Elsevier

Lithos

Volumes 380–381, January 2021, 105822
Lithos

Research Article
Comprehensive refertilization of the Archean–Paleoproterozoic lithospheric mantle beneath the northwestern North China Craton: Evidence from in situ Sr isotopes of the Siziwangqi peridotites

https://doi.org/10.1016/j.lithos.2020.105822Get rights and content

Highlights

  • SCLM beneath the northwestern NCC is studied by in situ Sr isotopes of peridotites.

  • There exists the remnants of Archean–Paleoproterozoic lithospheric mantle.

  • SCLM was modified by multiple stages of mantle metasomatism.

  • Refertilization leads to the transformation of Archean–Paleoproterozoic mantle.

Abstract

Petrological observations and in situ major and trace element and Sr isotopic data for spinel-facies harzburgite and lherzolite xenoliths from the Siziwangqi region provide constraints on the nature and evolution of the lithospheric mantle beneath the northwestern North China Craton (NCC). These peridotites can be divided into high-Mg# peridotites (Fo > 91) and low-Mg# peridotites (Fo < 91), according to olivine forsterite (Fo) contents. The high-Mg# peridotites are harzburgites, which are characterized by high Mg# (91.0–91.8), as well as low CaO (0.41–1.17 wt%) and Al2O3 (0.62–2.03 wt%) contents. The clinopyroxenes have light rare earth element (LREE) depleted to slightly enriched patterns, and variable but dominantly radiogenic Sr isotopic compositions (0.7031–0.7053). These features indicate that the high-Mg# peridotites are remnants of Archean–Paleoproterozoic refractory lithospheric mantle, which then experienced variable refertilization. In contrast, the low-Mg# peridotites are mainly lherzolites and minor harzburgites, which have low Mg# (89.2–90.9), and high CaO (0.98–3.53 wt%) and Al2O3 (1.38–3.85 wt%) contents, relative to the high-Mg# peridotites. The clinopyroxenes in low-Mg# peridotites have similar REE patterns as those in the high-Mg# peridotites, and some grains show increasing LREE contents from core to rim. These clinopyroxenes have relatively depleted Sr isotopic compositions (0.7021–0.7045). The low-Mg# peridotites are interpreted to be the reaction products of high-Mg# peridotites and asthenospheric melts. The lithospheric mantle beneath the Siziwangqi region experienced an earlier metasomatic event related to subduction of Paleo-Asian oceanic materials, as evidenced by the relatively high 87Sr/86Sr ratios (up to 0.7053) and depletion of Rb, Ba, Pb, Nb and Ta in clinopyroxenes. The clinopyroxenes in both high- and low-Mg# peridotites have low (La/Yb)N and high Ti/Eu ratios, positive correlations between 87Sr/86Sr and Mg# and Ca/Al, negative correlations between 87Sr/86Sr and Na2O, TiO2, Ti/Eu, and Σ(middle REEs + heavy REEs), and decreasing 87Sr/86Sr ratios from core to rim. These observations imply that the lithospheric mantle beneath the Siziwangqi region experienced later multi-stage refertilization by asthenospheric melts. Therefore, we conclude that the lithospheric mantle beneath the northwestern NCC has been comprehensively refertilized by multiple stages of peridotite–melt reactions, similar to the northern margin of the NCC, which had a significant role in the transformation of the lithospheric mantle.

