Abstract
This paper presents the first results of hygrometric analysis (sorption isotherm method) of the contents of bound water types for nonextracted rock samples of the Bazhenov Formation. The water sorption isotherms are characterized by an evident S shape, which allows determination of the maximum amount of mono-, poly-, and capillary condensation bound water and provides important conclusions on the hydrophilic properties of rocks of the formation. According to the morphology of the sorption isotherms, the amount of bound water, and their similar mineral compositions, nine samples were combined into four groups; other samples were considered individually. A correlation between the content of pore water and the amount of mono- and polylayered water was found.
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REFERENCES
Andrade, R.D., Lemus, R., and Perez, C.E., Models of sorption isotherms for food: uses and limitations, VITAE, 2011, vol. 18, no. 3, pp. 325–334.
Dorofeeva, T.V., Krasnov, S.G., Lebedev, V.A., and Petrova, G.V., Kollektory nefti bazhenovskoi svity Zapadnoi Sibiri (Oil Reservoirs in the Bazhenov Formation in West Siberia), Moscow: Nedra, 1983.
Ivanikova, N.P., et al., Fiziko-khimicheskie svoistva gruntov i metody ikh issledovaniya (Physico-Chemical Properties of Soils and Methods of Their Study), St. Petersburg: St. Peterburg. Univ., 1999.
Kazak, E.S., Bogdanovich, N.N., Kazak, A.V., Mamiashev, T.V., and Kostin, D.K., Quantification of residual pore water content and analysis of water extract of the Bazhenov Formation samples (Western Siberia) (Russian), Oil Industry J., 2017, vol. 4, pp. 48–52.
Korolev, V.A., Bound water in rocks: new facts and problems, Soros Edu. J., 1996, no. 9, pp. 79–85.
Kuligiewicz, A. and Derkowski, A., Tightly bound water in smectites, Am. Mineral., 2017, no. 5, pp. 28–35.
Likos, W. J. and Ning, Lu, Water vapor sorption behavior of smectite-kaolinite mixtures, Clays Clay Miner., 2002, vol. 50, no. 5, pp. 553–561.
Moiseenko, A.S., Mel’nikov, I.G., and Plyusina, I.I., Quantitative determination of associated water in rocks of terrigenous type, Geol. Nefti Gaza, 1987, no. 1, pp. 30–33.
Nikol’skii, B.P., Spravochnik khimika. Tom 3. (Khimicheskie ravnovesiya i kinetika. Svoistva rastvorov. Elektrodnye protsessy) (Chemist’s Guide. Vol. 3. Chemical Equilibrium and Kinetics. Properties of Solutions. Electrode Processes), Moscow: Khimiya, 1966.
Prado, J.R. and Vyazovkin, S., Activation energies of water vaporization from the bulk and from laponite, montmorillonite, and chitosan powders, Thermochim. Acta, 2011, vol. 524, nos. 1–2, pp. 197–201.
Shein, E.V., Kurs fiziki pochv: Uchebnik (Course of Soil Physics. A Manual), Moscow: Mosk. Gos. Univ., 2005.
Shein, E.V. and Skvortsova, E.B., Modern devices and methods for studying soil physical properties of soils investigation: 3D tomography, laser diffractometry, rheological properties and contact angle, in Mater. Vseross. konf. s mezhdunarodnym uchastiem “Sovremennye metody issledovaniya pochv i pochvennogo pokrova” (Proc. All-Russ. Conf. with Int. Participation “Modern Methods of Soil and Soil Cover Research”), Moscow: Pochv. Inst. im. V. V. Dokuchaeva, 2015, pp. 148–158.
Smagin, A.V., Physically based mathematical models of the water vapor sorption by soils, Eurasian Soil Sci., 2011, vol. 44, no. 6, pp. 659–669.
Trofimov, V. T., Korolev, V.A., Voznesenskii, E.A., Golodkovskaya, G.A., Vasil’chuk, Yu.K., and Ziangirov, R.S., Gruntovedenie (Soil Science), Trofimov, V.T., Ed., Moscow: Mosk. Gos. Univ., 2005.
Xu, W., Johnston, C.T., Parke, P., and Agnew, S.F., Infrared study of water sorption on Na-, Li-, Ca- and Mg-exchanged (SWy-1 and SAz-1) montmorillonite, Clays Clay Miner., 2000, vol. 48, pp. 120–131.
Zlochevskaya, R.I. and Korolev, V.A., Elektropoverkhnostnye yavleniya v glinistykh porodakh (Electrical Surface Phenomena in Clayey Rocks), Moscow: Mosk. Gos. Univ., 1988.
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This work was supported by the Russian Science Foundation, project no. 17-77-20120.
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Translated by I. Melekestseva
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Rod’kina, I.A., Kazak, E.S. Quantitative Analysis of Bound Water in Rocks of the Bazhenov Formation. Moscow Univ. Geol. Bull. 74, 464–472 (2019). https://doi.org/10.3103/S0145875219050107
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DOI: https://doi.org/10.3103/S0145875219050107