Skip to main content
SpringerLink
Log in

SYNTHESIS, STRUCTURE, AND PHOTOLUMINESCENT PROPERTIES OF LANTHANIDE (Ln = Dy, Tb) CHLORIDES AND THIOPHENOLATES SUPPORTED BY FORMAMIDINATE LIGANDS

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

This article has been updated

Abstract

The [Dy(DippForm)2Cl(THF)] (1a) and [Tb(DippForm)2Cl(THF)2] (1b) complexes are synthesized using salt metathesis reactions between lanthanide chlorides and K(DippForm) (DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate). In contrast to K(DippForm), a reaction of its less sterically demanding analogue K(MesForm) (MesForm = N,N′-bis(mesityl)formamidinate) with LnCl3 at any ratio of the reagents leads to the formation of the homoligand [Ln(MesForm)3] (Ln = Dy (2a), Tb (2b)) complexes. The [Ln(MesForm)2Cl(THF)] compounds are not isolated. Compounds 1a and 1b are successfully used as starting reagents for the preparation of new thiophenolate complexes [Ln(DippForm)2(SPh)(THF)] (Ln = Dy (3a), Tb (3b)). Crystal structures of compounds 1-3 are determined by single crystal X-ray diffraction. Photoluminescent properties of the complexes obtained are studied. The analysis of the spectra of both DippForm– and SPh– ligands shows an antenna effect for both Dy(III) and Tb(III). However, MesForm– acts as an efficient antenna for Tb(III) rather than Dy(III).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

Change history

  • 28 October 2020

    Added ESM information into HTML version of the Article.

REFERENCES

  1. F. T. Edelmann. Chem. Soc. Rev., 2009, 38, 2253.

  2. A. A. Trifonov. Coord. Chem. Rev., 2010, 254, 1327.

  3. F. T. Edelmann. Chem. Soc. Rev., 2012, 41, 7657.

  4. R. M. Roberts. J. Am. Chem. Soc., 1949, 71, 3848.

  5. K. M. Kuhn and R. H. Grubbs. Org. Lett., 2008, 10, 2075.

  6. M. L. Cole, G. B. Deacon, P. C. Junk, and K. Konstas. Chem. Commun., 2005, 1581.

  7. M. L. Cole and P. C. Junk. Chem. Commun., 2005, 2695.

  8. G. B. Deacon, M. E. Hossain, P. C. Junk, and M. Salehisaki. Coord. Chem. Rev., 2017, 340, 247.

  9. G. B. Deacon, P. C. Junk, and D. Werner. Polyhedron, 2016, 103, 178.

  10. M. L. Cole, G. B. Deacon, C. M. Forsyth, P. C. Junk, K. Konstas, J. Wang, H. Bittig, and D. Werner. Chem. Eur. J., 2012, 19, 1410.

