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Influence of chemically treated carbon fibers on the electromagnetic shielding of ultra-high-performance fiber-reinforced concrete

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Abstract

The effects of carbon fiber and its surface treatment through chemical solutions on the mechanical properties and electromagnetic (EM) shielding of ultra-high-performance fiber-reinforced concrete (UHPFRC) were analyzed. Three types of carbon fibers chemically treated with sodium hydroxide, nitric acid, and ammonia solutions were evaluated, along with a plain carbon fiber control sample, at two different concentrations of 0.1% and 0.3% by weight. The surface of carbon fiber was oxidized by chemical solutions. The conductivity of UHPFRC increased with increasing the carbon fiber content, and slightly better conductivity was obtained using the chemically treated carbon fibers than plain fibers at the lower content of 0.1 wt%. Both steel and carbon fibers were effective at improving the shielding effectiveness of ultra-high-performance concrete, and a higher shielding effectiveness was achieved for higher carbon fiber content. Surface treatment using the nitric acid solution was the most effective at enhancing the tensile performance and EM shielding effectiveness, and the best shielding effectiveness (49.0 dB at 1 GHz) was achieved for UHPFRC with 0.1 wt% nitric acid treated carbon fibers. The shielding effectiveness was found to be generally proportional to the electrical conductivity, although its increase was minor relative to that of the conductivity.

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References

  1. Muthusamy S, Chung DDL. Carbon-fiber cement-based materials for electromagnetic shielding. ACI Mater J. 2010;107(6):602–10.

    Google Scholar 

  2. Lee N, Kim S, Park G. The effects of multi-walled carbon nanotubes and steel fibers on the AC impedance and electromagnetic shielding effectiveness of high-performance, fiber-reinforced cementitious composites. Materials. 2019;12(21):3591.

    Article  Google Scholar 

  3. Yoo DY, You I, Zi G, Lee SJ. Effects of carbon nanomaterial type and amount on self-sensing capacity of cement paste. Measurement. 2019;134:750–61.

    Article  Google Scholar 

  4. Banthia N, Djeridane S, Pigeon M. Electrical resistivity of carbon and steel micro-fiber reinforced cements. Cem Concr Res. 1992;22(5):804–14.

    Article  Google Scholar 

  5. Baeza FJ, Galao O, Zornoza E, Garcés P. Effect of aspect ratio on strain sensing capacity of carbon fiber reinforced cement composites. Mater Des. 2013;51:1085–94.

    Article  Google Scholar 

  6. Chiarello M, Zinno R. Electrical conductivity of self-monitoring CFRC. Cem Concr Compos. 2005;27(4):463–9.

    Article  Google Scholar 

  7. Azhari F, Banthia N. Cement-based sensors with carbon fibers and carbon nanotubes for piezoresistive sensing. Cem Concr Compos. 2012;34(7):866–73.

    Article  Google Scholar 

  8. Han B, Yu X, Zhang K, Kwon E, Ou J. Sensing properties of CNT-filled cement-based stress sensors. J Civ Struct Health Monit. 2011;1(1–2):17–24.

    Article  Google Scholar 

  9. Yoo DY, Kim S, Lee SH. Self-sensing capability of ultra-high-performance concrete containing steel fibers and carbon nanotubes under tension. Sens Actuators A Phys. 2018;276:125–36.

    Article  Google Scholar 

  10. Singh AP, Gupta BK, Mishra M, Chandra A, Mathur RB, Dhawan SK. Multiwalled carbon nanotube/cement composites with exceptional electromagnetic interference shielding properties. Carbon. 2013;56:86–96.

    Article  Google Scholar 

  11. Wen S, Chung DDL. Electromagnetic interference shielding reaching 70 dB in steel fiber cement. Cem Concr Res. 2004;34(2):329–32.

    Article  Google Scholar 

  12. Chen J, Zhao D, Ge H, Wang J. Graphene oxide-deposited carbon fiber/cement composites for electromagnetic interference shielding application. Constr Build Mater. 2015;84:66–72.

    Article  Google Scholar 

  13. De Leo R, Gradoni G, Mazzoli A, Moglie F, Moriconi G, Primiani VM. Shielding effectiveness evaluation of densified-small-particles (DSP) cement composite. In: IEEE 2008 international symposium on electromagnetic compatibility-EMC, Hamburg, Germany, 2008, pp 1–6.

  14. Dai Y, Sun M, Liu C, Li Z. Electromagnetic wave absorbing characteristics of carbon black cement-based composites. Cem Concr Compos. 2010;32(7):508–13.

