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Neutrals influence on the water resistance coefficient of phenol-formaldehyde resin modified by wood pyrolysis liquid products

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Abstract

This article presents the results of the investigation of the properties of phenol-formaldehyde resin, obtained using the phenol-replacing fraction. A two-step method was developed for phenol-replacing fraction separation from liquid pyrolysis products with a yield up to 15%, and this fraction was used in the phenol-formaldehyde resin synthesis. Then, a work was conducted for the removal of neutrals from the modified phenol-formaldehyde resin with organic solvents, n-hexane and benzene. As a result, benzene was defined as a more efficient solvent because it removed more aromatics, like ethers and substituted phenols, that cannot react and worsen the glue line water resistance. Benzene dissolved 3.2% weight of the resin, and n-hexane dissolved 2.5% weight. The removal of neutrals increased the water resistance coefficient by more than 60%, so neutrals have a considerable effect on the resin properties. The results can be used for production of resin from renewable feedstock with the similar properties with the traditional resin.

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Authors and Affiliations

  1. Kazan National Research Technological University, 68 Marks str, Kazan, Russia

    Sergey Zabelkin, Aygul Valeeva, Almira Sabirzyanova, Andrey Grachev & Vladimir Bashkirov

  2. EnergoLesProm LLC, 1/47 Nigmatullin str., of. 116, Kazan, Russia

    Sergey Zabelkin & Andrey Grachev

Authors
  1. Sergey Zabelkin
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  2. Aygul Valeeva
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  3. Almira Sabirzyanova
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  5. Vladimir Bashkirov
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Correspondence to Sergey Zabelkin.

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Zabelkin, S., Valeeva, A., Sabirzyanova, A. et al. Neutrals influence on the water resistance coefficient of phenol-formaldehyde resin modified by wood pyrolysis liquid products. Biomass Conv. Bioref. 12, 5563–5570 (2022). https://doi.org/10.1007/s13399-020-01025-0

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  • DOI: https://doi.org/10.1007/s13399-020-01025-0

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