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Chemiluminescent Reaction of N-Octyl Luminol with a Hypochlorite Ion in a Micellar Medium

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Abstract

We study the effect of surfactants having a different charge and length of the hydrocarbon radical on the intensity and kinetic laws of the model chemiluminescent reaction of a hydrophobic analogue of luminol, N-octyl luminol. The effect of the solution pH and the charge, structure, and concentration of surfactants on the intensity of the chemiluminescence is assessed, and the kinetic laws of the chemiluminescent reaction are determined.

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ACKNOWLEDGMENTS

The authors thank M.Ya. Melnikov for his valuable advice and recommendations on the design of the article.

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Authors and Affiliations

  1. Research and Technical Center of Radiation and Chemical Safety and Hygiene, Federal Medical-Biological Agency, 123182, Moscow, Russia

    T. V. Yankova

  2. MIREA—Russian Technological University, 119454, Moscow, Russia

    P. V. Melnikov & N. K. Zaytsev

Authors
  1. T. V. Yankova
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  2. P. V. Melnikov
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  3. N. K. Zaytsev
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Corresponding author

Correspondence to T. V. Yankova.

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The authors declare that they have no conflict of interest.

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Translated by O. Zhukova

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Yankova, T.V., Melnikov, P.V. & Zaytsev, N.K. Chemiluminescent Reaction of N-Octyl Luminol with a Hypochlorite Ion in a Micellar Medium. Moscow Univ. Chem. Bull. 75, 299–304 (2020). https://doi.org/10.3103/S0027131420050090

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  • DOI: https://doi.org/10.3103/S0027131420050090

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