, A. DeLaRiva, J. McCabe, A. Datye, and E. Hensen. Appl. Catal., B, 2019, 243, 36–46.

  2. E. Derevyannikova, T. Kardash, A. Stadnichenko, O. Stonkus, E. Slavinskaya, V. Svetlichnyi, and A. Boronin. J. Phys. Chem. C, 2019, 123, 1320–1334.

  3. A. Zhou, J. Wang, H. Wang, H. Li, J. Wang, and M. Shen. J. Rare Earths, 2018, 36, 257–264.

  4. S. Gatla, D. Aubert, G. Agostini, O. Mathon, S. Pascarelli, T. Lunkenbein, M. Willinger, and H. Kaper. ACS Catal., 2016, 6, 6151–6155.

  5. M. Wickleder, F. Gerlach, S. Gagelmann, J. Bruns, M. Fenske, and K. Al-Shamery. Angew. Chem., Int. Ed., 2012, 51, 2199–2203.

  6. S. Khranenko, I. Baidina, and S. Gromilov. J. Struct. Chem., 2007, 48(6), 1152–1155.

  7. D. Vasilchenko, S. Berdugin, S. Tkachev, I. Baidina, G. Romanenko, O. Gerasko, and S. Korenev. Inorg. Chem., 2015, 54, 4644–4651.

  8. D. Vasilchenko, S. Tkachev, I. Baidina, and S. Korenev. Inorg. Chem., 2013, 52, 10532–10541.

  9. D. Dou, D. Liu, W Williamson, and K. Kharas, H.J. Robota. Appl. Catal., B, 2001, 30, 11–24.

  10. D. Vasilchenko, T. Asanova, B. Kolesov, A. Stadnichenko, E. Slavinskaya, E. Gerasimov, K. Lomachenko, A. Boronin, and S. Korenev. ChemCatChem, 2020, 12, 1413–1428.

  11. D. Vasilchenko, S. Tkachev, I. Baidina, G. Romanenko, and S. Korenev. J. Mol. Struct., 2017, 1130, 855–859.

  12. G. Sheldrick. Acta Crystallogr., Sect. A, 2008, 64,112–122.

  13. Bruker. SADABS. Bruker AXS Inc.: Madison, Wisconsin, USA, 2001.

  14. M. Belousoff, S. Langford, M. Latter, and V. Lau. Acta Crystallogr., Sect. E, 2005, 61, 3283–3284.

  15. N. Kazuo. Infrared and Raman Spectra of Inorganic and Coordination Compounds. Part B. Wiley: Hoboken, USA, 2009.

  16. D. Vasilchenko, P. Topchiyan, S. Berdyugin, E. Filatov, S. Tkachev, I. Baidina, V. Komarov, E. Slavinskaya, A. Stadnichenko, and E. Gerasimov. Inorg. Chem., 2019, 58, 6075–6087.

  17. D. Vasilchenko, P. Topchiyan, S.Tkachev, I. Baidina, I. Korolkov, E. Filatov and D. Sheven. J. Struct. Chem., 2019, 60(8), 1327–1334.

  18. M. Calleja, K. Johnson, W. Belcher, and J. Steed. Inorg. Chem., 2001, 40, 4978–4985.

Download references

Funding

The work was supported by RFBR (project No. 18-73-00054).

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Topchiyan, D. B. Vasilchenko, I. A. Baidina & I. V. Korolkov

  2. Novosibirsk State University, Novosibirsk, Russia

    P. A. Topchiyan

Authors
  1. P. A. Topchiyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. B. Vasilchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Baidina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. V. Korolkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. A. Topchiyan.

Ethics declarations

The authors declare that they have no conflict of interests.

Supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Topchiyan, P.A., Vasilchenko, D.B., Baidina, I.A. et al. ADDUCTS OF PLATINUM(IV) NITRATE COMPLEXES WITH 15-CROWN-5 ETHER. J Struct Chem 61, 1422–1431 (2020). https://doi.org/10.1134/S0022476620090097

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476620090097

Keywords

Search

Navigation