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The Effect of the Starting Mineralogical Mixture on the Nature of Fe-Serpentines Obtained during Hydrothermal Synthesis AT 90°C

Published online by Cambridge University Press:  01 January 2024

Isabella Pignatelli Open the ORCID record for Isabella Pignatelli [Opens in a new window] ,
Régine Mosser-Ruck ,
Enrico Mugnaioli ,
Jérôme Sterpenich  and
Mauro Gemmi
Isabella Pignatelli*
Affiliation:
Georessources UMR 7359 CNRS-UL, Université de Lorraine, BP 70239, 54506 Vandœuvre-lès-Nancy, Cedex, France
Régine Mosser-Ruck
Affiliation:
Georessources UMR 7359 CNRS-UL, Université de Lorraine, BP 70239, 54506 Vandœuvre-lès-Nancy, Cedex, France
Enrico Mugnaioli
Affiliation:
Center for Nanotechnology Innovation@NEST, Istituto Italiano di Tecnologia, Piazza San Silvestro 12, 56127 Pisa, Italy
Jérôme Sterpenich
Affiliation:
Georessources UMR 7359 CNRS-UL, Université de Lorraine, BP 70239, 54506 Vandœuvre-lès-Nancy, Cedex, France
Mauro Gemmi
Affiliation:
Center for Nanotechnology Innovation@NEST, Istituto Italiano di Tecnologia, Piazza San Silvestro 12, 56127 Pisa, Italy
*
*E-mail address of corresponding author: isabella.pignatelli@univ-lorraine.fr
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Abstract

The formation conditions and stability fields of Fe-serpentines are still poorly understood in both terrestrial (natural or anthropic) and extraterrestrial environments. Knowledge of the effects of physical-chemical parameters on compositional and structural features of Fe-serpentines is lacking, and only a few thermodynamic parameters of these minerals are available in the literature. To fill these gaps, the synthesis of these minerals, while controlling all the physicochemical experimental parameters, was undertaken. Two hydrothermal syntheses were carried out at 90°C to investigate the effect of two different starting mineralogical mixtures on the nature of Fe-serpentines. The run products were identified by several analytical techniques (powder X-ray diffraction, transmission, and scanning electron microscopy). Berthierine crystals were synthesized from a starting mixture of kaolinite and metal iron. The berthierines synthesized show different morphologies and iron contents (~3–38 at.%). From a starting mineralogical mixture composed of quartz and metal iron, cronstedtite crystallizes. Most of the crystals are 1M polytypes. Magnetite is always associated with both berthierine and cronstedtite. Lepidocrocite was observed only in the experiment with kaolinite. These experimental results demonstrated that Fe enrichment in serpentines depends on the silicate precursor (kaolinite or quartz) of the starting mixture. The results are also in agreement with the geochemical equilibrium predicted by thermodynamic modeling, i.e. the formation of berthierine and cronstedtite in association with magnetite at the expense of metal iron and silicates.