  11. G. B. Deacon, P. C. Junk, and D. Werner. Chem. Eur. J., 2016, 22, 160.

  12. R. Yadav, T. Simler, M. T. Gamer, R. Köppe, and P. W. Roesky. Chem. Commun., 2019, 55, 5765.

  13. M. L. Cole, G. B. Deacon, C. M. Forsyth, P. C. Junk, K. Konstas, and J. Wang. Chem. Eur. J., 2007, 13, 8092.

  14. M. L. Cole, G. B. Deacon, P. C. Junk, and J. Wang. Organometallics, 2013, 32, 1370.

  15. S. Bestgen, Q. Chen, N. H. Rees, and J. M. Goicoechea. Dalton Trans., 2018, 47, 13016.

  16. D. A. Bashirov, D. S. Kolybalov, T. S. Sukhikh, and S. N. Konchenko. J. Struct. Chem., 2020, 61(4), 550.

  17. L. Guo, X. Zhu, S. Zhou, X. Mu, Y. Wei, S. Wang, Z. Feng, G. Zhang, and B. Deng. Dalton Trans., 2014, 43, 6842.

  18. M. L. Cole, G. B. Deacon, C. M. Forsyth, P. C. Junk, D. Polo-Cerón, and J. Wang. Dalton Trans., 2010, 39, 6732.

  19. G. B. Deacon, P. C. Junk, J. Wang, and D. Werner. Inorg. Chem., 2014, 53, 12553.

  20. D. Werner, X. Zhao, S. P. Best, L. Maron, P. C. Junk, and G. B. Deacon. Chem. Eur. J., 2016, 23, 2084.

  21. G. B. Deacon, P. C. Junk, L. K. Macreadie, and D. Werner. Eur. J. Inorg. Chem., 2014, 2014, 5240.

  22. D. Werner, G. B. Deacon, P. C. Junk, and R. Anwander. Chem. Eur. J., 2014, 20, 4426.

  23. G. B. Deacon, P. C. Junk, and D. Werner. Eur. J. Inorg. Chem., 2015, 2015, 1484.

  24. Y.-Z. Ma, N. A. Pushkarevsky, T. S. Sukhikh, A. E. Galashov, A. G. Makarov, P. W. Roesky, and S. N. Konchenko. Eur. J. Inorg. Chem., 2018, 2018, 3388.

  25. Y.-Z. Ma, S. Bestgen, M. T. Gamer, S. N. Konchenko, and P. W. Roesky. Angew. Chem., Int. Ed., 2017, 56, 13249.

  26. H.-X. Li, Y.-J. Zhu, M.-L. Cheng, Z.-G. Ren, J.-P. Lang, and Q. Shen. Coord. Chem. Rev., 2006, 250, 2059.

  27. G. A. Kumar, R. E. Riman, and J. G. Brennan. Coord. Chem. Rev., 2014, 273–274, 111.

  28. J. Hong, L. Zhang, K. Wang, Y. Zhang, L. Weng, and X. Zhou. Chem. Eur. J., 2013, 19, 7865.

  29. I. V. Basalov, D. M. Lyubov, G. K. Fukin, A. V. Cherkasov, and A. A. Trifonov. Organometallics, 2013, 32, 1507.

  30. A. O. Tolpygin, A. V. Cherkasov, G. K. Fukin, and A. A. Trifonov. Inorg. Chem., 2014, 53, 1537.

  31. J. Hong, Z. Li, Z. Chen, L. Weng, X. Zhou, and L. Zhang. Dalton Trans., 2016, 45, 6641.

  32. Z. Zhang, L. Zhang, Y. Li, L. Hong, Z. Chen, and X. Zhou. Inorg. Chem., 2010, 49, 5715.

  33. D. Heitmann, C. Jones, D. P. Mills, and A. Stasch. Dalton Trans., 2010, 39, 1877.

  34. C. Schoo, S. Bestgen, R. Köppe, S. N. Konchenko, and P. W. Roesky. Chem. Commun., 2018, 54, 4770.

  35. D. Werner, G. B. Deacon, and P. C. Junk. Inorg. Chem., 2019, 58, 1912.

  36. G. M. Sheldrick. Acta Crystallogr., Sect. A, 2015, 71, 3.

  37. G. M. Sheldrick. Acta Crystallogr., Sect. C, 2015, 71, 3.

  38. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann. J. Appl. Crystallogr., 2009, 42, 339.

Download references

Funding

This work was supported by the Russian Science Foundation (grant No. 16-13-10294).

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    D. A. Bashirov, D. S. Kolybalov, T. S. Sukhikh & S. N. Konchenko

  2. Novosibirsk State University, Novosibirsk, Russia

    D. A. Bashirov, D. S. Kolybalov, T. S. Sukhikh & S. N. Konchenko

Authors
  1. D. A. Bashirov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. S. Kolybalov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. S. Sukhikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. N. Konchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. N. Konchenko.

Ethics declarations

The authors declare that they have no conflict of interests.

Supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bashirov, D.A., Kolybalov, D.S., Sukhikh, T.S. et al. SYNTHESIS, STRUCTURE, AND PHOTOLUMINESCENT PROPERTIES OF LANTHANIDE (Ln = Dy, Tb) CHLORIDES AND THIOPHENOLATES SUPPORTED BY FORMAMIDINATE LIGANDS. J Struct Chem 61, 1219–1226 (2020). https://doi.org/10.1134/S0022476620080065

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476620080065

Keywords

Search

Navigation