Abstract
Zinc oxide nanoparticles were synthesized through sol–gel technique using Azadirachta indica leaves extract. The formation of structure, crystallite parameters, size and morphology were studied through Fourier Transform Infrared spectroscopy, X-ray diffraction, Raman spectroscopy, Transmission Electron Microscopy (TEM) and Selected Area Electron Diffraction data records. X-ray diffraction peaks revealed the presence of hexagonal wurtzite structure for ZnO nanoparticles. The crystallite size and lattice strain of the prepared sample were respectively obtained through measuring the X-ray diffraction peaks broadening and Hall Williamson analysis using anisotropic and isotropic models. The estimated crystallite size using TEM, Scherrer formula and Hall Williamson models were found in well agreement with each other. The optical properties were investigated from the UV–Vis reflectance data and the photoluminescence spectrum recorded at room temperature. The chromaticity color coordinates obtained from the photoluminescence spectrum shows that the biosynthesized ZnO nanoparticles can be useful for white luminescence applications.
Similar content being viewed by others
References
P. Tamizhdurai, S. Sakthinathan, S. Chen, K. Shanthi, S. Sivasanker, and P. Sangeetha (2017). Sci. Rep. 7, 46372.
T. V. Vineeshkumar, D. Rithesh Raj, S. Prasanth, N. V. Unnikrishnan, and C. Sudarsanakumar (2014). Opt. Mater. 37, 439–445.
Z. Sabouri, A. Akbari, H. A. Hosseini, et al. (2019). J. Clust. Sci. 30, 1425–1434.
Arun S. Prasad (2016). Mater. Sci. Semicond. Process 53, 79–83.
X. Q. Zhang, S. L. Hou, H. B. Mao, J. Q. Wang, and Z. Q. Zhu (2010). Appl. Surf. Sci. 256, 3862–3865.
B. J. Jin, S. H. Bae, S. Y. Lee, and S. Im (2000). Mater. Sci. Eng. B. 71, 301–306.
N. L. Rosi and C. A. Mirkin (2005). Chem. Rev. 105, 1547–1562.
P. Amornpitoksuk, S. Suwanboon, S. Sangkanu, A. Sukhoom, J. Wudtipan, K. Srijan, et al. (2011). Powder Technol. 212, 432–438.
P. Kumbhakar, D. Singh, C. S. Tiwary, and A. K. Mitra (2008). Chalcogenide Lett. 5, (12), 387–394.
M. Bandeira, A. L. Possan, S. S. Pavin, et al. (2020). Nano. Struct. Nano. Objects 24, 100532.
M. Darroudi, Z. Sabouri, R. Kazemi Oskuee, A. Khorsand Zak, H. Kargar, and M. H. N. A. Hamid (2013). Ceramics International. 39, (8), 9195–9199.
R. A. Ismail, A. K. Ali, M. M. Ismail, and K. I. Hassoon (2011). Appl. Nanosci. 1, (1), 45–49.
I. A. Siddiquey, T. Furusawa, M. Sato, N. M. Bahadur, M. Mahbubul Alam, and N. Suzuki (2012). Ultrasonics Sonochem 19, 750–755.
S. Vijayakumar, B. Vaseeharan, and R. Sudhakaran (2019). J Clust Sci 30, 1465–1479.
P. Vasudevan, V. Vidyadharan, S. M. Simon, and N. V. Unnikrishnan (2020). J. Sci. Adv. Mater. Dev. 5, 242–249.
S. Ambika and M. Sundrarajan (2015). J. Photochem. Photobiol. B Biol. 149, 143–148.
M. Asimuddin, Mohammed Rafi Shaik, Syed Farooq Adil, Mohammed Rafiq H. Siddiqui, Abdulrahman Alwarthan, Kaiser Jamil, Mujeeb Khan (2020). J. King. Saud. Univ. Sci. 32, 648-656
