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Corrosion Control of Mild Steel Material in HCl Electrolyte by a Non-Steroidal Anti-Inflammatory Drug: Electrochemical and Kinetic Study

  • PHYSICOCHEMICAL PROBLEMS OF MATERIALS PROTECTION
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Abstract

The corrosion inhibition of mild steel by a drug substance, namely piroxicam, in HCl (1 M) solution was investigated. The Electrochemical Impedance Spectroscopy (EIS) and potentiodynamic polarization technique were used. EIS measurements showed larger capacitive loops in the presence of piroxicam. The inhibition efficiency was found to be dependent on the piroxicam concentration. From the polarization curves the corrosion current density (\({{i}_{{{\text{cor}}}}}\)) decreased from 109.4 to 16.93 μA/cm2. The adsorption mode of the drug obeys to the Langmuir isotherm model. The free energy of adsorption (∆Gads) revealed a spontaneous process with a mixed interaction type i.e. physical and chemical. The kinetic study was conducted using the weight loss technique at the optimal piroxicam concentration (600 ppm). The density functional theory (DFT) method was used to determine the principal species, neutral or ionized drug, involved the inhibition mechanism. Scanning electron microscopy (SEM) was carried out for the surface characterization of the carbon steel after immersion in the aggressive medium in the absence and presence of the drug substance.

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REFERENCES

  1. Sastri, V.S., Challenges in Corrosion: Costs, Causes, Consequences and Control, Hoboken, NJ: John Wiley and Sons, 2015.

    Book  Google Scholar 

  2. Carneiro, J., Tedim, J., and Ferreira, M.G.S., Prog. Org. Coat., 2015, vol. 89, pp. 348–356.

    Article  CAS  Google Scholar 

  3. Finšgar, M. and Jackson, J., Corros. Sci., 2014, vol. 86, pp. 17–41.

    Article  CAS  Google Scholar 

  4. Vazirinasab, E., Jafari, R., and Momen, G., Surf. Coat. Technol., 2017, vol. 341, pp. 40−56.

    Article  CAS  Google Scholar 

  5. Chafai. N., Chafaa. S., Benbouguerra. K., et al., J. Taiwan Inst. Chem. Eng., 2017, vol. 70, pp. 331–344.

    Article  CAS  Google Scholar 

  6. Lebrini, M., Robert, F., Vezin, H., and Roos, C., Corros. Sci., 2010, vol. 52, pp. 3367–3376.

    Article  CAS  Google Scholar 

  7. Zhang, S., Tao, Z., Li, W., and Hou, B., Appl. Surf. Sci., 2009, vol. 255, pp. 6757–6763.

    Article  CAS  Google Scholar 

  8. Vračar, L.M. and Dražić, D.M., Corros. Sci., 2002, vol. 44, pp. 1669–1680.

    Article  Google Scholar 

  9. Bahrami, M.J., Hosseini, S.M.A., and Pilvar, P., Corros. Sci., 2010, vol. 52, pp. 2793–2803.

    Article  CAS  Google Scholar 

  10. Wang, D., Xiang, B., Liang, Y., et al., Corros. Sci., 2014, vol. 85, pp. 77–86.

    Article  CAS  Google Scholar 

  11. Pavithra, M.K., Venkatesha, T.V., Punith Kumar, M.K., and Tondan, H.C., Corros. Sci., 2012, vol. 60, pp. 104–111.

    Article  CAS  Google Scholar 

  12. Gece, G., Corros. Sci., 2011, vol. 53, pp. 3873–3898.

    Article  CAS  Google Scholar 

  13. Golestani, G., Shahidi, M., and Ghazanfari, D., Appl. Surf. Sci., 2014, vol. 308, pp. 347–362.

    Article  CAS  Google Scholar 

  14. Eddy, N.O., Odoemelam, S.A., Ogoko, E.C., and Ita, B.I., Port. Electrochim. Acta, 2010, vol. 28, pp. 15–26.

    Article  CAS  Google Scholar 

  15. Shukla, S.K. and Quraishi, M.A., Corros. Sci., 2010, vol. 52, pp. 314–321.

    Article  CAS  Google Scholar 

  16. Obot, I.B. and Obi-Egbedi, N.O., Colloids Surf., A, 2008, vol. 330, pp. 207–212.

    Article  CAS  Google Scholar 

  17. Oguzie, E.E., Okolue, B.N., Ebenso, E.E., et al., Mater. Chem. Phys., 2004, vol. 87, pp. 394–401.

    Article  CAS  Google Scholar 

  18. Nouri, P.M. and Attar, M.M., Chem. Eng. Commun., 2016, vol. 203, pp. 505–515.

    Article  CAS  Google Scholar 

  19. Prabakaran, M., Kim, S.-H., Hemapriya, V., and Chung, I.-M., J. Ind. Eng. Chem., 2016, vol. 37, pp. 47–56.

    Article  CAS  Google Scholar 

  20. Bouklah, M., Hammouti, B., Lagrenée, M., and Bentiss, F., Corros. Sci., 2006, vol. 48, pp. 2831–2842.

    Article  CAS  Google Scholar 

  21. Fukui, K., Science, 1982, vol. 218, pp. 747–754.

    Article  CAS  Google Scholar 

  22. Orazem, M.E. and Tribollet, B., Corrosion, 2017, vol. 57, pp. 747–748.

    Google Scholar 

  23. Hsu, C.H., Mansfeld, F., Corrosion, 2001, vol. 57, pp. 747–748.

  24. Bentiss, F., Traisnel, M., and Lagrenee, M., Corros. Sci., 2000, vol. 42, pp. 127–146.

    Article  CAS  Google Scholar 

  25. Behpour, M., Ghoreishi, S.M., Mohammadi, N., and Salavati-Niasari, M., Corros. Sci., 2011, vol. 53, pp. 3380–3387.

    Article  CAS  Google Scholar 

  26. Li, X., Deng, S., and Fu, H., Corros. Sci., 2011, vol. 53, pp. 302–309.

    Article  CAS  Google Scholar 

  27. Obot, I.B., Ebenso, E.E., and Kabanda, M.M., J. Environ. Chem. Eng., 2013, vol. 1, pp. 431–439.

    Article  CAS  Google Scholar 

  28. Parr, R.G. and Pearson, R.G., J. Am. Chem. Soc., 1983, vol. 105, pp. 7512–7516.

    Article  CAS  Google Scholar 

  29. Koopmans, T., Physica, 1933, vol. 1, pp. 104–113.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Sciences, University of Algiers 1 Benyoucef Benkhedda, 16002, Algiers, Algeria

    Azeddine Addoun

  2. Laboratory of Chromatography, Faculty of Chemistry, USTHB, BP 32 El Alia, 16111, Algiers, Algeria

    Azeddine Addoun & Ouassila Ferroukhi

  3. Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry, USTHB, BP 32 El Alia, 16111, Algiers, Algeria

    Mohamed Trari

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  1. Azeddine Addoun
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  2. Mohamed Trari
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  3. Ouassila Ferroukhi
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Correspondence to Azeddine Addoun.

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Addoun, A., Trari, M. & Ferroukhi, O. Corrosion Control of Mild Steel Material in HCl Electrolyte by a Non-Steroidal Anti-Inflammatory Drug: Electrochemical and Kinetic Study. Prot Met Phys Chem Surf 56, 826–833 (2020). https://doi.org/10.1134/S2070205120040024

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  • DOI: https://doi.org/10.1134/S2070205120040024

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