Keywords

BerthierineCronstedtiteFe-serpentinesHydrothermal synthesis
Type
Article
Information
Clays and Clay Minerals , Volume 68 , Issue 4 , August 2020 , pp. 394 - 412
Copyright
Copyright © Clay Minerals Society 2020

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References

Amouric, M., Parron, C., Casalini, L., & Giresse, P. (1995). A (1: 1) 7-Å Fe phase and its transformation in recent sediments: an HRTEM and AEM study. Clays and Clay Minerals, 43, 446–454.CrossRefGoogle Scholar
Bailey, S. W. (1969). Polytypism of trioctahedral 1: 1 layer silicates. Clays and Clay Minerals, 17, 355–371.CrossRefGoogle Scholar
Bailey, S. W. (1988). Odinite, a new dioctahedral-trioctahedral Fe3+-rich 1: 1 clay mineral. Clay Minerals, 23, 237–247.CrossRefGoogle Scholar
Barber, D. J. (1981). Matrix phyllosilicates and associated minerals in C2M carbonaceous chondrites. Geochimica et Cosmochimica Acta, 45, 945–970.CrossRefGoogle Scholar
Bhattacharyya, D. P. (1983). Origin of berthierine in ironstones. Clays and Clay Minerals, 31, 173–182.CrossRefGoogle Scholar
Bildstein, O., Trotignon, L., Perronnet, M., & Jullien, M. (2006). Modelling iron–clay interactions in deep geological disposal conditions. Physics and Chemistry of the Earth, 31, 618–625.CrossRefGoogle Scholar
Bourdelle, F., Truche, L., Pignatelli, I., Mosser-Ruck, R., Lorgeoux, C., Roszypal, C., & Michau, N. (2014). Iron–clay interactions under hydrothermal conditions: impact of specific surface area of metallic iron on reaction pathway. Chemical Geology, 381, 194–205.CrossRefGoogle Scholar
Bourdelle, F., Mosser-Ruck, R., Truche, L., Lorgeoux, C., Pignatelli, I., & Michau, N. (2017). A new view on iron-claystone interactions under hydrothermal conditions (90°C) by monitoring in situ pH and H2 generation. Chemical Geology, 466, 600–607.CrossRefGoogle Scholar
Brindley, G. W. (1951). The crystal structures of some chamosite minerals. Mineralogical Magazine, 29, 502–525.CrossRefGoogle Scholar
Brindley, G. W. (1982). Chemical compositions of berthierines – A review. Clays and Clay Minerals, 30, 153–155.CrossRefGoogle Scholar
Browning, L. B., McSween, H. Y. Jr., & Zolensky, M. E. (1996). Correlated alteration effects in CM carbonaceous chondrites. Geochimica et Cosmochimica Acta, 60, 2621–2633.CrossRefGoogle Scholar
Calvin, W. M. (1998). Could Mars be dark and altered? Geophysical Research Letters, 25, 1597–1600.CrossRefGoogle Scholar
Calvin, W. M., & King, T. V. V. (1997). Spectral characteristics of iron-bearing phyllosilicates: Comparison to Orgueil (CI1), and Murchison and Murray (CM2). Meteoritics & Planetary Science, 32, 693–701.CrossRefGoogle Scholar
Carroll, S. A., & Walther, J. V. (1990). Kaolinite dissolution at 25°, 60°, and 80°C. American Journal of Science, 290, 797–810.CrossRefGoogle Scholar
Changela, H. G., & Bridges, J. C. (2011). Alteration assemblages in the nakhlites: variation with depth on Mars. Meteoritics & Planetary Science, 45, 1847–1867.CrossRefGoogle Scholar
Cliff, G., & Lorimer, G. W. (1975). The quantitative analysis of thin specimen. Journal of Microscopy, 103, 203–207.CrossRefGoogle Scholar
Cudennec, Y., & Lecerf, A. (2006). The transformation of ferrihydrite into goethite or hematite, revisited. Journal of Solid State Chemistry, 179, 716–722.CrossRefGoogle Scholar
de Combarieu, G., Schlegel, M. L., Neff, D., Foy, E., Vantelon, D., Barboux, P., & Gin, S. (2011). Glass-iron-clay interactions in a radioactive waste geological disposal: An integrated laboratory-scale experiment. Applied Geochemistry, 26, 65–79.CrossRefGoogle Scholar
