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Kinetics of the Formation of Nitroso Radicals in the System of Butyl Rubber Curing in the Presence of Sterically Hindered 2,4,6-Tri-tert-butylphenol

  • Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
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Abstract

The kinetics of the activity of the butyl rubber (BR) curing system without and with various amounts of antioxidant P-23 at temperatures of 55 and 80°C was studied. The induction period of the vulcanization of the BR samples in the presence of sterically hindered phenol was found to exceed that for the samples without phenol. With rising temperature the rate of the rubber vulcanization tends to increase due to an increase in the initiation rate.

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REFERENCES

  1. Fomin, V.M., Radikal’no-tsepnoe okislenie organicheskikh soedinenii i ego tormozhenie ingibitorami fenol’nogo tipa: Uchebnoe posobie (Radical-Chain Oxidation of Organic Compounds and Its Inhibition by Phenolic Inhibitors: a Tutorial), Nizhny Novgorod: Nizhegorod. Gos. Univ., 2010.

  2. Vulcanization of Elastomers: Principles and Practice of Vulcanization of Commercial Rubbers, Alliger, G. and Sjothun, I.J., Eds., New York: Reinhold, 1964.

  3. Hoffman, W., Vulcanization and Vulcanizing Agents, New York: Palmerton, 1967.

  4. Emmanuel’, N.M., Denisov, E.T., and Maizus, Z.K., Tsepnye reaktsii okisleniya uglevodorodov v zhidkoi faze (Chain Reactions of Oxidation of Hydrocarbons in the Liquid Phase), Moscow: Nauka, 1965.

  5. Denisov, E.T. and Emmanuel’, N.M., Usp. Khim., 1958, vol. 27, p. 365.

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  6. Ershov, V.V., Nikiforov, G.A., and Volod’kin, A.A., Prostranstvenno-zatrudnennye fenoly (Sterically Hindered Phenols), Moscow: Khimiya, 1972.

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Authors and Affiliations

  1. Research Institute of Polymer Materials, Joint-Stock Company, 614101, Perm, Russia

    E. Kh. Afiatullov, T. A. Chapko & L. N. Gur’eva

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  1. E. Kh. Afiatullov
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  2. T. A. Chapko
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  3. L. N. Gur’eva
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Correspondence to L. N. Gur’eva.

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Afiatullov, E.K., Chapko, T.A. & Gur’eva, L.N. Kinetics of the Formation of Nitroso Radicals in the System of Butyl Rubber Curing in the Presence of Sterically Hindered 2,4,6-Tri-tert-butylphenol. Russ J Gen Chem 90, 1808–1810 (2020). https://doi.org/10.1134/S1070363220090352

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  • DOI: https://doi.org/10.1134/S1070363220090352

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