Abstract
Results of a single-stage heterogeneous catalytic synthesis of zingerone and dehydrozingerone have been described. The prospects of the proposed approach have been shown; the main kinetic laws governing the reaction have been revealed. Optimum conditions for zingerone and dehydrozingerone synthesis providing a yield of the target products of 45.8 and 76.2%, respectively, have been found.
Similar content being viewed by others
REFERENCES
N. S. Mashhadi, R. Ghiasvand, G. Askari, et al., Int. J. Prev. Med. 4, 36 (2013).
L. A. Svetaz, M. G. Di Liberto, M. M. Zanardi, et al., Int. J. Mol. Sci. 15, 22 042 (2014).
S. L. Bhanawase and G. D. Yadav, Curr. Catal. 6, 105 (2017).
S. G. Shin, J. Y. Kim, H. Y. Chung, and J. C. Jeong, J. Agricul. Food Chem. 53, 7617 (2005).
V. Mani, S. Arivalagan, A. I. Siddique, and N. Namasivayam, Mol. Cell. Biochem. 421, 169 (2016).
J. C. Chen, L. J. Huang, S. L. Wu, et al., J. Agricul. Food Chem. 55, 8390 (2007).
H. Nomura, J. Chem. Soc. Trans. 111, 769 (1917).
P. Van der Schaft, Flavour Development, Analysis and Perception in Food and Beverages, Ed. by J. K. Parker, J. S. Elmore, and L. Methven (Elsevier–WP, Amsterdam, 2015), p. 235.
Z. Wang, G. Yin, J. Qin, et al., Synthesis 2008, 3675 (2008).
A. V. Chistyakov, P. A. Zharova, S. A. Nikolaev, and M. V. Tsodikov, Catal. Today 279, 124, (2017).
A. V. Chistyakov, S. A. Nikolaev, P. A. Zharova, et al., Energy 166, 569 (2019).
P. A. Zharova, A. V. Chistyakov, M. V. Tsodikov, et al., Chem. Eng. Trans. 57, 31 (2017).
P. A. Zharova, A. V. Chistyakov, M. V. Tsodikov, et al., Chem. Eng. Trans. 50, 295 (2016).
E. F. Iliopoulou, E. V. Antonakou, S. A. Karakoulia, et al., Chem. Eng. J. 134, 51 (2007).
R. Kumar, S. Sithambaram, and S. L. Suib, J. Catal. 262, 304 (2009).
H. A. Benesi and B. H. C. Winquist, Surface Acidity of Solid Catalysts (Academic, New York, 1978).
O. G. Ellert, M. V. Tsodikov, S. A. Nikolaev, and V. M. Novotortsev, Usp. Khim. 83, 718 (2014).
S. D. Robertson, B. D. McNicol, J. H. de Baas, et al., J. Catal. 37, 424 (1975).
A. K. Singh and Q. Xu, ChemCatChem 5, 652 (2013).
J. H. Sinfelt, Acc. Chem. Res. 10, 15 (1977).
I. Chorkendorff and J. W. Niemantsvedriet, Concepts of Modern Catalysis and Kinetics, 2nd Ed. (Wiley–VCH, Weinheim, 2007).
Funding
This work was supported by the Russian Foundation for Basic Research, project no. 18-33-01068.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that there is no conflict of interest regarding the publication of this manuscript.
Additional information
Translated by M. Timoshinina
Rights and permissions
About this article
Cite this article
Chistyakova, P.A., Chistyakov, A.V. & Tsodikov, M.V. Heterogeneous Catalytic Synthesis of Zingerone and Dehydrozingerone. Pet. Chem. 60, 1080–1086 (2020). https://doi.org/10.1134/S0965544120090066
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965544120090066