Abstract
This review considers the major approaches used in the application of coupling agents and lubricants onto fiber. It is shown that the use of lubricants and coupling agents in the matrix–filler system of carbon and glass fiber-reinforced plastics (GFRPs and CFRPs) provides the required level of interfacial interaction. For polymer composite materials, the maximum positive effect is achieved by controlling the ratio of the functional groups on the surface of the fiber. It has been found that nitrogen-containing modifiers should be used for the formation of the optimum composition of the surface of a fiber with the predominance of amino and hydroxyl groups. The considered methods of modification of the surface of the fiber will make it possible to improve the quality of the polymer composite materials being developed due to the increase in the adhesive interaction of their components.
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REFERENCES
Beider, E.Ya., Petrova, G.N., Izotova, T.F., and Barbot’ko, S.L., Glass reinforced plastics based on a thermoplastic matrix, Tr. Vseross. Nauchno-Issled. Inst. Aviats. Mater., 2013, no. 7, article no. 03.
Beider, E.Ya., Petrova, G.N., Izotova, T.F., and Gureeva, E.V., Thermoplastic composite materials and polyimide foams, Tr. Vseross. Nauchno-Issled. Inst. Aviats. Mater., 2013, no. 11, article no. 01.
Kablov, E.N., Innovative developments at the All-Russian Scientific Research Institute of Aviation Materials on implementing “Strategic Directions in the Development of Materials and Technologies for Processing Them for the Period until 2030”, Aviats. Mater. Tekhnol., 2015, no. 1 (34), pp. 3–33.
Gunyaev, G.M., Chursova, L.V., Komarova, O.A., and Gunyaeva, A.G., Structural carbon fiber reinforced plastics (CFRP) modified by nanoparticles, Aviats. Mater. Tekhnol., 2012, no. S, pp. 277–286.
Kablov, E.N., Aerospace materials science, Vse Mater., 2008, no. 3, pp. 2–14.
Sorokin, A.E., Beider, E.Ya., and Perfilova, D.N., Effect of climatic factors on the properties of a carbon fiber reinforced plastic based on a polyphenylene sulfide binding material, Tr. Vseross. Nauchno-Issled. Inst. Aviats. Mater., 2015, no. 1, article no. 10.
Kablov, E.N., Startsev, O.V., Deev, I.S., and Nikishin, E.F., Properties of polymeric composite materials after the effect of outer space in near-Earth orbits: Part 1, Vse Mater., 2012, no. 10, pp. 2–9.
Matveeva, I.G. and Lebedev, M.P., Polymer composite materials based on basalt, Theor. Found. Chem. Eng., 2018, vol. 52, pp. 670–672. https://doi.org/10.1134/S0040579518040206
Sidorov, D.V. and Shcherbakova, G.I., High-technology components of composite materials and special fibers for a wide range of applications, Khim. Tekhnol., 2016, vol. 17, no. 4, pp. 183–192.
Kerber, M.L., Vinogradov, V.M., Golovkin, G.S., Gorbatkina, Yu.A., Kryzhanovskii, V.K., Kuperman, A.M., Simonov-Emel’yanov, I.D., Khaliulin, V.I., and Bunakov, V.A., Polimernye kompozitsionnye materialy. Struktura. Svoistva. Tekhnologiya. Uchebnoe posobie (Polymeric Composite Materials: Structure, Properties, and Technology: A Textbook), St. Petersburg: Professiya, 2014, 4th ed.
Sharma, M., Gao, S., Mäder, E., Sharma, H., Wei, L.Y., and Bijwe, J., Carbon fiber surfaces and composite interphases, Compos. Sci. Technol., 2014, vol. 102, pp. 35–50. https://doi.org/10.1016/j.compscitech.2014.07.005
Mizerovskii, L.N., Improved spin finish for synthetic fibres: A new approach to solving the problem, Fibre Chem., 2000, vol. 32, no. 3, pp. 221–226. https://doi.org/10.1007/BF02361065
Golovkin, G.S., Specific features of the regulation of the mechanical properties of reinforced thermoplastics, Plast. Massy, 2008, no. 12, pp. 3–8.
Thomason, J.L. and Adzima, L.J., Sizing up the interphase: An insider’s guide to the science of sizing, Composites, Part A, 2001, vol. 32, nos. 3–4, pp. 313–321. https://doi.org/10.1016/S1359-835X(00)00124-X
Weitzsacker, C.L., Bellamy, M., and Sherwood, P.M.A., Studies of the effect of size on carbon fiber surfaces, J. Vac. Sci. Technol., A, 1994, vol. 12, no. 4, pp. 2392–2397. https://doi.org/10.1116/1.579220
Mizerovskii, L.N., Improved spin finish for synthetic fibres: A new approach to solving the problem, Fibre Chem., 2000, vol. 32, no. 3, pp. 221–226. https://doi.org/10.1007/BF02361065
Ivashchenko, E.A., Sizing and finishing agents for basalt and glass fibers, Theor. Found. Chem. Eng., 2009, vol. 43, pp. 511–516. https://doi.org/10.1134/S0040579509040277
Druzhinina, T.V., Grebennikov, S.F., Kharchenko, I.M., Kobrakov, K.I., and Efimenkov, R.G., The role of pyrolytic additives in the formation of the porous structure of activated carbon fibers, Khim. Tekhnol., 2009, vol. 10, no. 1, pp. 21–25.
