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Silicon-containing polyimides: synthesis, properties, and application as optical fiber light guide coatings

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Abstract

Organosoluble polyimides with tetramethyldisiloxane fragments in the main chain were synthesized by one-step high-temperature polycondensation and their properties were studied. Heat resistant polymers (Tg = 195–240 °C, T10% = 420–490 °C) were tested as protective coatings for quartz optical fibers. The new developed coatings have high thermal (72 h at 300 °C) and hydrolytic stability.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. A. Sapozhnikov, A. V. Chuchalov, B. A. Bayminov, P. A. Shibaeva, E. M. Chaika, M. I. Buzin & Ya. S. Vygodskii

  2. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    A. V. Chuchalov & P. A. Shibaeva

  3. Fiber Optics Research Center, Russian Academy of Sciences, 38 ul. Vavilova, 119333, Moscow, Russian Federation

    A. F. Kosolapov & S. L. Semjonov

Authors
  1. D. A. Sapozhnikov
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  2. A. V. Chuchalov
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  3. B. A. Bayminov
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  4. P. A. Shibaeva
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  5. E. M. Chaika
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  6. M. I. Buzin
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  7. A. F. Kosolapov
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  8. S. L. Semjonov
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  9. Ya. S. Vygodskii
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Corresponding author

Correspondence to D. A. Sapozhnikov.

Additional information

Based on the materials of the International Conference “Chemistry of Organoelement Compounds and Polymers 2019” (November 18–22, 2019, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1486–1491, August, 2020.

The authors are grateful to E. S. Afanas’ev for conducting thermomechanical tests of polymers.

This work was financially supported by the Russian Foundation for Basic Research (Project No. 18-29-17035_mk). Studies of polymer properties were financially supported by the Ministry of Science and Higher Education of the Russian Federation.

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Sapozhnikov, D.A., Chuchalov, A.V., Bayminov, B.A. et al. Silicon-containing polyimides: synthesis, properties, and application as optical fiber light guide coatings. Russ Chem Bull 69, 1486–1491 (2020). https://doi.org/10.1007/s11172-020-2927-z

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  • DOI: https://doi.org/10.1007/s11172-020-2927-z

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