Abstract
The catalytic system N-hydroxyphthalimide–Fe(III) is used for the first time in the aerobic oxidation of alkylbenzenes to the corresponding hydroperoxides. It is shown that micro amounts of Fe(асас)3 or Fe(benz)3 increase the efficiency of radical catalyst N-hydroxyphthalimide; as a result, hydroperoxidation of ethylbenzene and isopropylbenzene proceeds at temperatures of 90–100 and 60°C, respectively, instead of in the temperature range of 150–120°C typical of noncatalytic synthesis. At substrate conversion of 10–20%, the selectivity for hydroperoxides remains at the level of 90–95%. Further successful tests of the obtained solutions in the MoO3/SiO2-catalyzed epoxidation of olefins without prior removal of the catalytic system components show the promise of using this low-temperature synthesis of hydroperoxides as the initial stage of olefin epoxidation.
Similar content being viewed by others
REFERENCES
Tolstikov, G.A., Reaktsii gidroperekisnogo okisleniya (Hydropeoxidation Reactions), Moscow: Nauka, 1976.
Sheldon, R.A., J. Mol. Catal., 1980, vol. 7, no. 1, pp. 107–126.
US Patent 3351635, 1967.
Paushkin, Ya.M., Adel’son, S.V., and Vishnyakova, T.P., Tekhnologiya neftekhimicheskogo sinteza (Technology of Petrochemical Synthesis), Moscow: Khimiya, 1973, part 1.
Buijink, J.K.F., Lange, J.-P., Bos, A.N.R., Horton, A.D., and Niele, F.G.M., in Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis, Oyama, S.T., Ed., Amsterdam: Elsevier, 2008, ch. 13, pp. 355–371.
Toribio, P.P., Gimeno-Gargallo, A., Capel-Sanchez, M.C., de Frutos, M.P., Campos-Martin, J.M., and Fierro, J.L.G., Appl. Catal., A, 2009, vol. 363, nos. 1–2, pp. 32–39.
Kurganova, E.A., Selective aerobic oxidation of arylarenes to hydroperoxides in the presence of phthalimide catalysts, Doctoral. (Chem.) Dissertation, Yaroslavl: Yarosl. State Techn. Univ., 2017.
Carrara, N., Badano, J.M., Betti, C., Lederhos, C., Busto, M., Vera, C., and Quiroga, M., in New Advances in Hydrogenation Processes—Fundamentals and Applications, Ravanchi, M.T., Ed., London: Intech, 2017, ch. 9. https://pdfs.semanticscholar.org/3dda/ 3aeed3cd8ebad74f07b846a9612e9b0e1aa0.pdf?_ga=2. 64257711.1676827604.1594567511-371476595.1592594199. Cited July 13, 2020.
Sheldon, R.A. and Arends, I.W.C.E., J. Mol. Catal. A: Chem., 2006, vol. 251, nos. 1–2, pp. 200–214.
Tsyskovskii, V.K., Prokof’ev, B.K., Pyl’nikov, V.I., Shcheglova, Ts.N., and Kopalkina, L.N., Zh. Prikl. Khim., 1974, vol. 47, no. 5, pp. 1112–1117.
Kharlampidi, Kh.E., Nurullina, N.M., Batyrshin, N.N., and Usmanova, Yu.Kh., Kinet. Catal., 2018, vol. 59, no. 3, pp. 328–332.
Ishii, Y. and Sakaguchi, S., Catal. Today, 2006, vol. 117, nos. 1–3, pp. 105–113.
Kurganova, E.A. and Koshel’, G.N., Ross. Khim. Zh., 2014, vol. 58, nos. 3–4, pp. 91–102.
Kurganova, E.A., Dakhnavi, E.M., and Koshel’, G.N., Pet. Chem., 2017, vol. 57, no. 3, pp. 262–266.
Sapunov, V.N., Kurganova, E.A., and Koshel, G.N., Int. J. Chem. Kinet., 2018, vol. 50, no. 1, pp. 3–14.
Kuznetsova, N.I., Kuznetsova, L.I., Yakovina, O.A., Karmadonova, I.E., and Bal’zhinimaev, B.S., J. Catal. Lett., 2020, vol. 150, no. 4, pp. 1020–1027. https://doi.org/10.1007/s10562-019-02999-x
Melone, L. and Punta, C., Beilstein J. Org. Chem., 2013, vol. 9, no. 1, pp. 1296–1310.
Arends, I.W.C.E., Sasidharan, M., Kühnle, A., Duda, M., Jost, C., and Sheldon, R.A., Tetrahedron, 2002, vol. 58, no. 44, pp. 9055–9061.
Orlińska, B. and Zawadiak, J., React. Kinet., Mech. Catal., 2013, vol. 110, pp. 15–30.
Dobras, G. and Orlińska, B., Appl. Catal., A, 2018, vol. 561, pp. 59–67.
Melone, L., Franchi, P., Lucarini, M., and Punta, C., Adv. Synth. Catal., 2013, vol. 355, no. 16, pp. 3210–3220.
Elimanova, G.G., Batyrshin, N.N., and Kharlampidi, Kh.E., Kinet. Catal., 2017, vol. 58, no. 1, pp. 46–50.
Shen, K., Liu, X., Lu, G., Miao, Y., Guo, Y., Wang, Y., and Guo, Y., J. Mol. Catal. A: Chem., 2013, vol. 373, pp. 78–84.
Farzaneh, F., Zamanifar, E., and Williams, C.D., J. Mol. Catal. A: Chem., 2004, vol. 218, no. 2, pp. 203–209.
Lin, K., Pescarmona, P.P., Houthoofd, K., Liang, D., Van Tendeloo, G., and Jacobs, P.A., J. Catal., 2009, vol. 263, no. 1, pp. 75–82.
Rekkab-Hammoumraoui, I., Khaldi, I., Choukchou-Braham, A., and Bachir, R., Res. J. Pharm., Biol. Chem. Sci., 2013, vol. 4, pp. 935–946.
Khare, S. and Shrivastava, S., J. Mol. Catal. A: Chem., 2004, vol. 217, nos. 1–2, pp. 51–58.
Zhang, X., Huang, Y., Guo, Y., Yuan, X., and Jiao, F., Microporous Mesoporous Mater., 2018, vol. 262, pp. 251–257.
Liu, J., Fang, S., Jian, R., Wu, F., and Jian, P., Powder Technol., 2018, vol. 329, pp. 19–24.
Miao, Y., Lu, G., Liu, X., Guo, Y., Wang, Y., and Guo, Y., J. Ind. Eng. Chem., 2010, vol. 16, no. 1, pp. 45–50.
Li, K.-T., Lin, C.-C., and Lin, P.-H., in Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis, Oyama, S.T., Ed., Amsterdam: Elsevier, 2008, ch. 14, pp. 373–386.
Funding
This work was performed as part of a State Task for Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, project no. AAAA-A17-117041710083-5. It was supported by the Russian Foundation for Basic Research and the Government of Novosibirsk oblast, project no. 19-43-540008.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by G. Levit
Rights and permissions
About this article
Cite this article
Karmadonova, I.E., Zudin, V.N., Kuznetsova, N.I. et al. Preparation of Ethylbenzene and Isopropylbenzene Hydroperoxides in the N-Hydroxyphthalimide–Fe(III) Homogeneous Catalytic System and Use of Solutions in the Epoxidation of Olefins. Catal. Ind. 12, 216–225 (2020). https://doi.org/10.1134/S2070050420030058
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070050420030058