Introduction

Refertilization of the lithospheric mantle commonly refers to episodic infiltration of fertile metasomatic melt/fluid into originally highly refractory protoliths, leading to mineralogical and geochemical re-enrichment and rejuvenation of the subcontinental lithospheric mantle (SCLM) via peridotite–melt/fluid reactions or metasomatism (Foley, 2008; Griffin et al., 2009; Tang et al., 2008, Tang et al., 2011, Tang et al., 2013a; Zhang, 2005, Zhang, 2009; Zhang et al., 2007, Zhang et al., 2009, Zhang et al., 2012; Zou et al., 2016, Zou et al., 2020). In general, the percolating melt/fluid is derived from the asthenosphere (Tang et al., 2008, Tang et al., 2011; Zhang et al., 2012; Zou et al., 2016, Zou et al., 2020), subducted slab (Liu et al., 2005; Tang et al., 2007, Tang et al., 2012; Wang et al., 2019; Zhang et al., 2003), subducted continental crust (Sun et al., 2013; Zhang et al., 2002), or recycled crust (Gao et al., 2004; Tang et al., 2014; Zhang et al., 2010). Compared with depleted mantle peridotite, the metasomatic melt/fluid are typically rich in Fe, Ca, Al, Na, and incompatible trace elements, and depleted in Mg and Ni. As a result, refertilization transforms high-Mg# peridotites to low-Mg# peridotites and leads to the formation of some pyroxenite veins (Griffin et al., 2009; Zhang, 2005, Zhang, 2009; Zhang et al., 2007). Refertilization can also decouple the age of the present-day lithospheric mantle from that of the overlying crust, and rejuvenate the mantle Resingle bondOs isotopic data (Griffin et al., 2004; Tang et al., 2013b; Xu et al., 2008; Zhang, 2009; Zhang et al., 2008, Zhang et al., 2009, Zhang et al., 2012). Multi-stage and varying degrees of refertilization contribute to the transformation of old and refractory lithospheric mantle to “young” and fertile lithospheric mantle (Foley, 2008; Tang et al., 2013b; Zhang, 2009; Zhang et al., 2008).

The North China Craton (NCC) is an ideal site to investigate refertilization of the lithospheric mantle. Petrological, geochemical, and Resingle bondOs isotopic studies of xenocrysts and mantle xenoliths in Paleozoic kimberlites from Mengyin and Fuxian have demonstrated that the SCLM beneath the NCC was thick (>200 km), cold (geotherm = 36–40 mW/m2), refractory, and old in the Paleozoic (Chu et al., 2009; Gao et al., 2002; Wu et al., 2006; Zhang et al., 2008; Zheng et al., 2001), similar to typical Archean cratons. However, Cenozoic basalt-hosted xenocrysts and mantle xenoliths have revealed the SCLM under the NCC is thin (<80 km), hot (50–105 mW/m2), fertile, and “young” (Chu et al., 2009; Fan et al., 2000; Griffin et al., 1998; Menzies et al., 1993; Rudnick et al., 2004; Xu, 2001; Zhang, 2009; Zheng et al., 2006). It is considered that the geochemical compositions and physical properties of the SCLM beneath the NCC changed dramatically during the Mesozoic (Fan et al., 2000; Gao et al., 2002; Griffin et al., 1998; Menzies et al., 1993; Rudnick et al., 2004; Tang et al., 2013a; Xu, 2001; Zhang, 2009; Zhang et al., 2008; Zheng et al., 2001, Zheng et al., 2006).

Nonetheless, most previous studies have focused on the Eastern Block and the Central Zone of the NCC, and the architecture of the SCLM beneath the Western Block is less well-constrained due to the relative paucity of basalt-hosted mantle xenoliths and xenocrysts since the Cenozoic. Published geophysical data indicate that the current lithospheric thickness of the Western Block is up to 200 km (Chen, 2009, Chen, 2014; Chen et al., 2008), which remains relatively stable like a typical craton. In contrast, the lithospheric thickness of the northwestern NCC is ca. 70–120 km (Chen, 2009, Chen, 2014; Chen et al., 2008), which is obviously different from the typical architecture of cratonic lithospheric mantle. This may imply that considerable modification of the SCLM has occurred beneath the northwestern NCC, similar to the Eastern Block. Therefore, in this study, we report petrological observations and in situ mineral major and trace element and Sr isotopic data for peridotite xenoliths hosted by Cenozoic basalts in the Siziwangqi region (Fig. 1). The aim of this study was to investigate the nature and evolution of the lithospheric mantle beneath the northwestern NCC.

