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Assessing major factors impacts on the hydrogeochemistry in a riverside alluvial aquifer, northeast China

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Abstract

The 18 main physicochemical parameters were analyzed in 8 surface water samples and 67 groundwater samples from a typical riverside alluvial aquifer (RAA), which is the main water source in northeast China and is mainly characterized by nitrogen pollution. By integrating hydrochemical methods and multivariate statistical methods (hierarchical cluster analysis (HCA), principal component analysis (PCA), and factor analysis (FA)), the hydrogeochemistry of this RAA was investigated in the present study to reveal the spatial characteristics of groundwater chemistry and estimate the major controlling factors and their contribution to the spatial variations of groundwater chemistry. The results indicated that the groundwater chemistry had high spatial variability in the study area and was characterized by exceeding concentrations of nitrogen, Fe, and Mn. According to the dominant chemical composition, the HCA classified these samples into four chemically distinct groups (groups 1–4). The groundwater quality deteriorated from group 1 to group 4, which was induced by anthropogenic pollution (agricultural activities and polluted river water) and diverse hydrogeochemical processes. PCA and FA were used to evaluate and verify the contribution of these processes to groundwater chemistry. Four factors that explained 76.52% of the total variance of these distinct groups were identified: (1) Cl and/or SO42− salt input, mineral dissolution, and industrial and domestic sewage discharges; (2) nitrate generation processes; (3) the original geological environment based on water-rock interaction; (4) ammonia input from industrial and domestic sewage, and agricultural fertilizers. The results of the present study provide a valuable scientific basis for better understanding the characteristics of groundwater hydrochemical and hydrogeochemical processes, and it can be considered as a reference that contributes to the management of RAAs and relevant policy-making for similar regions.

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References

  • Appelo CAJ, Postma D (2004) Geochemistry, groundwater and pollution. CRC press

  • Avtar R, Kumar P, Surjan A, Gupta LN, Roychowdhury K (2013) Geochemical processes regulating groundwater chemistry with special reference to nitrate and fluoride enrichment in Chhatarpur area, Madhya Pradesh, India. Environ Earth Sci 70:1699–1708. https://doi.org/10.1007/s12665-013-2257-7

    Article  Google Scholar 

  • Berg M, Tran HC, Nguyen TC, Pham HV, Schertenleib R, Giger W (2001) Arsenic contamination of groundwater and drinking water in Vietnam: a human health threat. Environ Sci Technol 35:2621–2626. https://doi.org/10.1021/es010027y

    Article  Google Scholar 

  • Bertrand G, Goldscheider N, Gobat J-M, Hunkeler D (2012) Review: From multi-scale conceptualization to a classification system for inland groundwater-dependent ecosystems. Hydrogeol J 20:5–25. https://doi.org/10.1007/s10040-011-0791-5

    Article  Google Scholar 

  • Carling M, Hammar M (1995) Nitrogen metabolism and leakage from pit latrines. University of Ludea, Report 20

  • Chae G-T et al (2004a) Hydrogeochemistry of alluvial groundwaters in an agricultural area: an implication for groundwater contamination susceptibility. Chemosphere 55:369–378

    Article  Google Scholar 

  • Chae GT et al (2004b) Hydrogeochemistry of alluvial groundwaters in an agricultural area: an implication for groundwater contamination susceptibility Chemosphere 55:369-378. https://doi.org/10.1016/j.chemosphere.2003.11.001

  • Corner S (2009) Choosing the right type of rotation in PCA and EFA JALT testing & evaluation. SIG newsletter 13:20–25

    Google Scholar 

  • Cox D, Lawver DE, Baker M, Doerfert D, Kistler M (n.d.) Identifying factors associated with the teaching of water issues in secondary agricultural science programs

  • Di Curzio D, Palmucci W, Rusi S, Signanini P (2016) Evaluation of processes controlling Fe and Mn contamination in the San Pedro Sula porous aquifer (North Western Honduras). RENDICONTI ONLINE SOCIETA GEOLOGICA ITALIANA 41:42–45

    Article  Google Scholar 

  • Di Curzio D, Rusi S, Signanini P (2019) Advanced redox zonation of the San Pedro Sula alluvial aquifer (Honduras) using data fusion and multivariate geostatistics. Sci Total Environ 695:133796

