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Cyclohexene Epoxidation Catalysts Based on Porous Aromatic Frameworks

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Abstract

Molybdenum and tungsten catalysts, PAF-30-Mo and PAF-30-W, synthesized based on a porous aromatic framework PAF-30 have been tested in the epoxidation of cyclohexene with tert-butyl hydroperoxide. The influence of the temperature and the substrate to oxidant ratio on the characteristic features of the process has been studied. It has been shown that the catalysts exhibit high activity and make it possible to obtain cyclohexene epoxide in a high yield; however, they lose their activity over time due to the leaching of the metal from the pores of the polymer.

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Funding

This study was supported by the Russian Foundation for Basic Research (project no. 18-33-20069).

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    L. A. Kulikov, V. A. Yarchak, A. V. Zolotukhina, A. L. Maksimov & E. A. Karakhanov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. V. Zolotukhina & A. L. Maksimov

Authors
  1. L. A. Kulikov
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  2. V. A. Yarchak
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  3. A. V. Zolotukhina
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  4. A. L. Maksimov
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  5. E. A. Karakhanov
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Corresponding author

Correspondence to L. A. Kulikov.

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CONFLICT OF INTEREST

A.L. Maksimov is the editor-in-chief of the Neftekhimiya (Petroleum Chemistry) journal. The other authors declare that they have no conflict of interest.

AUTHOR INFORMATION

L.A. Kulikov, ORCID: https://orcid.org/0000-0002-7665-5404

V.A. Yarchak, ORCID: https://orcid.org/0000-0003-4986-0549

A.V. Zolotukhina, ORCID: https://orcid.org/0000-0002-0797-0611

A.L. Maksimov, Dr. Sci. (Chem.), prof., ORCID: https://orcid.org/0000-0001-9297-4950

E.A. Karakhanov, Dr. Sci. (Chem.), prof., ORCID: https://orcid.org/0000-0003-4727-954X

Additional information

Translated by E. Boltukhina

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Kulikov, L.A., Yarchak, V.A., Zolotukhina, A.V. et al. Cyclohexene Epoxidation Catalysts Based on Porous Aromatic Frameworks. Pet. Chem. 60, 1087–1093 (2020). https://doi.org/10.1134/S0965544120090169

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  • DOI: https://doi.org/10.1134/S0965544120090169

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