Section snippets

Geological background

The NCC is one of the world's oldest Archean cratons, and contains a crustal nucleus that is 3.8–2.5 Ga in age (Zhai and Santosh, 2011). The NCC is bounded by the Central Asian Orogenic Belt (CAOB) to the north and Qingling–Dabie–Sulu Ultrahigh-pressure Metamorphic Belt to the south. The NCC is divided into the Eastern and Western blocks and the intervening Trans-North China Orogen (TNCO), with the latter witnessing the collision between the Eastern and Western blocks at ca. 1.85 Ga (Santosh,

Xenolith petrology

The Siziwangqi basalts contain abundant mantle xenoliths, comprising dominantly spinel-facies harzburgites and lherzolites. Forty-five representative peridotite xenoliths selected for this work are rounded in shape, fresh, and range from 2 to 7 cm in size. The peridotites can be classified into two groups based on textures and the forsterite (Fo) contents of olivine: high-Mg# peridotites (Fo > 91) and low-Mg# peridotites (Fo < 91) (Table 1). In the Ol–Opx–Cpx ternary classification diagram (

Analytical methods

In situ major element compositions of olivine, clinopyroxene, orthopyroxene, and spinel were determined with a JXA-8230 electron microprobe at the State Key Laboratory of Continental Dynamics (SKL-CD), Northwest University, Xi'an, China. The analyses were performed at an accelerating voltage of 15 kV and beam current of 20 nA, with a beam diameter of 2 μm.

In situ trace element compositions of clinopyroxene were measured with an Agilent 7900 inductively coupled plasma mass spectrometer (ICP-MS)

Major elements

The major element compositions of minerals in the Siziwangqi peridotites are listed in Table S1. Two grains of olivine, orthopyroxene, clinopyroxene, and spinel in each sample and two points (core and rim) in each grain were analyzed. Most minerals (except for olivine in some samples) are homogeneous on an inter- and intra-granular scale. Thus, with the exception of olivine with compositional zoning and minerals in melt pockets, the data for other minerals presented in Table S1 are average

High-Mg# peridotites

The Archean lithospheric mantle is predominantly composed of highly refractory (Fo > 92.5) harzburgites and rare lherzolites (Boyd, 1989; Griffin et al., 1998), which are considered to be the residues of large degrees of partial melting of PM (Griffin et al., 1999). In general, from Archean through to Proterozoic and to Phanerozoic peridotites, the peridotites become less refractory and the clinopyroxene modal proportion increases (Griffin et al., 1998). In a plot of Fo content vs. modal

Conclusions

Petrological observations, elemental compositions, and in situ Sr isotopic data for the Siziwangqi peridotite xenoliths hosted by Cenozoic basalts, along with previous studies along the northern margin of the NCC, allow us to draw the following conclusions.

  • (1)

    The Siziwangqi high-Mg# peridotites are spinel-facies harzburgites, with relatively high Fo values (>91) and radiogenic Sr (0.7031–0.7053). They are relicts of Archean–Paleoproterozoic lithospheric mantle that have experienced weak

Declaration of Competing Interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgements

This research was financially supported by the National Natural Science Foundation of China, China (Grant 41688103). We thank Xiaoqi Zhang and Haibo Zou for assistance with the fieldwork and sample collection. We gratefully acknowledge Wenqiang Yang and Zhian Bao for assistance with the elemental analysis at the SKL-CD, Northwest University. We gratefully thank Zhaochu Hu and Wen Zhang for help with the Sr isotopic analysis at the GPMR, China University of Geosciences.

References (79)

  • Y.S. Liu et al.

    In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard

    Chem. Geol.

    (2008)
  • J.G. Liu et al.

    Mapping lithospheric boundaries using Os isotopes of mantle xenoliths: an example from the North China Craton

    Geochim. Cosmochim. Acta

    (2011)
  • W.F. McDonough et al.

    The composition of the Earth

    Chem. Geol.

    (1995)
  • D.C. Presnall et al.

    Generation of mid-ocean ridge basalts at pressures from 1 to 7 GPa

    Geochim. Cosmochim. Acta

    (2002)
  • F. Princivalle et al.

    Ultramafic xenoliths from Damaping (Hannuoba region, NE-China): Petrogenetic implications from crystal chemistry of pyroxenes, olivine and Cr-spinel and trace element content of clinopyroxene

    Lithos

    (2014)
  • R.L. Rudnick et al.

    Petrology and geochemistry of spinel peridotite xenoliths from Hannuoba and Qixia, North China craton

    Lithos

    (2004)
  • M. Santosh

    Assembling North China Craton within the Columbia supercontinent: the role of double-sided subduction

    Precambrian Res.

    (2010)
  • M. Santosh et al.