Weitzsacker, C.L., Bellamy, M., and Sherwood, P.M.A., Studies of the effect of size on carbon fiber surfaces, J. Vac. Sci. Technol., A, 1994, vol. 12, no. 4, pp. 2392–2397. https://doi.org/10.1116/1.579220
Cheng, T.H, Zhang, J., Yumitori, S., Jones, F.R., and Anderson, C.W., Sizing resin structure and interphase formation in carbon fibre composites, Composites, 1994, vol. 25, no. 7, pp. 661–670. https://doi.org/10.1016/0010-4361(94)90199-6
Dai, Z., Zhang, B., Shi, F., Li, M., Zhang, Z., and Gu, Y., Chemical interaction between carbon fibers and surface sizing, J. App. Polym. Sci., 2012, vol. 124, no. 3, pp. 2127–2132. https://doi.org/10.1002/app.35226
Dilsiz, N. and Wightman, J.P., Surface analysis of unsized and sized carbon fibers, Carbon, 1999, vol. 37, no. 7, pp. 1105–1114. https://doi.org/10.1016/S0008-6223(98)00300-5
Dilsiz, N. and Wightman, J.P., Effect of acid–base properties of unsized and sized carbon fibers on fiber/epoxy matrix adhesion, Colloids Surf., A, 2000, vol. 164, nos. 2–3, pp. 325–336. https://doi.org/10.1016/S0927-7757(99)00400-8
Liu, J., Ge, H., Chen, J., Wang, D., and Liu, H., The preparation of emulsion type sizing agent for carbon fiber and the properties of carbon fiber/vinyl ester resin composites, J. App. Polym. Sci., 2012, vol. 124, no. 1, pp. 864–872. https://doi.org/10.1002/app.35126
Allred, R.E., Wesson, S.P., Shin, E.E., Inghram, L., McCorkle, L., Papadopoulos, D., Wheeler, D., and Sutter, J.K., The influence of sizings on the durability of high-temperature polymer composites, High Perform. Polym., 2003, vol. 15, no. 4, pp. 395–419. https://doi.org/10.1177/09540083030154002
Fernández, B., Arbelaiz, A., Valea, A., Mujika, F., and Mondragon, I., A comparative study on the influence of epoxy sizings on the mechanical performance of woven carbon fiber-epoxy composites, Polym. Compos., 2004, vol. 25, no. 3, pp. 319–330. https://doi.org/10.1002/pc.20026
Jones, F.R., The chemical aspects of fibre surfaces and composite interfaces and interphases, and their influence on the mechanical behaviour of interfaces, Proc. 28th Risø International Symposium on Materials Science “Interface Design of Polymer Matrix Composites – Mechanics, Chemistry, Modelling and Manufacturing”, Sørensen, B.F., Mikkelsen, L.P., Lilholt, H., Goutianos, S., and Abdul-Mahdi, F.S., Eds., Roskilde: Risø National Laboratory, 2007, pp. 21–44.
Jones, F.R., A review of interphase formation and design in fibre-reinforced composites, J. Adhes. Sci. Technol., 2010, vol. 24, no. 1, pp. 171–202. https://doi.org/10.1163/016942409X12579497420609
Yumitori, S., Wang, D., and Jones, F.R., The role of sizing resins in carbon fibre-reinforced polyethersulfone (PES), Composites, 1994, vol. 25, no. 7, pp. 698–705. https://doi.org/10.1016/0010-4361(94)90204-6
Clarke, W.A. and Eitman, D.A., US Patent 5562966, 1996.