    Article  Google Scholar 

  15. Liu Z, Ge H, Wu J, Chen J. Enhanced electromagnetic interference shielding of carbon fiber/cement composites by adding ferroferric oxide nanoparticles. Constr Build Mater. 2017;151:575–81.

    Article  Google Scholar 

  16. Fu X, Chung DDL. Contact electrical resistivity between cement and carbon fiber: its decrease with increasing bond strength and its increase during fiber pull-out. Cem Concr Res. 1995;25(7):1391–6.

    Article  Google Scholar 

  17. Fu X, Lu W, Chung DDL. Ozone treatment of carbon fiber for reinforcing cement. Carbon. 1998;36(9):1337–455.

    Article  Google Scholar 

  18. Fu X, Lu W, Chung DDL. Improving the bond strength between carbon fiber and cement by fiber surface treatment and polymer addition to cement mix. Cem Concr Res. 1996;26(7):1007–122.

    Article  Google Scholar 

  19. Song W, Gu A, Liang G, Yuan L. Effect of the surface roughness on interfacial properties of carbon fibers reinforced epoxy resin composites. Appl Surf Sci. 2011;257(9):4069–74.

    Article  Google Scholar 

  20. Richard P, Cheyrezy M. Composition of reactive powder concretes. Cem Concr Res. 1995;25(7):1501–11.

    Article  Google Scholar 

  21. Graybeal BA. Material property characterization of ultra-high performance concrete (No. FHWA-HRT-06–103). 2006.

  22. ACI Committee 239. Ultra-high performance concrete. ACI Fall Convention. Toronto, Ontario, Canada; 2012.

  23. Vande Voort TL. Design and field testing of tapered H-shaped ultra high performance concrete piles. M.S. thesis, Iowa State University, Iowa; 2008.

  24. Yoo DY, Kim MJ. High energy absorbent ultra-high-performance concrete with hybrid steel and polyethylene fibers. Constr Build Mater. 2019;209:354–63.

    Article  Google Scholar 

  25. Yoo DY, Banthia N. Mechanical and structural behaviors of ultra-high-performance fiber-reinforced concrete subjected to impact and blast. Constr Build Mater. 2017;149:416–31.

    Article  Google Scholar 

  26. Yoo DY, Yoon YS. A review on structural behavior, design, and application of ultra-high-performance fiber-reinforced concrete. Int J Concr Struct Mater. 2016;10(2):125–42.

    Article  Google Scholar 

  27. Yoo DY, Kim S, Park GJ, Park JJ, Kim SW. Effects of fiber shape, aspect ratio, and volume fraction on flexural behavior of ultra-high-performance fiber-reinforced cement composites. Compos Struct. 2017;174:375–88.

    Article  Google Scholar 

  28. ASTM C1437. Standard test method for flow of hydraulic cement mortar. West Conshohocken: ASTM International; 2013. p. 1–2.

    Google Scholar 

  29. Graybeal BA. Flexural behavior of an ultrahigh-performance concrete I-girder. J Bridge Eng. 2008;13(6):602–10.

    Article  Google Scholar 

  30. Yoo DY, Kang ST, Yoon YS. Effect of fiber length and placement method on flexural behavior, tension-softening curve, and fiber distribution characteristics of UHPFRC. Constr Build Mater. 2014;64:67–81.

    Article  Google Scholar 

  31. Wang C, Li KZ, Li HJ, Jiao GS, Lu J, Hou DS. Effect of carbon fiber dispersion on the mechanical properties of carbon fiber-reinforced cement-based composites. Mater Sci Eng: A. 2008;487(1–2):52–7.

    Article  Google Scholar 

  32. Katz A, Li VC, Kazmer A. Bond properties of carbon fibers in cementitious matrix. J Mater Civ Eng. 1995;7(2):125–8.

    Article  Google Scholar 

  33. Wang DW, Feng LI, Min LIU, Cheng HM. Improved capacitance of SBA-15 templated mesoporous carbons after modification with nitric acid oxidation. New Carbon Mater. 2007;22(4):307–14.

    Article  Google Scholar 

  34. Jiang L, Wang J, Mao X, Xu X, Zhang B, Yang J, Wang Y, Zhu J, Hou S. High rate performance carbon nano-cages with oxygen-containing functional groups as supercapacitor electrode materials. Carbon. 2017;111:207–14.