    Article  Google Scholar 

  • Dragon K (2006) Application of factor analysis to study contamination of a semi-confined aquifer (Wielkopolska Buried Valley aquifer, Poland). J Hydrol 331:272–279. https://doi.org/10.1016/j.jhydrol.2006.05.032

    Article  Google Scholar 

  • DZ/T 0290-2015 (2015) Standard for groundwater quality. Ministry of Land and Resources of the People’s Republic of China, Beijing

    Google Scholar 

  • Esmaeili A, Moore F, Keshavarzi B (2014) Nitrate contamination in irrigation groundwater, Isfahan, Iran. Environ Earth Sci 72:2511–2522

    Article  Google Scholar 

  • Guo W, He M, Yang Z, Lin C, Quan X (2011a) Aliphatic and polycyclic aromatic hydrocarbons in the Xihe River, an urban river in China’s Shenyang City: distribution and risk assessment. J Hazard Mater 186:1193–1199. https://doi.org/10.1016/j.jhazmat.2010.11.122

    Article  Google Scholar 

  • Guo W, He MC, Yang ZF, Lin CY, Quan XC (2011b) Aliphatic and polycyclic aromatic hydrocarbons in the Xihe River, an urban river in China's Shenyang City: distribution and risk assessment. J Hazard Mater 186:1193–1199. https://doi.org/10.1016/j.jhazmat.2010.11.122

    Article  Google Scholar 

  • Hou G et al (2014a) Performance of a permeable reactive barrier for in situ removal of ammonium in groundwater. Water Sci Technol Water Supply 14:585. https://doi.org/10.2166/ws.2014.012

    Article  Google Scholar 

  • Hou GH et al (2014b) Performance of a permeable reactive barrier for in situ removal of ammonium in groundwater. Water Science and Technology-Water Supply 14:585–592. https://doi.org/10.2166/ws.2014.012

    Article  Google Scholar 

  • Hu Y, Moiwo JP, Yang Y, Han S, Yang Y (2010) Agricultural water-saving and sustainable groundwater management in Shijiazhuang Irrigation District, North China Plain. J Hydrol 393:219–232. https://doi.org/10.1016/j.jhydrol.2010.08.017

    Article  Google Scholar 

  • Huang G, Sun J, Zhang Y, Chen Z, Liu F (2013) Impact of anthropogenic and natural processes on the evolution of groundwater chemistry in a rapidly urbanized coastal area, South China. Sci Total Environ 463-464:209–221. https://doi.org/10.1016/j.scitotenv.2013.05.078

    Article  Google Scholar 

  • Huang H, Liu M, Wang J, He J, Chen H (2018) Sources identification of nitrogen using major ions and isotopic tracers in Shenyang, China. Geofluids 2018:1–11. https://doi.org/10.1155/2018/8683904

    Article  Google Scholar 

  • Jacks G, Sefe F, Carling M, Hammar M, Letsamao P (1999) Tentative nitrogen budget for pit latrines—eastern Botswana. Environ Geol 38:199–203

    Article  Google Scholar 

  • Jeong CH (2001) Effect of land use and urbanization on hydrochemistry and contamination of groundwater from Taejon area, Korea. J Hydrol 253:194–210

    Article  Google Scholar 

  • Jiang Y, Wu Y, Groves C, Yuan D, Kambesis P (2009) Natural and anthropogenic factors affecting the groundwater quality in the Nandong karst underground river system in Yunan, China. J Contam Hydrol 109:49–61. https://doi.org/10.1016/j.jconhyd.2009.08.001

    Article  Google Scholar 

  • Kelly WR (1997) Heterogeneities in ground-water geochemistry in a sand aquifer beneath an irrigated field. J Hydrol 198:154–176

    Article  Google Scholar 

  • Kim K, Rajmohan N, Kim HJ, Hwang G-S, Cho MJ (2004) Assessment of groundwater chemistry in a coastal region (Kunsan, Korea) having complex contaminant sources: a stoichiometric approach. Environ Geol 46:763–774. https://doi.org/10.1007/s00254-004-1109-x