    Paleoproterozoic ultrahigh-temperature granulites in the North China Craton: Implications for tectonic models on extreme crustal metamorphism

    Precambrian Res.

    (2012)
  • M. Sneeringer et al.

    Strontium and samarium diffusion in diopside

    Geochim. Cosmochim. Acta

    (1984)
  • H. Staudigel et al.

    Large scale isotopic Sr, Nd and O isotopic anatomy of altered oceanic crust: DSDP/ ODP sites417/ 418

    Earth Planet. Sci. Lett.

    (1995)
  • Y.J. Tang et al.

    Lithium isotopic systematics of peridotite xenoliths from Hannuoba, North China Craton: Implications for melt–rock interaction in the considerably thinned lithospheric mantle

    Geochim. Cosmochim. Acta

    (2007)
  • Y.J. Tang et al.

    Refertilization of ancient lithospheric mantle beneath the central North China Craton: evidence from petrology and geochemistry of peridotite xenoliths

    Lithos

    (2008)
  • Y.J. Tang et al.

    Slab-derived lithium isotopic signatures in mantle xenoliths from northeastern North China Craton

    Lithos

    (2012)
  • Y.J. Tang et al.

    Widespread refertilization of cratonic and circum-cratonic lithospheric mantle

    Earth Sci. Rev.

    (2013)
  • Y.J. Tang et al.

    Highly heterogeneous lithospheric mantle beneath the Central Zone of the North China Craton evolved from Archean mantle through diverse melt refertilization

    Gondwana Res.

    (2013)
  • C.Y. Wang et al.

    Lithospheric transformation of the northern North China Craton by changing subduction style of the Paleo-Asian oceanic plate: Constraints from peridotite and pyroxenite xenoliths in the Yangyuan basalts

    Lithos

    (2019)
  • F.Y. Wu et al.

    The chemical-temporal evolution of lithospheric mantle underlying the North China Craton

    Geochim. Cosmochim. Acta

    (2006)
  • D. Wu et al.

    In-situ trace element and Sr isotopic compositions of mantle xenoliths constrain two-stage metasomatism beneath the northern North China Craton

    Lithos

    (2017)
  • Y.G. Xu

    Thermo-tectonic destruction of the archaean lithospheric keel beneath the sino-korean craton in China: evidence, timing and mechanism

    Phys. Chem. Earth Solid Earth Geod.

    (2001)
  • X.S. Xu et al.

    Re-Os isotopes of sulfides in mantle xenoliths from eastern China: progressive modification of lithospheric mantle

    Lithos

    (2008)
  • M.G. Zhai et al.

    The early Precambrian odyssey of the North China Craton: a synoptic overview

    Gondwana Res.

    (2011)
  • H.F. Zhang

    Transformation of lithospheric mantle through peridotite-melt reaction: a case of Sino-Korean craton

    Earth Planet. Sci. Lett.

    (2005)
  • H.F. Zhang et al.

    Secular evolution of the lithosphere beneath the eastern North China Craton: evidence from Mesozoic basalts and high-Mg andesites

    Geochim. Cosmochim. Acta

    (2003)
  • H.F. Zhang et al.

    Melt-peridotite interaction in the Pre-Cambrian mantle beneath the western North China Craton: Petrology, geochemistry and Sr, Nd and Re isotopes

    Lithos

    (2012)
  • H.T. Zhang et al.

    Low-δ13C carbonates in the Miocene basalt of the northern margin of the North China Craton: Implications for deep carbon recycling

    J. Asian Earth Sci.

    (2017)
  • W. Zhang et al.

    Improved in situ Sr isotopic analysis by a 257nm femtosecond laser in combination with the addition of nitrogen for geological minerals

    Chem. Geol.

    (2018)
  • G.C. Zhao et al.

    Metamorphism of basement rocks in the Central Zone of the North China Craton: implications for Paleoproterozoic tectonic evolution

    Precambrian Res.

    (2000)
  • G.C. Zhao et al.

    Late Archean to Paleoproterozoic evolution of the North China Craton: key issues revisited

    Precambrian Res.

    (2005)
  • J.P. Zheng et al.

    Relict refractory mantle beneath the eastern North China block: significance for lithosphere evolution

    Lithos

    (2001)
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