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The history of organoplatinum chemistry in Iran: 40-year research

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Abstract

This review article is based on the scientific investigations of Prof. Mehdi Rashidi during his working years in Shiraz University, Chemistry Department, Organometallic Chemistry Laboratory. Herein, we tried to overlook 40 years of his researches and intend to briefly point out all his publications during his research years. Prof. Rashidi’s researches were mostly focused on the synthesis and characterization of organoplatinum(II) and (IV) complexes having different applications. In this regard, he introduced many synthetic methods for new organoplatinum complexes mostly with the help of NMR spectroscopy and X-ray crystallography as characterization techniques. His researches were divided into some main themes like “substitution reactions,” “oxidative addition reactions,” “biological properties” and “photophysical properties” in organoplatinum chemistry. In this review article, the mentioned outlined items are briefly discussed as different areas of research that most of the contents are the outcomes of many Ph.D. and master theses. Besides, all the publications he authored are fully cited in the present review article.

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Abbreviations

ppy:

2-Phenylpyridinate

bzq:

Benzo[h]quinolinate

tpy:

2-(p-Tolyl)pyridinate

FDA:

Food and drug administration

HOR:

Hydrogen oxidation reaction

EOR:

Ethanol oxidation reaction

MOR:

Methanol oxidation reaction

ORR:

Oxygen reduction reaction

MLCT:

Metal-to-ligand charge transfer

ILCT:

Intraligand charge transfer

LC:

Ligand-centered

COD:

Cycloocta-1,5-diene

bpy:

2,2′-Bipyridine

phen:

1,10-Phentantroline

dppm:

1,1-Bis(diphenylphosphino)methane

dppe:

1,2-Bis(diphenylphosphino)ethane

dppa:

N,N-Bis(diphenylphosphino)amine

dppf:

1,1′-Bis(diphenylphosphino)ferrocene

dfppe:

1,2-Bis(bis(pentafluorophenyl)phosphine)ethane

KIE:

Kinetics isotope effect

SDS:

Sodium dodecyl sulfate

DFT:

Density functional theory

phpz:

1-Phenylpyrazolate

NMR:

Nuclear magnetic resonance

BSA:

Bovine serum albumin

HSA:

Human serum albumin

PTA:

1,3,5-Triaza-7-phosphaadamantane

EtB:

Ethidium bromides

CD:

Circular dichroism

CVD:

Chemical vapor deposition

PVP:

Polyvinylpyrrolidone

TEM:

Transmission electron microscope

SAED:

Selected area electron diffraction

RGO:

Reduced graphene oxide

XRD:

X-ray diffraction

dppp:

1,3-Bis(diphenylphosphino)propane

HOMO:

Highest occupied molecular orbital

LUMO:

Lowest unoccupied molecular orbital

MTO:

Methyltrioxorhenium

ECW:

Electrostatic-covalent model

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Acknowledgements

The authors are grateful for the dedicated efforts of the graduate students, co-workers and colleagues that have contributed to our research activities. This work is supported by Shiraz University and Iran Science Elites Federation Grant No. 97277.

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Authors and Affiliations

  1. Rashidi Laboratory of Organometallic Chemistry, Department of Chemistry, College of Sciences, Shiraz University, 71467-13565, Shiraz, Iran

    Reza Babadi Aghakhanpour, Sareh Paziresh, S. Masoud Nabavizadeh & S. Jafar Hoseini

  2. Department of Chemistry, Shiraz Branch, Islamic Azad University, 71993–37635, Shiraz, Iran

    Fatemeh Niroomand Hosseini

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  1. Reza Babadi Aghakhanpour
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  3. S. Masoud Nabavizadeh
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Correspondence to S. Masoud Nabavizadeh.

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Aghakhanpour, R.B., Paziresh, S., Nabavizadeh, S.M. et al. The history of organoplatinum chemistry in Iran: 40-year research. J IRAN CHEM SOC 17, 2683–2715 (2020). https://doi.org/10.1007/s13738-020-01892-4

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