    Article  Google Scholar 

  • Kim K et al (2005) Evaluation of geochemical processes affecting groundwater chemistry based on mass balance approach: a case study in Namwon, Korea. Geochem J 39:357–369

    Article  Google Scholar 

  • Kim KH, Yun ST, Choi BY, Chae GT, Joo Y, Kim K, Kim HS (2009) Hydrochemical and multivariate statistical interpretations of spatial controls of nitrate concentrations in a shallow alluvial aquifer around oxbow lakes (Osong area, central Korea). J Contam Hydrol 107:114–127. https://doi.org/10.1016/j.jconhyd.2009.04.007

    Article  Google Scholar 

  • Kim H-R et al (2019) Nitrate contamination and subsequent hydrogeochemical processes of shallow groundwater in agro-livestock farming districts in South Korea. Agric Ecosyst Environ 273:50–61. https://doi.org/10.1016/j.agee.2018.12.010

    Article  Google Scholar 

  • Kløve B et al (2011) Groundwater dependent ecosystems. Part II Ecosystem services and management in Europe under risk of climate change and land use intensification. Environ Sci Policy 14:782–793

    Article  Google Scholar 

  • Lapworth DJ, Krishan G, MacDonald AM, Rao MS (2017) Groundwater quality in the alluvial aquifer system of northwest India: new evidence of the extent of anthropogenic and geogenic contamination. Sci Total Environ 599-600:1433–1444. https://doi.org/10.1016/j.scitotenv.2017.04.223

    Article  Google Scholar 

  • Li X, Du J, Cui J, Chai L, Yang Z, Ma H (2012) An analysis of the resources evaluation and exploration potential of the shallow groundwater of the Hun River fan China. Rural Water and Hydropower 49-54 + 58

  • Li H, Hopke PK, Liu X, Du X, Li F (2015) Application of positive matrix factorization to source apportionment of surface water quality of the Daliao River basin, northeast China. Environ Monit Assess 187:80. https://doi.org/10.1007/s10661-014-4154-2

    Article  Google Scholar 

  • Li P, Li X, Meng X, Li M, Zhang Y (2016) Appraising groundwater quality and health risks from contamination in a semiarid region of northwest China. Exposure Health 8:361–379. https://doi.org/10.1007/s12403-016-0205-y

    Article  Google Scholar 

  • Lin CY, Abdullah MH, Praveena SM, Yahaya AHB, Musta B (2012) Delineation of temporal variability and governing factors influencing the spatial variability of shallow groundwater chemistry in a tropical sedimentary island. J Hydrol 432-433:26–42. https://doi.org/10.1016/j.jhydrol.2012.02.015

    Article  Google Scholar 

  • Lin C, He M, Liu X, Guo W, Liu S (2013) Contamination and ecological risk assessment of toxic trace elements in the Xi River, an urban river of Shenyang city, China. Environ Monit Assess 185:4321–4332. https://doi.org/10.1007/s10661-012-2871-y

    Article  Google Scholar 

  • Loh YSA, Yidana SM, Banoeng-Yakubo B, Sakyi PA, Addai MO, Asiedu DK (2016) Determination of the mineral stability field of evolving groundwater in the Lake Bosumtwi impact crater and surrounding areas. J Afr Earth Sci 121:286–300

    Article  Google Scholar 

  • Loni OA et al (2014) Evaluation of groundwater quality in an evaporation dominant arid environment; a case study from Al Asyah area in Saudi Arabia. Arab J Geosci 8:6237–6247. https://doi.org/10.1007/s12517-014-1623-4

    Article  Google Scholar 

  • McDonald RI, Green P, Balk D, Fekete BM, Revenga C, Todd M, Montgomery M (2011) Urban growth, climate change, and freshwater availability. Proc Natl Acad Sci 108:6312–6317

    Article  Google Scholar 

  • Mencio A et al (2016) Nitrate pollution of groundwater; all right…, but nothing else? Sci Total Environ 539:241–251. https://doi.org/10.1016/j.scitotenv.2015.08.151

    Article  Google Scholar 

  • Meng L et al (2018) Quantitative source apportionment of groundwater pollution: a case study of alluvial fan groundwater in the Hun river region, NE China. Geochemistry: Exploration, Environment, Analysis. https://doi.org/10.1144/geochem2018-053

