Skip to main content
Log in

Development of a Process for Producing Detonation Nanodiamonds from Tetryl and Binary Compositions Based on It

  • PRODUCTION, STRUCTURE, PROPERTIES
  • Published:
Journal of Superhard Materials Aims and scope Submit manuscript

Abstract

A technology is developed for producing detonation nanodiamonds (DNDs) from individual compounds (tetryl and picric acid) and binary compositions with a tetryl content of ≥50 wt %. A DND yield of up to 7.5 wt % is achieved. The main trends in the dependence of the DND yield on the content of tetryl mixed with TNT, RDX, and picric acid are established. The dependences of the DND content in the diamond batch on the composition of the explosive and the pressure in the Chapman–Jouguet plane are determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

Notes

  1. Hereinafter, the composition is given in wt %.

REFERENCES

  1. Danilenko, V.V., Vzryv: fizika, tekhnika, tekhnologiya (Explosion: Physics, Equipment, and Technology), Moscow: Energoatomizdat, 2010.

  2. Dolmatov, V.Yu., Detonatsionnye nanoalmazy. Poluchenie, svoistva, primenenie (Detonation Diamonds: Synthesis, Properties, and Use), St. Petersburg: Professional, 2011.

  3. Anisichkin, V.F., Mal’kov, I.Yu., and Sagdiev, F.A., Synthesis of diamond by detonation of aromatic nitric compounds, Materialy V Vsesoyuznogo soveshchaniya po detonatsii (Proc. V All-Union Meeting on Detonationa), Krasnoyarsk, 1991, vol. 1, pp. 27–30.

  4. Volk, F., Energy output of insensitive high explosives by measuring the detonation products, Philos. Trans. R. Soc., A, 1992, vol. 339, p. 335.

  5. Volkov, K.V., Danilenko, V.V., and Elin, V.I., Synthesis of diamond from the carbon in the detonation products of explosives, Combust., Explos. Shock Waves (Engl. Transl.), 1990, vol. 26, no. 3, pp. 366–368.

    Article  Google Scholar 

  6. Lyamkin, A.I., The formation of nanodiamonds during the dynamic action on carbon-containing compounds, Doctoral (Phys.–Math.) Dissertation, Krasnoyarsk: Krasnoyarsk State Tech. Univ., 2007.

  7. Vereshchagin, A.L., Detonatsionnye nanoalmazy (Detonation Diamonds), Biisk: Altaisk. Gos. Tekh. Univ., 2001.

  8. Marchukov, V.A., Kolodyazhnyi, A.L., Makarov, I.A., Korolev, K.M., and Suschev V.G., RF Patent 2599665, 2016.

  9. Titov, V.M., Anisichkin, V.F., and Mal’kov, I.Yu., Synthesis of ultradispersed diamond in detonation waves, Combust., Explos. Shock Waves (Engl. Transl.), 1989, vol. 25, no. 3, pp. 372–379.

    Article  Google Scholar 

  10. Petrov, E.A., Physicochemical processes of detonation synthesis of nanodiamonds, Materialy Mezhdunarodnoi nauchno-tekhnicheskoi i metrologicheskoi konferentsii, 22–24 dekabrya 2004 g. (Proc. Int. Sci.-Tech. and Metrological Conf., December 22–24, 2004), Kazan, 2004, pp. 881–888.

  11. Dolmatov, V.Yu., Vehanen, A., Myllymäki, V., Kozlov, A.S., and Nguyen, T.T.B., Effect of armoring composition on the yield of nanodiamonds and content of impurities, Russ. J. Appl. Chem., 2018, vol. 91, no. 2, pp. 225−229.

    Article  CAS  Google Scholar 

  12. Dolmatov, V.Yu., Vehanen, A., and Myllymäki, V., The influence of aqueous armor composition for TNT–RDX explosive charge on the yield and quality of detonation nanodiamond and diamond-containing soot in detonation synthesis, J. Superhard Mater., 2017, vol. 39, no. 2, pp. 143–146.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. Yu. Dolmatov.

Additional information

Translated by O. Kadkin

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dolmatov, V.Y., Malygin, A.A., Dorokhov, A.O. et al. Development of a Process for Producing Detonation Nanodiamonds from Tetryl and Binary Compositions Based on It. J. Superhard Mater. 42, 145–156 (2020). https://doi.org/10.3103/S1063457620030053

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1063457620030053

Keywords:

Navigation