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Features of Formation of Mononuclear and Binuclear Copper(II) Complexes with 2,2'-Bipyridyl and closo-Decaborate Anion

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Abstract

The copper(I) complexation reaction with 2,2'-bipyridyl in the presence of salts of the closo-deca-borate anion has been studied in air in organic solvents (1,2-dichloroethane and DMF). It has been found that, as a result of the redox reaction, copper(II) coordination compounds with the [B10H10]2– anion and 2,2'-bipy-ridyl anion are prepared from known copper(I) complex [\({\text{Cu}}_{2}^{{\text{I}}}\)(Bipy)2[B10H10]] formed in situ. It has been shown that the reaction conditions (the process temperature and solvent nature) have a significant effect on the reaction path and, accordingly, on the composition and structure of the resulting complexes. Mono- and binuclear Cu(II) complexes [CuII(Bipy)2Cl]2[B10H10] and {[\({\text{Cu}}_{2}^{{{\text{II}}}}\)(Bipy)2(μ-OH)2][B10H10]} have been isolated and chara-cterized. According to X-ray diffraction, the structure of complex {[\({\text{Cu}}_{2}^{{{\text{II}}}}\)(Bipy)2(μ-OH)2][B10H10]} contains long Cu…H(B) contacts between the closo-decaborate anion and the metal atom.

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Funding

This work was carried out as part of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    E. A. Malinina, V. V. Avdeeva, S. E. Korolenko, S. E. Nefedov, L. V. Goeva & N. T. Kuznetsov

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  1. E. A. Malinina
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  2. V. V. Avdeeva
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  3. S. E. Korolenko
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  4. S. E. Nefedov
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Correspondence to S. E. Korolenko.

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Translated by V. Avdeeva

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Malinina, E.A., Avdeeva, V.V., Korolenko, S.E. et al. Features of Formation of Mononuclear and Binuclear Copper(II) Complexes with 2,2'-Bipyridyl and closo-Decaborate Anion. Russ. J. Inorg. Chem. 65, 1343–1350 (2020). https://doi.org/10.1134/S0036023620090119

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