Abstract
Phosphorylthioformic acid morpholides can be successfully used as a precursor in the synthesis of complexes of phosphoryl-substituted thiohydrazides with hydrazine and morpholine. The reaction of sterically hindered phosphorylthioformic acid morpholides with hydrazine hydrate proceeds chemoselectively with the formation of hydrazono(morpholino)methylphosphodiamides.
This is a preview of subscription content, log in via an institution to check access.
References
T. Murai, Chemistry of Thioamides, Springer, 2019, 1.
S. Majnooni, J. Duffield, J. Price, A. R. Khosropour, H. Zali-Boeini, M. H. Beyzavi, ACS Comb. Sci., 2019, 21, 516.
M. S. Yadav, A. S. Singh, A. K. Agrahari, N. Mishra, V. K. Tiwari, ACS Omega, 2019, 4, 6681.
A. Y. Aksinenko, A. N. Pushin, V. B. Sokolov, Phosphorus, Sulfur, Silicon, Relat. Elem., 2019, 194, 775.
M. Barikani, S. Mehdipour-Ataei, J. Polym. Sci., Part A: Polym. Chem., 2000, 38, 1487.
S. Ankushrao, V. Gugwad, V. Ubale, N. Maldar, A. Ghanwat, Polym. Sci., Ser. B, 2018, 60, 263.
M. A. Kozlov, Y. A. Volkova, I. V. Zavarzin, Russ. Chem. Bull., 2019, 68, 2105.
M. Kozlov, A. Kozlov, A. Komkov, K. Lyssenko, I. Zavarzin, Y. Volkova, Adv. Synth. Catal., 2019, 361, 2904.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1604–1606, August, 2020.
This work was financially supported by the Russian Science Foundation (Project No. 18-73-00321).
Rights and permissions
About this article
Cite this article
Kozlov, M.A., Volkova, Y.A. & Zavarzin, I.V. New transformations of phosphorylthioformic acid morpholides. Russ Chem Bull 69, 1604–1606 (2020). https://doi.org/10.1007/s11172-020-2943-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-020-2943-z