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Copper-Containing Catalysts in the Liquid-Phase Hydrogenolysis of Glycerol

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Abstract

The features of the liquid-phase hydrogenolysis of glycerol to 1,2-propylene glycol over Cu/Al2O3 catalysts (Cu = 2–80 wt %) and individual copper particles have been studied. It has been shown that the main factor determining the activity of the catalysts is the specific surface area of copper. It has been found that the Cu/Al2O3 catalyst containing 60 wt % Cu is the most efficient. A new reaction mechanism is proposed based on the obtained data.

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Funding

This work was performed as part of a state task for the Topchiev Institute of Petrochemical Synthesis,Russian Academy of Sciences.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    G. S. Dmitriev, V. I. Khadzhiev, I. S. Mel’chakov & L. N. Zanaveskin

  2. Faculty of Chemistry, Moscow State University, 119234, Moscow, Russia

    S. A. Nikolaev & D. I. Ezzhelenko

Authors
  1. G. S. Dmitriev
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  2. V. I. Khadzhiev
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  3. S. A. Nikolaev
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  4. D. I. Ezzhelenko
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  5. I. S. Mel’chakov
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  6. L. N. Zanaveskin
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Corresponding author

Correspondence to G. S. Dmitriev.

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CONFLICT OF INTEREST

The authors declare that they have no conflict of interest.

AUTHOR INFORMATION

G.S. Dmitriev, ORCID: https://orcid.org/0000-0001-6529-2655

V.I. Khadzhiev, ORCID: https://orcid.org/0000-0002-2180-7423

S.A. Nikolaev, ORCID: http://orcid.org/0000-0002-9091-3537

D.I. Ezzhelenko, ORCID: http://orcid.org/0000-0003-2218-8254

I.S. Mel’chakov, ORCID: https://orcid.org/0000-0002-4888-877X

L.N. Zanaveskin, ORCID: https://orcid.org/0000-0001-7306-6164

Additional information

Translated by E. Boltukhina

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Dmitriev, G.S., Khadzhiev, V.I., Nikolaev, S.A. et al. Copper-Containing Catalysts in the Liquid-Phase Hydrogenolysis of Glycerol. Pet. Chem. 60, 1066–1072 (2020). https://doi.org/10.1134/S096554412009008X

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  • DOI: https://doi.org/10.1134/S096554412009008X

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