Skip to main content
Log in

Synthesis, Structure and Properties of Material Based on V2AlC MAX Phase

  • STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION
  • Published:
Physics of Metals and Metallography Aims and scope Submit manuscript

Abstract–A material based on the V2AlC MAX phase has been obtained for the first time by the method of self-propagating high-temperature synthesis (SHS) using a reaction mixture of vanadium oxide(V) and (IV) powders with aluminum and carbon (graphite). The obtained material was characterized by X-ray diffraction and energy-dispersive X-ray spectroscopy. The Rietveld method was used to perform quantitative analysis. The synthesized material based on the V2AlC MAX phase is an electrical conductor that demonstrates the metallic behavior of conductivity in the entire measured temperature range of 300–1300 K in the vacuum of 2 × 10–3 Pa. It has been suggested that the V2AlC phase makes a decisive contribution to the electrical resistance of the synthesized material that may be caused by the formation of V2AlC nanolaminate grains contacting with each other in the bulk of the material.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. J. C. Schuster, H. Nowotny, and C. Vaccaro, “The ternary systems: Cr–Al–C, V–Al–C, and Ti–Al–C and the behavior of H-phases (M2AlC),” J. Solid State Chem. 32, 213–219 (1980).

    Article  CAS  Google Scholar 

  2. J. Etzkorn, M. Ade, and H. Hillebrecht, “V2AlC, V4AlC3 − x (x ≈ 0 : 31), and V12Al3C8: synthesis, crystal growth, structure, and superstructure,” Inorg. Chem. 46, 7646–7653 (2007).

    Article  CAS  Google Scholar 

  3. C. Hu, J. Wang, F. Li, J. Wang, and Y. Zhou, “Crystal structure of V4AlC3: a new layered ternary carbide,” J. Am. Ceram. Soc. 91, 636–639 (2008).

    Article  CAS  Google Scholar 

  4. B. Hallstedt, “Thermodynamic evaluation of the Al–V–C system,” CALPHAD: Comput. Coupling Phase Diagrams Thermochem. 41, 156–159 (2013). https://doi.org/10.1016/j.calphad.2013.03.002

    Article  CAS  Google Scholar 

  5. S. Gupta and M. W. Barsoum, “Synthesis and oxidation of V2AlC and (Ti0.5, V0.5)2AlC in air,” J. Electrochem. Soc. 151, 24–29 (2004).

    Article  Google Scholar 

  6. J. M. Schneider, R. Mertens, and D. Music, “Structure of V2AlC studied by theory and experiment,” J. Appl. Phys. 99, 013501 (2006).

    Article  Google Scholar 

  7. H. Chunfeng, H. Lingfeng, L. Mingyue, W. Xiaohui, W. Jingyang, L. Meishuan, and Z. Yanchun, “In situ reaction synthesis and mechanical properties of V2AlC,” J. Am. Ceram. Soc. 91, 4029–4035 (2008). https://doi.org/10.1111/j.1551-2916.2008.02774.x

    Article  CAS  Google Scholar 

  8. B.-Y. Liang, J. Zhang, and Y.-C. Mu, “Combustion synthesis of V2AlC materials,” Mater. Sci. Eng. Powder Metall. 18, 447–451 (2013).

    Google Scholar 

  9. R. Kiffer and Kh. Braun, Vanadium, Niobium, Tantalum (Metallurgy of Pure Metals and Their Alloys) (Metallurgiya, Moscow, 1968).

    Google Scholar 

  10. ICDD Database. PDF No. 01-074-5286.

  11. J. D. Hettinger, S. E. Lofland, P. Finkel, T. Meehan, J. Palma, K. Harrell, S. Gupta, A. Ganguly, T. El-Raghy, and M. W. Barsoum, “Electrical transport, thermal transport, and elastic properties of M2AlC (M = Ti, Cr, Nb, and V),” Phys. Rev. B 72, 115120 (2005).

    Article  Google Scholar 

  12. C. M. Hamm, M. DuËrrschnabel, L. Molina-Luna, R. Salikhov, D. Spoddig, M. Farle, U. Wiedwald, and C. S. Birkel, “Structural, magnetic and electrical transport properties of non-conventionally prepared MAX phases V2AlC and (V/Mn)2AlC,” Mater. Chem. Front. 2, 483 (2018). https://doi.org/10.1039/C7QM00488E

    Article  CAS  Google Scholar 

  13. V. A. Gorshkov, P. A. Miloserdov, M. A. Luginina, N. V. Sachkova, and A. F. Belikova, “High-temperature synthesis of a cast material with a maximum content of the MAZ phase Cr2AlC,” Inorg. Mater. 53, 271–277 (2017). https://doi.org/10.1134/S0020168517030062

    Article  CAS  Google Scholar 

  14. V. A. Gorshkov, P. A. Miloserdov, A. V. Karpov, A. S. Shchukin, and A. S. Sytschev, “Investigation of the composition and properties of a Cr2AlC MAX phase-based material prepared by metallothermic SHS,” Phys. Met. Metallogr. 120, 471–475 (2019). https://doi.org/10.1134/S0031918X19050041

    Article  CAS  Google Scholar 

  15. P. A. Miloserdov, V. A. Gorshkov, I. D. Kovalev, and D. Yu. Kovalev, “High-temperature synthesis of cast materials based on Nb2AlC MAX phase,” Ceram. Int. 45, 2689–2691 (2019). https://doi.org/10.1016/j.ceramint.2018.10.198

    Article  CAS  Google Scholar 

  16. A. Shiryaev, “Thermodynamics of SHS processes: An advanced approach,” Int. J. Self-Propag. High-Temp. Synth. 4, 351–362 (1995).

    CAS  Google Scholar 

  17. V. A. Firsova, N. G. Pyatygina, and T. I. Ivanova, “Rietveld method,” Registration Certificate of Software No. 2010613016 (06 May 2010).

  18. Crystallography Open Database. http://www.crystallography.net/cod/.

  19. Materials Project. https://materialsproject.org/.

  20. A. V. Karpov, Yu. G. Morozov, V. A. Bunin, and I. P. Borovinskaya, “Effect of yttria additions on the electrical conductivity of shs nitride ceramics,” Inorg. Mater. 38, 631–634 (2002).

    Article  CAS  Google Scholar 

  21. A. I. Gusev, “Effect of carbon vacancies on the electric resistivity of nonstoichiometric VCy vanadium carbide,” JETP Lett. 90, 191–196 (2009).

    Article  CAS  Google Scholar 

  22. S. Ratnadwip, R. Shubhankar, P. Arnab, S. Biswarup, and M. Prabhat, “Planar Hall effect in the type-II Dirac semimetal VAl3,” Phys. Rev. B 98, 081103(R). https://doi.org/10.1103/PhysRevB.98.081103

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. A. Gorshkov.

Additional information

Translated by A. Bannov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gorshkov, V.A., Karpov, A.V., Kovalev, D.Y. et al. Synthesis, Structure and Properties of Material Based on V2AlC MAX Phase. Phys. Metals Metallogr. 121, 765–771 (2020). https://doi.org/10.1134/S0031918X20080037

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0031918X20080037

Keywords:

Navigation