  • Min JH, Yun ST, Kim K, Kim HS, Kim DJ (2003) Geologic controls on the chemical behaviour of nitrate in riverside alluvial aquifers, Korea. Hydrol Process 17:1197–1211

    Article  Google Scholar 

  • Mondal NC, Singh VP, Singh S, Singh VS (2011) Hydrochemical characteristic of coastal aquifer from Tuticorin, Tamil Nadu, India. Environ Monit Assess 175:531–550

    Article  Google Scholar 

  • Mustapha A, Aris AZ, Juahir H, Ramli MF (2012) Surface water quality contamination source apportionment and physicochemical characterization at the upper section of the Jakara Basin, Nigeria. Arab J Geosci 6:4903–4915. https://doi.org/10.1007/s12517-012-0731-2

    Article  Google Scholar 

  • Naseem S, McArthur JM (2018) Arsenic and other water-quality issues affecting groundwater, Indus alluvial plain, Pakistan. Hydrol Process 32:1235–1253. https://doi.org/10.1002/hyp.11489

    Article  Google Scholar 

  • Nixdorf E, Sun Y, Su J, Wang Q, Wang T, Kolditz O, Xi B (2018) Groundwater risk sources identification and risk reduction management in the Song-Liao-River-Basin. In: Chinese water systems. Terrestrial Environmental Sciences, pp 349–398. https://doi.org/10.1007/978-3-319-76469-6_5

    Chapter  Google Scholar 

  • Nkotagu H (1996) Origins of high nitrate in groundwater in Tanzania. J Afr Earth Sci 22:471–478

    Article  Google Scholar 

  • Noshadi M, Ghafourian A (2016) Groundwater quality analysis using multivariate statistical techniques (case study: Fars province, Iran). Environ Monit Assess 188:419. https://doi.org/10.1007/s10661-016-5412-2

    Article  Google Scholar 

  • Palmucci W, Rusi S (2014) Boron-rich groundwater in Central Eastern Italy: a hydrogeochemical and statistical approach to define origin and distribution. Environ Earth Sci 72:5139–5157

    Article  Google Scholar 

  • Palmucci W, Rusi S, Di Curzio D (2016) Mobilisation processes responsible for iron and manganese contamination of groundwater in Central Adriatic Italy. Environ Sci Pollut Res Int 23:11790–11805. https://doi.org/10.1007/s11356-016-6371-4

    Article  Google Scholar 

  • Pastén-Zapata E, Ledesma-Ruiz R, Harter T, Ramírez AI, Mahlknecht J (2014) Assessment of sources and fate of nitrate in shallow groundwater of an agricultural area by using a multi-tracer approach. Sci Total Environ 470:855–864

    Article  Google Scholar 

  • Qin R, Wu Y, Xu Z, Xie D, Zhang C (2013) Assessing the impact of natural and anthropogenic activities on groundwater quality in coastal alluvial aquifers of the lower Liaohe River Plain, NE China. Appl Geochem 31:142–158. https://doi.org/10.1016/j.apgeochem.2013.01.001

    Article  Google Scholar 

  • Rodell M, Velicogna I, Famiglietti JS (2009) Satellite-based estimates of groundwater depletion in India. Nature 460:999. https://doi.org/10.1038/nature08238

    Article  Google Scholar 

  • Rui LI, Hong-jie GAO, Yong-hui S, Jian-feng P, Hui-bin YU, Si-yu W (2013) Study on spatial distribution characteristics of water quality in Xihe River and Baitapu River of Shenyang. J Environ Eng Technol:429–436. https://doi.org/10.3969/j.issn.1674-991X.2013.05.067

  • Semar A, Saibi H, Medjerab A (2012) Contribution of multivariate statistical techniques in the hydrochemical evaluation of groundwater from the Ouargla phreatic aquifer in Algeria. Arab J Geosci 6:3427–3436. https://doi.org/10.1007/s12517-012-0616-4