de la Fuerte, D., Díaz, I., Alcántara, J., Chico, B., Simancas, J., Llorente, I., García-Delgado, A., Jiménez, J. A., Adeva, P., & Morcillo, M. (2016). Corrosion mechanisms of mild stell in chloride-rich atmospheres. Materials and Corrosion, 67, 227–238.CrossRefGoogle Scholar
Dove, P. M., & Crerar, D. A. (1990). Kinetics of quartz dissolution in electrolyte solutions using a hydrothermal mixed flow reactor. Geochimica et Cosmochimica Acta, 54, 955–969.CrossRefGoogle Scholar
Dove, P., & Elston, S. F. (1992). Dissolution kinetics of quartz in sodium chloride solutions: analysis of existing data and a rate model for 25°C. Geochimica et Cosmochimica Acta, 56, 4147–4156.CrossRefGoogle Scholar
Dove, P. M., Han, N., & De Yoreo, J. J. (2005). Mechanisms of classical crystal growth theory explain quartz and silicate dissolution behavior. Proceedings of the National Academy of Sciences, 102, 15357–15363.CrossRefGoogle ScholarPubMed
Ďurovič, S. (1997). Cronstedtite-1M and co-existence of 1M and 3T polytypes. Ceramics-Silikáty, 41, 98–104.Google Scholar
Dzene, L., Brendlé, J., Limousy, L., Dutournié, P., Martin, C., & Michau, N. (2018). Synthesis of iron-rich tri-octahedral clay minerals: a review. Applied Clay Science, 166, 276–287.CrossRefGoogle Scholar
Edwards, P. P., Kuznetsov, V. L., & David, W. I. F. (2007). Hydrogen energy. Philosophical Transactions of the Royal Society, 365, 1043–1056.Google ScholarPubMed
Elmaleh, A., Tarantino, S. C., Zema, M., Devouard, B., & Fialin, M. (2012). The low-temperature magnetic signature of Fe-rich serpentine in CM2 chondrites: comparison with terrestrial cronstedtite and evolution with the degree of alteration. Geochemistry Geophysics Geosystems, 13, Q05Z42. https://doi.org/10.1029/2011GC003964.CrossRefGoogle Scholar
Elmaleh, A., Bourdelle, F., Caste, F., Benzerara, K., Leroux, H., & Devouard, B. (2015). Formation and transformations of Fe-rich serpentines by asteroidal aqueous. Geochimica et Cosmochimica Acta, 158, 162–178.CrossRefGoogle Scholar
Frondel, C. (1962). Polytypism in cronstedtite. American Mineralogist, 47,781–783.Google Scholar
Geiger, C. A., Henry, D. L., Bailey, S. W., & Maj, J. J. (1983). Crystal structure of cronstedtite-2H 2. Clays and Clay Minerals, 31, 97–108.CrossRefGoogle Scholar
Gemmi, M., Mugnaioli, E., Gorelik, T. E., Kolb, U., Palatinus, L., Boullay, P., Hovmöller, S., & Abrahams, J. P. (2019). 3D Electron Diffraction: the nanocrystallography revolution. ACS Central Science, 5, 1315–1329.CrossRefGoogle ScholarPubMed
Giresse, P., Wiewiora, A., & Lacka, B. (1988). Mineral phases and processes within green peloids from two recent deposits near the Congo river mouth. Clay Minerals, 23, 447–458.CrossRefGoogle Scholar
Gole, M. L. (1980a). Low-temperature retrograde minerals in metamorphosed Archean banded iron-formations, Western Australia. The Canadian Mineralogist, 18, 205–214.Google Scholar
Gole, M. J. (1980b). Mineralogy and petrology of very-low metamorphic grade Archean banded iron-formations, Weld Range, Western Australia. American Mineralogist, 65, 8–25.Google Scholar
Guggenheim, S., Bailey, S. W., Eggleton, R. A., & Wilkes, P. (1982). Structural aspects of greenalite and related minerals. The Canadian Mineralogist, 20, 1–18.Google Scholar