B. S. Siddiqui, F. Afshan, T. Gulzar, and M. Hanif (2004). Phytochemistry 65, (16), 2363.
B. S. Tiwary (1985). Assoc. Phys. India. 33, (12), 817.
K. Jayasankar, B. K. Abhishek Pandey, and Siddhartha Das Mishra (2016). Mater. Chem. Phys. 171, 195–200.
N. S. Gonçalves, J. A. Carvalho, Z. M. Lima, and J. M. Sasaki (2012). Mater. Lett. 72, 36–38.
K. Venkateswarlu, A. Chandra Bose, and N. Rameshbabu (2010). Physica B Condens. Matter. 405, 4256–4261.
R. Yogamalar, R. Srinivasan, A. Vinu, K. Ariga, and A. C. Bose (2009). Solid State Commun. 149, 1919–1923.
A. Khorsand Zak and W. H. A. Majid (2010). Ceram. Int. 36, 1905–1910.
G. Sangeetha, S. Rajeshwari, and R. Venkatesh (2011). Mater. Res. Bull. 46, 2560–2566.
E. Nagaraj, P. Shanmugam, K. Karuppannan, T. Chinnasamy, and S. Venugopal (2020). New J. Chem. 44, 2166–2179.
S. Fakhari, M. Jamzad, and H. K. Fard (2019). Green Chem. Lett. Rev 12, (1), 19–24.
T. D. Malevu and R. O. Ocaya (2014). Int. J. Electrochem. Sci. 9, 8011–8023.
P. Bindu and S. Thomas (2014). J. Theor. Appl. Phys. 8, 123–134.
L. Shen, et al. (2006). Nanotechnology. 17, 5117–5123.
V. Mote, Y. Purushotham, and B. Dole (2012). J. Theor. Appl. Phys. 6, 6.
V. Biju, N. Sugathan, V. Vrinda, et al. (2008). J. Mater. Sci. 43, 1175–1179.
A. F. Jaramillo, R. Baez-Cruz, L. F. Montoya, C. Medinam, E. Pérez-Tijerina, F. Salazar, D. Rojas, and M. F. Melendrez (2017). Ceramics. Int. 43, 11838–11847.
Y. W. Chen, Y. C. Liu, S. X. Lu, C. S. Xu, C. L. Shao, C. Wang, J. Y. Zhang, Y. M. Lu, D. Z. Shen, and X. W. Fan (2015). J. Chem. Phys. 123, 134701.
J. G. Ma, Y. C. Liu, R. Mu, J. Y. Zhang, Y. M. Lu, D. Z. Shen, and X. W. Fan (2004). J. Vac. Sci. Technol. B 22, 94–98.
M. Gautam, M. Verma, and G. Misra (2011). J. Biomed. Nanotechnol. 7, 161–162.
J. W. Chan, H. Winhold, M. H. Corzett, J. M. Ulloa, M. Cosman, R. Balhorn, and T. Huser (2007). Raman Spectroscopy. Cytometry Part A. 71A, 468–474.
K. Maquelin, C. Kirschner, L. P. Choo-Smith, N. van den Braak, H. P. Endtz, and D. G. Naumann (2002). J. Pupp. J. Microbiol. Methods 51, 255–271.
L. He, Y. Liu, A. Mustapha, and M. Lin (2011). Microbiological Research 166, 207–215.
P. Mohammad and H. Fozia (2014). J Mater Res Technol. https://doi.org/10.1016/j.jmrt.2014.07.001.
M. S. Samuel, L. Bose, and K. C. George (2009). SB Academic Review. XVI, (1), 57–65.
A. Khorsand Zak, W. H. Abd Majid, M. R. Mahmoudian, M. Darroudi, and R. Yousefi (2013). Adv Powder Technol. 24, 618–624.
Juan Estrada-Urbina, Alejandro Cruz-Alonso, Martha Santander-González, Abraham Méndez-Albores, and Alma Vázquez-Durán (2018). Nanomaterials 8, 247.
Jun Zhang, Junhua Xi, and Zhenguo Ji (2011). J. Mater. Chem. 22, 17700–17708.
L. Irimpan, V. Nampoori, P. Radhakrishnan, A. Deepthy, and B. Krishnan (2007). J. Appl. Phys. 102, 063524.
J. H. Zhao, et al. (2015). Optik–Int. J. Light Electron Opt. 127, (3), 1421–1423.
D. Raoufi (2013). J. Luminescence. 134, 213–219.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Vasudevan, P., Prasad, A.S. Phytochemical Mediated Sol–Gel Synthesis, Crystallographic Structure, Morphology and Optical Investigations on ZnO Nanoparticles. J Clust Sci 32, 1253–1260 (2021). https://doi.org/10.1007/s10876-020-01891-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10876-020-01891-8