    Article  Google Scholar 

  • Shi X, Wang Y, Jiao JJ, Zhong J, Wen H, Dong R (2018) Assessing major factors affecting shallow groundwater geochemical evolution in a highly urbanized coastal area of Shenzhen City, China. J Geochem Explor 184:17–27. https://doi.org/10.1016/j.gexplo.2017.10.003

    Article  Google Scholar 

  • Singh KP, Gupta S, Rai P (2014) Investigating hydrochemistry of groundwater in Indo-Gangetic alluvial plain using multivariate chemometric approaches. Environ Sci Pollut Res 21:6001–6015. https://doi.org/10.1007/s11356-014-2517-4

    Article  Google Scholar 

  • Su XS, Yuan WZ, Xu W, Du SH (2015) A groundwater vulnerability assessment method for organic pollution: a validation case in the Hun River basin, Northeastern China. Environ Earth Sci 73:467–480. https://doi.org/10.1007/s12665-014-3859-4

    Article  Google Scholar 

  • Su XS, Yuan WZ, Du SH, Cui G, Bai J, Du SY (2017) Responses of groundwater vulnerability to groundwater extraction reduction in the Hun River Basin, northeastern China. Hum Ecol Risk Assess 23:1121–1139. https://doi.org/10.1080/10807039.2017.1300858

    Article  Google Scholar 

  • Tabachnick B, Fidell L (2013) Using multivariate statistics, 6th edn, new international edition. Pearson Education Limited, Harlow

    Google Scholar 

  • Wakida FT, Lerner DN (2005) Non-agricultural sources of groundwater nitrate: a review and case study. Water Res 39:3–16. https://doi.org/10.1016/j.watres.2004.07.026

    Article  Google Scholar 

  • Wang J (2013) The study of groundwater nitrogen contamination in a riparian area of the Hun River. China University of Geosciences (Beijing), Shenyang

    Google Scholar 

  • Wu X et al (2017) Investigating hydrochemical groundwater processes in an inland agricultural area with limited data: a clustering approach. Water 9:723

    Article  Google Scholar 

  • Yang W, Wang Y, Li Y, Pan J, Yuan Y, Guo Y (2006) Biogeochemical characteristics and nitrogen transformation in saturated rock formations. Journal of Shenyang Jianzhu University (Natural Science):812-816

  • Zhang Y, Guo F, Meng W, Wang X-Q (2008) Water quality assessment and source identification of Daliao river basin using multivariate statistical methods. Environ Monit Assess 152:105–121. https://doi.org/10.1007/s10661-008-0300-z

    Article  Google Scholar 

  • Zhang J, Dai JL, Chen HR, Du XM, Wang WX, Wang RQ (2012) Petroleum contamination in groundwater/air and its effects on farmland soil in the outskirt of an industrial city in China. J Geochem Explor 118:19–29. https://doi.org/10.1016/j.gexplo.2012.04.002

    Article  Google Scholar 

  • Zhang H, Sun L, Sun T, Li H, Luo Q (2013) Spatial distribution and seasonal variation of polycyclic aromatic hydrocarbons (PAHs) contaminations in surface water from the Hun River, northeast China. Environ Monit Assess 185:1451–1462. https://doi.org/10.1007/s10661-012-2644-7

    Article  Google Scholar 

  • Zhang JJ, Zhai YZ, Xue PW, Huan H, Zhao XB, Teng YG, Wang JS (2017) A GIS-based LVF model for semiquantitative assessment of groundwater pollution risk: a case study in Shenyang, NE China. Hum Ecol Risk Assess 23:276–298. https://doi.org/10.1080/10807039.2016.1245099

    Article  Google Scholar 

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Acknowledgments

This study was funded by the Major Science and Technology Program for Water Pollution Control and Treatment (Nos. 2018ZX07109 and 2009ZX07424-002). The authors thank the Beijing Key Laboratory of Water Resources and Environmental Engineering for their technical support. The authors would also like to thank the editor and anonymous reviewers for their valuable comments and suggestions.

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Correspondence to Mingzhu Liu.

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Wang, L., Du, T., Hu, Q. et al. Assessing major factors impacts on the hydrogeochemistry in a riverside alluvial aquifer, northeast China. Arab J Geosci 13, 1072 (2020). https://doi.org/10.1007/s12517-020-06058-3

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