Guillaume, D., Neaman, A., Cathelineau, M., Mosser-Ruck, R., Peiffert, C., Abdelmoula, M., Dubessy, J., Villiéras, F., Baronnet, A., & Michau, N. (2003). Experimental synthesis of chlorite from smectite at 300°C in the presence of metallic Fe. Clay Minerals, 38, 281–302.CrossRefGoogle Scholar
Hicks, L. J., Bridges, J. C., & Gurman, S. J. (2014). Ferric saponite and serpentine in the nakhlite martian meteorites. Geochimica et Cosmochimica Acta, 136, 194–210.CrossRefGoogle Scholar
Hornibrook, E. R. C., & Longstaffe, F. J. (1996). Berthierines from the Lower Cretaceous Clearwater formation, Alberta, Canada. Clays and Clay Minerals, 44, 1–21.CrossRefGoogle Scholar
Hybler, J. (2014). Refinement of cronstedtite- 1M. Acta Crystallographica, B70, 963–972.Google Scholar
Hybler, J., Petfiček, V., Ďurovič, S., & Smrčok, L. (2000). Refinement of the crystal structure of cronstedtite-1T Clays and Clay Minerals, 48, 331–338.CrossRefGoogle Scholar
Hybler, J., Petfiček, V., Fábry, J., & Ďurovič, S. (2002). Refinement of the crystal structure of cronstedtite-2H2. Clays and Clay Minerals, 50, 601–613.CrossRefGoogle Scholar
Hybler, J., Ďurovič, S., & Kogure, T. (2008). Polytypism in cronstedtite. Acta Crystallographica, A64, 498–499.CrossRefGoogle Scholar
Hybler, J., Sejkora, J., & Venclík, V. (2016). Polytypism of cronstedtite from Pohled, Czech Republic. European Journal of Mineralogy, 28, 765–775.CrossRefGoogle Scholar
Hybler, J., Števko, M., & Sejkora, J. (2017). Polytypism of cronstedtite from Nižná Slaná, Slovakia. European Journal of Mineralogy, 29, 91–99.CrossRefGoogle Scholar
Hybler, J., Klementová, M., Jarošová, M., Pignatelli, I., Mosser-Ruck, R., & Ďurovič, S. (2018). Polytype identification in trioctahedral 1: 1 layer silicates. Clays and Clay Minerals, 66, 379–402.CrossRefGoogle Scholar
Iijima, A., & Matsumoto, R. (1982). Berthierine and chamosite in coal measures of Japan. Clays and Clay Minerals, 30, 264–274.CrossRefGoogle Scholar
Kogure, T., Hybler, J., & Yoshida, H. (2002). Coexistence of two polytypic groups in cronstedtite from Lostwithiel England. Clays and Clay Minerals, 50, 504–513.CrossRefGoogle Scholar
Kolb, U., Mugnaioli, E., & Gorelik, T. E. (2011). Automated electron diffraction tomography - a new tool for nanocrystal structure analysis. Crystal Research and Technology, 46, 542–554.CrossRefGoogle Scholar
Kreutzer, S., Friedrich, J., Sanderson, D., Adamiec, G., Chruśscińska, A., Fasoli, M., Martini, M., Polymeris, G. S., Burbidge, C. I., & Schmidt, C. (2017). Les sables de Fontainebleau: a natural quartz reference sample and its characterization. Ancient TL, 35, 21–31.Google Scholar
Lanson, B. (1997). Decomposition of experimental X-ray diffraction patterns (profile fitting): a convenient way to study clay minerals. Clays and Clay Minerals, 45, 132–146.CrossRefGoogle Scholar
Lanson, B., & Besson, G. (1992). Characterisation of the end of smectite-to-illite transformation: decomposition of X-ray patterns. Clays and Clay Minerals, 40, 40–52.CrossRefGoogle Scholar
Lanson, B., Van Lantenois, S., Aken, P. A., Bauer, A., & Plançon, A. (2012). Experimental investigation of smectite interaction with metal iron at 80°C: structural characterization of newly formed Fe-rich phyllosilicates. American Mineralogist, 97, 864–871.CrossRefGoogle Scholar
Lantenois, S., Lanson, B., Muller, F., Bauer, A., Jullien, M., & Plançon, A. (2005). Experimental study of smectite interaction with metal Fe at low temperature: 1. Smectite destabilization. Clays and Clay Minerals, 53, 597–612.CrossRefGoogle Scholar
