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Study of the structure and electrical conductivity of lithium-conducting polymer electrolytes based on PEG-1500—LiX (X = SCN, N(CF3SO2)2)

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Abstract

A comprehensive study of lithium-conducting polymer electrolytes based on polyethylene glycol 1500 and lithium salts (LiSCN and LiN(CF3SO2)2) was carried out using thermogravimetry, differential thermal analysis, electrometry, and vibrational spectroscopy. Their phase composition was refined, structural changes resulting from varying the concentration of lithium salts were determined, the most probable structures of complex solvate and ionic complexes were established.

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Authors and Affiliations

  1. Analytical Center for Collective Use, Dagestan Federal Research Center of the Russian Academy of Sciences, 45 ul. M. Gadzhieva, 367000, Makhachkala, Russian Federation

    M. M. Gafurov, M. A. Akhmedov, K. Sh. Rabadanov, N. S. Shabanov, A. M. Amirov, S. I. Suleymanov & M. B. Ataev

Authors
  1. M. M. Gafurov
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  2. M. A. Akhmedov
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  3. K. Sh. Rabadanov
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  4. N. S. Shabanov
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  5. A. M. Amirov
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  6. S. I. Suleymanov
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  7. M. B. Ataev
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Corresponding author

Correspondence to M. A. Akhmedov.

Additional information

Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1463–1469, August, 2020.

The study was carried out using the equipment of the Analytical Center for Collective Use, Dagestan Federal Research Center of the Russian Academy of Sciences.

This work was financially supported by the Ministry of Higher Education and Science of the Russian Federation (state assignment No. NIOKRAAAA-A18-118011800129-4).

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Gafurov, M.M., Akhmedov, M.A., Rabadanov, K.S. et al. Study of the structure and electrical conductivity of lithium-conducting polymer electrolytes based on PEG-1500—LiX (X = SCN, N(CF3SO2)2). Russ Chem Bull 69, 1463–1469 (2020). https://doi.org/10.1007/s11172-020-2924-2

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  • DOI: https://doi.org/10.1007/s11172-020-2924-2

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