    Article  Google Scholar 

  35. Paul CR. Introduction to electromagnetic compatibility. Hoboken: Wiley; 2006.

    Google Scholar 

  36. JSCE. Recommendations for design and construction of high performance fiber reinforced cement composites with multiple fine cracks (HPFRCC). Tokyo: Japan Society of Civil Engineers; 2008.

    Google Scholar 

  37. Kanakubo T. Tensile characteristics evaluation method for ductile fiber-reinforced cementitious composites. J Adv Concr Technol. 2006;4(1):3–17.

    Article  Google Scholar 

  38. Jung M, Lee YS, Hong SG. Effect of incident area size on estimation of EMI shielding effectiveness for ultra-high performance concrete with carbon nanotubes. IEEE Access. 2019;7:183105–17.

    Article  Google Scholar 

  39. Shahzad F, Kumar P, Yu S, Lee S, Kim YH, Hong SM, Koo CM. Sulfur-doped graphene laminates for EMI shielding applications. J Mater Chem C. 2015;3(38):9802–10.

    Article  Google Scholar 

  40. Luo S, Van Ooij WJ. Surface modification of textile fibers for improvement of adhesion to polymeric matrices: a review. J Adhes Sci Technol. 2002;16(13):1715–35.

    Article  Google Scholar 

  41. Yoo DY, Kim S, Kim MJ. Comparative shrinkage behavior of ultra-high-performance fiber-reinforced concrete under ambient and heat curing conditions. Constr Build Mater. 2018;162:406–19.

    Article  Google Scholar 

  42. Breuer S, Prutsch D, Ma Q, Epp V, Preishuber-Pflügl F, Tietz F, Wilkening M. Separating bulk from grain boundary Li ion conductivity in the sol–gel prepared solid electrolyte Li1.5Al0.5Ti1.5 (PO4)3. J Mater Chem A. 2015;3(42):21343–50.

    Article  Google Scholar 

  43. Neithalath N, Jain J. Applications of electrical impedance methods in linking structure of micro-and macro-porous concretes to their transport properties. In: ACI Spring 2010 convention, 2010, pp 33–50.

  44. Wansom S, Kidner NJ, Woo LY, Mason TO. AC-impedance response of multi-walled carbon nanotube/cement composites. Cem Concr Compos. 2006;28(6):509–19.

    Article  Google Scholar 

  45. Hixson AD, Woo LY, Campo MA, Mason TO, Garboczi EJ. Intrinsic conductivity of short conductive fibers in composites by impedance spectroscopy. J Electroceram. 2001;7(3):189–95.

    Article  Google Scholar 

  46. You I, Yoo DY, Kim S, Kim MJ, Zi G. Electrical and self-sensing properties of ultra-high-performance fiber-reinforced concrete with carbon nanotubes. Sensors. 2017;17(11):2481.

    Article  Google Scholar 

  47. Jou WS, Wu TL, Chiu SK, Cheng WH. Electromagnetic shielding of nylon-66 composites applied to laser modules. J Electron Mater. 2001;30(10):1287–93.

    Article  Google Scholar 

  48. Jou WS, Wu TL, Chiu SK, Cheng WH. The influence of fiber orientation on electromagnetic shielding in liquid-crystal polymers. J Electron Mater. 2002;31(3):178–84.

    Article  Google Scholar 

  49. Das NC, Liu Y, Yang K, Peng W, Maiti S, Wang H. Single-walled carbon nanotube/poly (methyl methacrylate) composites for electromagnetic interference shielding. Polym Eng Sci. 2009;49(8):1627–34.

    Article  Google Scholar 

  50. Al-Ghamdi AA, Al-Hartomy OA, El-Tantawy F, Yakuphanoglu F. Novel polyvinyl alcohol/silver hybrid nanocomposites for high performance electromagnetic wave shielding effectiveness. Microsyst Technol. 2015;21(4):859–68.

    Article  Google Scholar 

  51. Shukla V. Review of electromagnetic interference shielding materials fabricated by iron ingredients. Nanoscale Adv. 2019;1(5):1640–71.

    Article  Google Scholar 

Download references

Acknowledgements

This research was supported by a Grant (19SCIP-B146648-02) from the Construction Technology Research Project funded by the Ministry of Land, Infrastructure, and Transport of the Korean government.

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Yoo, DY., Kang, MC., Choi, HJ. et al. Influence of chemically treated carbon fibers on the electromagnetic shielding of ultra-high-performance fiber-reinforced concrete. Archiv.Civ.Mech.Eng 20, 123 (2020). https://doi.org/10.1007/s43452-020-00117-y

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  • DOI: https://doi.org/10.1007/s43452-020-00117-y

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