Lauretta, D. S., Hua, X., & Buseck, P. R. (2000). Mineralogy of finegrained rims in the ALH 81002 CM chondrite. Geochimica et Cosmochimica Acta, 64, 3263–3273.CrossRefGoogle Scholar
Lee, M. R., & Chatzitheodoris, E. (2016). Replacement of glass in the Nakhla meteorite by berthierine: implications for understanding the origins of aluminum-rich phyllosilicates on Mars. Meteoritics & Planetary Science, 51, 1643–1653.CrossRefGoogle Scholar
Liu, H., Li, P., Zhu, M., Wei, Y., & Sun, Y. (2007). Fe(II)-induced transformation from ferrihyfrite to lepidocrocite and goethite. Journal of Solid State Chemistry, 180, 2121–2128.CrossRefGoogle Scholar
López-García, J. A., Manteca, J. I., Prieto, A. C., & Calvo, B. (1992). Primera aparicíon en España de cronstedtita. Caracterizacíon estructural. Boletín de la Sociedad Española de Mineralogía, 15, 21–25.Google Scholar
McAlister, J. A., & Kettler, R. M. (2008). Metastable equilibria among dicarboxylic acids and oxidation state during aqueous alteration on the CM2 chondrite parent body. Geochimica et Cosmochimica Acta, 72, 233–241.CrossRefGoogle Scholar
McCollom, T. M., & Seewald, J. S. (2013). Serpentinites, hydrogen, and life. Elements, 9, 129–134.CrossRefGoogle Scholar
Misawa, T., Hashimoto, K., & Shimodaira, S. (1974). The mechanism of formation of iron oxide and oxyhydroxides in aqueous solutions at room temperature. Corrosion Science, 14, 131–149.CrossRefGoogle Scholar
Mosser-Ruck, R., Cathelineau, M., Guillaume, D., & Charpentier, D. (2010). Effects of temperature, pH, and iron/clay and liquid/clay ratios on experimental conversion of dioctahedral smectite to berthierine, chlorite, vermiculite, or saponite. Clays and Clay Minerals, 58, 280–291.CrossRefGoogle Scholar
Mugnaioli, E., & Gemmi, M. (2018). Single-crystal analysis of nanodomains by electron diffraction tomography: mineralogy at the order-disorder borderline. Zeitschrift für Kristallographie, 233, 163–178.CrossRefGoogle Scholar
Müller, W. F., Kurat, G., & Kracher, A. (1979). Chemical and crystal-lographic study of cronstedtite in the matrix of the Cochabamba (CM2) carbonaceous chondrite. Tschermaks Mineralogische und Petrographische Mitteilungen, 26, 293–304.CrossRefGoogle Scholar
Parkhurst, D. & Appelo, C.A.J. (1999). User's guide to PHREEQC (version 2) -a computer program for speciation, reaction-path, 1D-transport, and inverse geochemical calculations. U.S. Geological Survey Water Resources Investigation Report 99, 99–4259. U.S. Geological Survey, Reston, Virginia, USA. 312 pp.Google Scholar
Perronnet, M., Jullien, M., Villiéras, F., Raynal, J., Bonnin, D., & Bruno, G. (2008). Evidence of a critical content in Fe(0) on FoCa7 bentonite reactivity at 80°C. Applied Clay Science, 38, 187–202.CrossRefGoogle Scholar
Pignatelli, I., Mugnaioli, E., Hybler, J., Mosser-Ruck, R., Cathelineau, M., & Michau, N. (2013). A multi-technique characterization of cronstedtite synthesized by iron-clay interaction in a step-by-step cooling procedure. Clays and Clay Minerals, 61, 277–289.CrossRefGoogle Scholar
Pignatelli, I., Bourdelle, F., Bartier, D., Mosser-Ruck, R., Truche, L., Mugnaioli, E., & Michau, N. (2014). Iron-clay interactions: detailed study of the mineralogical transformation of claystone with emphasis on the formation of iron-rich T-O phyllosilicates in a step-by-step cooling experiment from 90°C to 40°C. Chemical Geology, 387, 1–11.CrossRefGoogle Scholar
Pignatelli, I., Marrocchi, Y., Vacher, L., Delon, R., & Gounelle, M. (2016). Multiple precursors of secondary mineralogical assemblages in CM chondrites. Meteoritics & Planetary Science, 51, 785–805.CrossRefGoogle Scholar