Kettle, A.P., Beck, A.J., O’Toole, L., Jones, F.R., and Short, R.D., Plasma polymerisation for molecular engineering of carbon-fibre surfaces for optimized composites, Compos. Sci. Technol., 1997, vol. 57, no. 8, pp. 1023–1032. https://doi.org/10.1016/S0266-3538(96)00162-5
Zinger, B., Shkolnik, S., and Höcker, H., Electrocoating of carbon fibres with polyaniline and poly(hydroxyalkyl methacrylates), Polymer, 1989, vol. 30, no. 4, pp. 628–635. https://doi.org/10.1016/0032-3861(89)90146-8
Huang, S., Huang, B., Zhou, K., and Li, Z., Effects of coatings on the mechanical properties of carbon fiber reinforced HAP composites, Mater. Lett., 2004, vol. 58, pp. 3582–3585. https://doi.org/10.1016/j.matlet.2004.05.086
Li, J., Fan, Q., Chen, Z.H., Huang, K.B., and Cheng, Y.L., Effect of electropolymer sizing of carbon fiber on mechanical properties of phenolic resin composites, Trans. Nonferrous Met. Soc. China, 2006, vol. 16, suppl. 2, pp. s457–s461. https://doi.org/10.1016/S1003-6326(06)60233-1
Zhang, C.H., Zhang, Z.Q., and Cao, H.L., Effects of epoxy/SiO2 hybrid sizing on the mechanical properties of carbon fiber composites, Solid State Phenom., 2007, vols. 121–123, pp. 1253–1256. https://doi.org/10.4028/www.scientific.net/SSP.121-123.1253
Liu, W.B., Zhang, S., Hao, L.F., Jiao, W.C., Yang, F., Li, X.F., and Wang, R.G., Properties of carbon fiber sized with poly(phthalazinone ether ketone) resin, J. App. Polym. Sci., 2013, vol. 128, no. 6, pp. 3702–3709. https://doi.org/10.1002/app.38605
Drzal, L.T. and Raghavendran, V.K., Adhesion of thermoplastic matrices to carbon fibers: Effect of polymer molecular weight and fiber surface chemistry, J. Thermoplast. Compos. Mater., 2003, vol. 16, no. 1, pp. 21–30. https://doi.org/10.1177/0892705703016001209
Ershov, I.P., Zenitova, L.A., Sergeeva, E.A., and Abdullin, I.Sh., Selective removal of the components of a sizing formulation from the surface of fiberglass, Vestn. Tekhnol. Univ., 2015, vol. 18, no. 7179, p. 180.
Shershneva, I.N., Lesnichaya, V.A., Muradyan, V.E., and Smirnov, Yu.N., Study of the effect of polymeric sizing formulations on the physicomechanical properties of glass-reinforced plastics based on thermoplastic matrices, Plast. Massy, 2012, no. 11, pp. 45–51.
Gashnikova, G.Yu., Aretemenko, S.E., Nikulina, L.P., and Gorokhovskii, A.V., Modification of filler as a method for targeted regulation of the properties of glass-filled polyvinyl butyral, Plast. Massy, 2001, no. 2, p. 10.
Pukánszky, B., Interfaces and interphases in multicomponent materials: Past, present, future, Eur. Polym. J., 2005, vol. 41, no. 4, pp. 645–662. https://doi.org/10.1016/j.eurpolymj.2004.10.035
Kopylov, V.M., Ivanov, V.V., and Kovyazin, V.A., Silane coupling agents, Vse Mater., 2007, no. 3, pp. 23–31.
Kopylov, V.M., Ivanov, V.V., and Kovyazin, V.A., Silane coupling agents: A conclusion, Vse Mater., 2007, no. 4, pp. 18–20.
Zelenetskii, A.N., Gorbatkina, Yu.A., Kuperman, A.M., Pirogov, O.N., Tovmasyan, M.A., Denisov, K.A., and Vasil’ev, I.A., Study of the modification of the surface of glass fibers by silane coupling agents and its effect on the strength of the interface and the properties of polypropylene glass-reinforced plastics, Vysokomol. Soedin., Ser. A Ser. B, 1995, vol. 37, no. 5, pp. 775–780.
Arkles, B., Silane Coupling Agents: Connecting Across Boundaries, Morrisville, Pa.: Gelest, 2006, 2nd ed.
Ishida, H., A review of recent progress in the studies of molecular and microstructure of coupling agents and their functions in composites, coatings and adhesive joints, Polym. Compos., 1984, vol. 5, no. 2, pp. 101–123. https://doi.org/10.1002/pc.750050202
Bigg, D.M., Effect of compounding on the properties of short fiber reinforced injection moldable thermoplastic composites, Polym. Compos., 1985, vol. 6, no. 1, pp. 20–28. https://doi.org/10.1002/pc.750060105
Li, C. and Liu, X., Mechanical and thermal properties study of glass fiber reinforced polyarylene ether nitriles, Mater. Lett., 2007, vol. 61, nos. 11–12, pp. 2239–2242. https://doi.org/10.1016/j.matlet.2006.08.055
Beider, E.Ya., Petrova, G.N., and Izotova, T.F., Effect of sizing formulations on the properties of glass fiber reinforced thermoplastics, Tr. Vseross. Nauchno-Issled. Inst. Aviats. Mater., 2014, no. 9, article no. 07.
