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Green Synthesis up to Geometric Gold Microparticles

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Abstract

In this work the study of optical properties of micro and nanostructured particles of gold is approached. A method of nanoparticle stabilization synthesis based on the philosophy of green chemistry by using orange extract (Citrus X sinensis) was proposed. Controlling specific parameters of the proposed synthesis method, particles with sizes lower than 50 nm were obtained and after the heat treatment the geometric particle sizes ranged from 0.2 to 2 μm. The optical absorption of the particles was studied finding absorption bands associated with the surface plasmon resonance. Experimentally, the nanomaterials obtained were tested on pyridine as SERS substrate. Complementary, in order to find clues of vibrational behavior, theoretically the interaction with pyridine molecule and gold layer structure were considered. The individual systems were perturbed by incident radiation with blue (435 nm), green (532 nm), red (638 nm) and infrared (785 nm and 1064) wavelengths for its SERS analysis.

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Acknowledgements

Special thanks to cDr. Belem Gonzales and the Laboratory of Crystallography and Geochemistry, of the Department of Geology of the University of Sonora for the development of SEM measurements. This work was supported by Project A1-S-46242 of the CONACYT Basic Science. The author M. Cortez-Valadez appreciates the support by “Cátedras CONACYT” program.

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Authors and Affiliations

  1. CONACYT-Departamento de Investigación en Física, Universidad de Sonora, Apdo. Postal 5-88, 83190, Hermosillo, Sonora, Mexico

    M. Cortez-Valadez

  2. Departamento de Física, Universidad de Sonora, Rosales y Luis Encinas S/N, C.P. 83000, Hermosillo, Sonora, Mexico

    L. P. Ramírez-Rodríguez

  3. CENAM, Centro Nacional de Metrología, km 4.5 Carretera a Los Cués, El Marqués, C.P. 76246, Santiago de Querétaro, QRO, Mexico

    F. Martínez-Suarez

  4. Universidad Autónoma de Sinaloa, Fuente de Poseidón y Prol. Ángel Flores S/N, C.P. 81223, Los Mochis, Sinaloa, Mexico

    R. A. Vargas-Ortiz

  5. Departamento de Nanocatálisis, Centro de Nanociencias y Nanotecnología (CNyN), Universidad Nacional Autónoma de México, Carretera Tijuana-Ensenada, Km. 107, Ensenada, Baja California, Mexico

    F. F. Castillón-Barraza

  6. Departamento de Investigación en Física, Universidad de Sonora, Apdo. Postal 5-88, 83190, Hermosillo, Sonora, Mexico

    M. Flores-Acosta

Authors
  1. M. Cortez-Valadez
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  2. L. P. Ramírez-Rodríguez
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  3. F. Martínez-Suarez
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  4. R. A. Vargas-Ortiz
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  5. F. F. Castillón-Barraza
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  6. M. Flores-Acosta
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Correspondence to M. Cortez-Valadez or F. F. Castillón-Barraza.

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Cortez-Valadez, M., Ramírez-Rodríguez, L.P., Martínez-Suarez, F. et al. Green Synthesis up to Geometric Gold Microparticles. J Inorg Organomet Polym 31, 1079–1085 (2021). https://doi.org/10.1007/s10904-020-01721-4

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  • DOI: https://doi.org/10.1007/s10904-020-01721-4

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