Pignatelli, I., Marrocchi, Y., Mugnaioli, E., Bourdelle, F., & Gounelle, M. (2017). Mineralogical, crystallographic and redox features of the earliest stages of fluid alteration in CM chondrites. Geochimica et Cosmochimica Acta, 209, 106–122.CrossRefGoogle Scholar
Pignatelli, I., Mugnaioli, E., & Marrocchi, Y. (2018). Cronstedtite polytypes in the Paris meteorite. European Journal of Mineralogy, 30, 349–354.CrossRefGoogle Scholar
Ramachandran, R., & Menon, R. K. (1998). An overview of industrial uses of hydrogen. International Journal of Hydrogen Energy, 23, 593–598.CrossRefGoogle Scholar
Refait, P., & Génin, J. M. R. (1997). The mechanisms of oxidation of ferrous hydroxychloride β-Fe2(OH)3Cl in aqueous solution: the formation of akaganeite vs goethite. Corrosion Science, 39, 539–553.CrossRefGoogle Scholar
Refait, P., Abdelmoula, M., & Génin, J. M. R. (1998). Mechanisms of formation and structure of green rust one in aqueous corrosion of iron in the presence of chloride ions. Corrosion Science, 40, 1547–1560.CrossRefGoogle Scholar
Réguer, S., Dillmann, P., & Mirambet, F. (2007). Buried iron archeological artefacts: corrosion mechanisms related to the presence of Cl-containing phases. Corrosion Science, 49, 2726–2744.CrossRefGoogle Scholar
Rivard, C., Pelletier, M., Michau, N., Razafitianamaharavo, A., Bihannic, I., Abdelmoula, M., Ghanbaja, J., & Villiéras, F. (2013a). Berthierine-like mineral formation and stability during the interaction of kaolinite with metallic iron at 90°C under anoxic and oxic conditions. American Mineralogist, 98, 163–180.CrossRefGoogle Scholar
Rivard, C., Montargès-Pelletier, E., Vantelon, D., Pelletier, M., Karunakaran, C., Mochot, L. J., Villieras, F., & Michau, N. (2013b). Combination of multi-scale and multi-edge X-ray spectroscopy for investigating the products obtained from the interaction between kaolinite and metallic iron in anoxic conditions at 90°C. Physics and Chemistry of Minerals, 40, 115–132.CrossRefGoogle Scholar
Rivas-Sanchez, M. L., Alva-Valdivia, L. M., Arenas-Alatorre, J., Urrutia-Fucugauchi, J., Ruiz-Sandoval, M., & Ramos-Molina, M. A. (2006). Berthierine and chamosite hydrothermal: genetic guides in the Peña Colorada magnetite-bearing ore deposit, Mexico. Earth Planets and Space, 58, 1389–1400.CrossRefGoogle Scholar
Rubin, A. E., Trigo-Rodríguez, J. M., Huber, H., & Wasson, J. T. (2007). Progressive aqueous alteration of CM carbonaceous chondrites. Geochimica et Cosmochimica Acta, 71, 2361–2382.CrossRefGoogle Scholar
Saadi, F. A., Wolf, K.-H., & Kruijsdijk, C. (2017). Characterization of Fontainebleau sandstone: quartz overgrowth and its impact on porethroat framework. Journal of Petroleum & Environmental Biotechnology, 8, 1–12.CrossRefGoogle Scholar
Schlegel, M. L., Bataillon, C., Benhamida, K., Blanc, C., Menut, D., & Lacour, J. L. (2008). Metal corrosion and argillite transformation at the water-saturated, high-temperature iron-clay interface: a microscopic-scale study. Applied Geochemistry, 23, 2619–2633.CrossRefGoogle Scholar
Schulte, M., & Shock, E. (2004). Coupled organic synthesis and mineral alteration on the meteorite parent bodies. Meteoritics & Planetary Science, 46, 1577–1590.CrossRefGoogle Scholar
Schwertmann, U., & Fechter, H. (1994). The formation of green rust and its transformation to lepidocrocite. Clay Minerals, 29, 87–92.CrossRefGoogle Scholar