Li, J., Effect of silane coupling agent on the tensile properties of carbon fiber-reinforced thermoplastic polyimide composites, Polym.-Plast. Technol. Eng., 2010, vol. 49, no. 4, pp. 337–340. https://doi.org/10.1080/03602550903414001
Chuang, S.L., Chu, N.-J., and Whang, W.T., Effect of polyamic acids on interfacial shear strength in carbon fiber/aromatic thermoplastics, J. App. Polym. Sci., 1990, vol. 41, nos. 1–2, pp. 373–382. https://doi.org/10.1002/app.1990.070410129
Beider, E.Ya., Petrova, G.N., and Dykun, M.I., Sizing of carbon fibers as fillers for carbon fiber reinforced thermoplastics, Tr. Vseross. Nauchno-Issled. Inst. Aviats. Mater., 2014, no. 10, article no. 03.
Yuan, H., Zhang, S., Lu, C., He, S., and An, F., Improved interfacial adhesion in carbon fiber/polyether sulfone composites through an organic solvent-free polyamic acid sizing, Appl. Surf. Sci., 2013, vol. 279, pp. 279–284. https://doi.org/10.1016/j.apsusc.2013.04.085
Giraud, I., Franceschi-Messant, S., Perez, E., Lacabanne, C., and Dantras, E., Preparation of aqueous dispersion of thermoplastic sizing agent for carbon fiber by emulsion/solvent evaporation, Appl. Surf. Sci., 2013, vol. 266, pp. 94–99. https://doi.org/10.1016/j.apsusc.2012.11.098
Zhang, X., Pei, X., Jia, Q., and Wang, Q., Effects of carbon fiber surface treatment on the tribological properties of 2D woven carbon fabric/polyimide composites, Appl. Phys. A: Mater. Sci. Process., 2009, vol. 95, pp. 793–799. https://doi.org/10.1007/s00339-009-5073-x
Novikova, O.A. and Serov, V.P., Modifikatsiya poverkhnosti armiruyushchikh volokon v kompozitsionnykh materialakh (Modification of the Surface of Reinforcing Fibers in Composite Materials), Kiev: Naukova Dumka, 1989.
Raghavendran, V.K. and Drzal, L.T., Fiber-matrix interfacial adhesion improvement in carbon fiber-bisphenol-A polycarbonate composites by polymer grafting, J. Adhes., 2002, vol. 78, no. 10, pp. 895–922. https://doi.org/10.1080/00218460214096
He, X., Zhang, F., Wang, R., and Liu, W., Preparation of a carbon nanotube/carbon fiber multi-scale reinforcement by grafting multi-walled carbon nanotubes onto the fibers, Carbon, 2007, vol. 45, no. 13, pp. 2559–2563. https://doi.org/10.1016/j.carbon.2007.08.018
Peng, Q., He, X., Li, Y., Wang, C., Wang, R., Hu, P., Yan, Y., and Sritharan, T., Chemically and uniformly grafting carbon nanotubes onto carbon fibers by poly(amidoamine) for enhancing interfacial strength in carbon fiber composites, J. Mater. Chem., 2012, vol. 22, no. 13, pp. 5928–5931. https://doi.org/10.1039/C2JM16723A
Thostenson, E.T. and Chou, T.-W., Aligned multi-walled carbon nanotube-reinforced composites: Processing and mechanical characterization, J. Phys. D: Appl. Phys., 2002, vol. 35, no. 16, pp. L77–L80. https://doi.org/10.1088/0022-3727/35/16/103
Liu, H., Li, J., Liu, X., and Jiang, S., A novel multiwalled carbon nanotubes bonded fused-silica fiber for solid phase microextraction–gas chromatographic analysis of phenols in water samples, Talanta, 2009, vol. 78, no. 3, pp. 929–935. https://doi.org/10.1016/j.talanta.2008.12.061
Zhao, F. and Huang, Y., Grafting of polyhedral oligomeric silsesquioxanes on a carbon fiber surface: Novel coupling agents for fiber/polymer matrix composites, J. Mater. Chem., 2011, vol. 21, no. 11, pp. 3695–3703. https://doi.org/10.1039/C0JM03128C
Functional Fillers for Plastics, Xanthos, M., Ed., Weinheim: Wiley-VCH, 2005.
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This work was performed as part of integrated scientific direction 13.2 “Structural Polymer CMs” (Strategic Directions in the Development of Materials and Technologies for Processing Them for the Period until 2030) [3].
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Sorokin, A.E., Petrova, G.N. Lubricants and Coupling Agents in the Processes of the Liquid-Phase Modification of the Surface of Carbon and Glass Fiber Fillers in the Production of Structural Materials: A Review. Theor Found Chem Eng 54, 737–744 (2020). https://doi.org/10.1134/S0040579520040120
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DOI: https://doi.org/10.1134/S0040579520040120