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Synthesis and stability of thermally labile 1,2-oxaphosphetane 2-oxides and 1,2-thiaphosphetane 2-sulfides (microreview)

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Chemistry of Heterocyclic Compounds Aims and scope

Synthesis and thermal stability of 1,2-oxaphosphetane 2-oxide and 1,2-thiaphosphetane 2-sulfide derivatives are discussed. This microreview covers the available synthetic methods of thermally labile 1,2-oxaphosphetane 2-oxides and 1,2-thiaphosphetane 2-sulfides and their fragmentation. The synthetic approaches may be classified in four distinct categories: cycloaddition, cyclization, fragmentation, and annulation.

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Financial support by the National Natural Science Foundation of China (No. 21772010) is gratefully acknowledged.

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  1. State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, 15 Northern 3rd Ring Road East, Chaoyang District, Beijing, 100029, People’s Republic of China

    Jiaxi Xu

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  1. Jiaxi Xu
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Correspondence to Jiaxi Xu.

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Published in Khimiya Geterotsiklicheskikh Soedinenii, 2020, 56(8), 979–981

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Xu, J. Synthesis and stability of thermally labile 1,2-oxaphosphetane 2-oxides and 1,2-thiaphosphetane 2-sulfides (microreview). Chem Heterocycl Comp 56, 979–981 (2020). https://doi.org/10.1007/s10593-020-02763-9

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  • DOI: https://doi.org/10.1007/s10593-020-02763-9

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