Schwertmann, U., & Thalmann, H. (1976). The influence of [Fe(II)], [Si], and pH on the formation of lepidocrocite and ferrihydrite during oxidation of aqueous FeCl2 solutions. Clay Minerals, 11, 189–200.CrossRefGoogle Scholar
Seyfried, W. E. Jr., Foustoukos, D. I., & Fu, Q. (2007). Redox evolution and mass transfer during serpentinization: An experimental and theoretical study at 200°C, 500 bar with implications for ultramafichosted hydrothermal systems at Mid-Ocean Ridges. Geochimica et Cosmochimica Acta, 71, 3872–3886.CrossRefGoogle Scholar
Smrčok, L., & Weiss, Z. (1993). DIFK91: a program for the modelling of powder diffraction patterns on a PC. Journal of Applied Crystallography, 26, 140–141.CrossRefGoogle Scholar
Smrčok, L., Ďurovič, S., Petříček, V., & Weiss, Z. (1994). Refinement of the crystal structure of cronstedtite-3T. Clays and Clay Minerals, 42, 544–551.CrossRefGoogle Scholar
Song, Y., Jiang, G., Chen, Y., Zhao, P., & Tian, Y. (2017). Effects of chloride ions on corrosion of ductile iron and carbon steel in soil and environments. Scientific Reports, 7, 6865.CrossRefGoogle ScholarPubMed
Steadman, R., & Nuttall, P. M. (1964). Further polymorphism in cronstedtite. Acta Crystallographica, 17, 404–406.CrossRefGoogle Scholar
Tomeoka, K., & Buseck, P. R. (1985). Indicators of aqueous alteration in CM carbonaceous chondrites: Microtextures of a layered mineral containing Fe, S, O and Ni. Geochimica et Cosmochimica Acta, 49, 2149–2163.CrossRefGoogle Scholar
Tosca, N. J., Guggenheim, S., & Pufahl, P. K. (2016). An authigenic origin for Precambrian greenalite: implications for iron formation and the chemistry of ancient seawater. GSA Bulletin, 128, 511–530.CrossRefGoogle Scholar
Van Lier, J. A., De Bruyn, P. L., & Overbeek, J. T. G. (1960). The solubility of quartz. The Journal of Physical Chemistry, 64, 1675–1682.CrossRefGoogle Scholar
Wahle, M. W., Bujnowski, T. J., Guggenheim, S., & Kogure, T. (2010). Guidottiite, the Mn-analogue of cronstedtite: a new serpentine-group mineral from South Africa. Clays and Clay Minerals, 58, 364–376.CrossRefGoogle Scholar
Wilson, J., Cressey, G., Cressey, B., Cuadros, J., Ragnarsdottir, K. V., Savage, D., & Shibata, M. (2006). The effect of iron on montmorillonite stability. (II) Experimental investigation. Geochimica et Cosmochimica Acta, 70, 323–336.CrossRefGoogle Scholar
Wolery, T.J. & Jove-Colon, C.F. (2004). Qualification of thermodynamic data for geochemical modeling of mineral–water interactions in dilute systems. Rep. ANL-WIS-GS-000003 REV 00, U.S. Dept. of Energy, Washington, DC.Google Scholar
Zega, T. J., & Buseck, P. R. (2003). Fine-grained-rim mineralogy of the Cold Bokkeveld CM chondrite. Geochimica et Cosmochimica Acta, 67, 1711–1721.CrossRefGoogle Scholar
Zolensky, M.E. (1984). Hydrothermal alteration of CM carbonaceous chondrites; implications of the identification of tochilinite as one type of meteoritic PCP. in: 47th Annual Meeting of the Meteoritical Society, p. 19.Google Scholar
Zolensky, M. & Keller, L.P. (1999). Clay Minerals. In Primitive Meteorites and Interplanetary Dust I. In Program and Abstracts for Clay Minerals Society 28th Annual Meeting, p. 184.Google Scholar
Zolensky, M. & McSween, H.Y. (1988). Aqueous alteration. Pp. 114–143 in: Meteorites and the Early Solar System (Kerridge, J.F. and Matthews, M.S., editors). University of Arizona Press.Google Scholar
Zolotov, M. Y. (2014). Formation of brucite and cronstedtite bearing mineral assemblages on Ceres. Icarus, 228, 13–26.CrossRefGoogle Scholar