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Heterogeneous Catalysts SILP with Phosphotungstic Acid for Oxidative Desulfurization: Effect of Ionic Liquid

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Abstract

SILP (supporting ionic liquid phase) catalysts for peroxide thiophene oxidation were obtained on silica gel, they included imidazole cations with sulfonic acid group and phosphotungstate anions. The composition of the active phase and the surface structure of the catalysts are characterized by a set of modern physicochemical methods, including mass spectrometry using the SALDI technique. It was found that the organic cation structure affects the stability of heteropolyanions, decomposition processes in the SILP and the catalytic properties of the samples. SILP catalysts are effective in desulfurization of the diesel fraction and provide fuel with an S content of less than 10 ppm.

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Funding

The work was supported by the Russian Foundation for Basic Research, project no. 19-33-90024. Equipment purchased under the University Development Program of the Moscow State University was used in the study.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. A. Bryzhin, V. M. Zelikman, M. I. Shilina & I. G. Tarkhanova

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    A. K. Buryak

  3. Helmholtz Institut Erlangen-Nürnberg for Renewable Energy, 91058, Erlangen, Germany

    M. G. Gantman

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  1. A. A. Bryzhin
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  2. A. K. Buryak
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  3. M. G. Gantman
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  4. V. M. Zelikman
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  5. M. I. Shilina
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  6. I. G. Tarkhanova
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Correspondence to I. G. Tarkhanova.

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Translated by O. Kadkin

Abbreviations: HPA, heteropolyacid; IL, ionic liquid; ODS, oxidative desulfurization; ZI, Zwitterionic compound; PTA, phosphotungstic heteropolyacid; SALDI, surface-assisted laser desorption/ionization; NMR, nuclear magnetic resonance; TPD NH3, temperature programmed desorption of ammonia; SEM, scanning electron microscopy; SEI, secondary electron imaging; GLC, gas–liquid chromatography; DMF, dimethylformamide; BJH, Barrett–Joyner–Halenda method; BET, Brunauer–Emmett–Teller method.

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Bryzhin, A.A., Buryak, A.K., Gantman, M.G. et al. Heterogeneous Catalysts SILP with Phosphotungstic Acid for Oxidative Desulfurization: Effect of Ionic Liquid. Kinet Catal 61, 775–785 (2020). https://doi.org/10.1134/S0023158420050018

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