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Features of Preparation of Multilayer Ultrathin Coatings from Thermosetting Epoxy Amine Systems by Spin-Coating Technique

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Abstract

The basic factors influencing the quality of thin films prepared by the spin-coating technique from thermosetting stoichiometric epoxy-amine mixtures have been studied. It has been shown that films 2.5–3.0 nm thick are formed on silicon supports from a 0.025 wt % solution of the stoichiometric mixture of epoxy resin and amine in toluene. Multilayer polymer coatings with thickness up to 40 nm have been prepared from successively deposited partially cured epoxy-amine layers. The thickness of these coatings grows linearly with an increase in the number of layers, while their surface energy decreases. The revealed features may be used for creating multilayer polymer coatings, the properties of which vary along the coating thickness.

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ACKNOWLEDGEMENTS

We are grateful to the Center for Collective Use of the Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Science, for the possibility to use the equipment in the experiments.

Funding

This work was supported by the Russian Science Foundation, project no. 18-79-00114.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    I. N. Senchikhin, A. V. Zaitseva, V. A. Zakharova & T. V. Kharitonova

  2. Russian Technological University MIREA, M. V. Lomonosov Institute of Fine Chemical Technologies, 119454, Moscow, Russia

    E. S. Zhavoronok

Authors
  1. I. N. Senchikhin
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  2. A. V. Zaitseva
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  3. V. A. Zakharova
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  4. T. V. Kharitonova
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  5. E. S. Zhavoronok
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Correspondence to I. N. Senchikhin.

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Translated by L. Tkachenko

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Senchikhin, I.N., Zaitseva, A.V., Zakharova, V.A. et al. Features of Preparation of Multilayer Ultrathin Coatings from Thermosetting Epoxy Amine Systems by Spin-Coating Technique. Colloid J 82, 584–591 (2020). https://doi.org/10.1134/S1061933X20050166

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  • DOI: https://doi.org/10.1134/S1061933X20050166

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