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Conductivity increase effect in nanocomposite polymer gel electrolytes: manifestation in the IR spectra

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Abstract

Nanocomposite polymer electrolytes based on poly(ethylene glycol) diacrylate and 1 M LiBF4 solution in γ-butyrolactone containing SiO2 nanoparticles were studied by FT IR spectroscopy. Quantum chemical modeling of five different solvate complexes of ions composed of LiBF4 with solvent molecules was carried out and their theoretical IR spectra were calculated. The compositions of the solvate complexes of LiBF4 in the nanocomposite gel electrolyte were studied by comparing the experimental and theoretical IR spectra. It was concluded that the conductivity peak observed upon adding 2 wt.% SiO2 is due to the appearance of mobile ions as a consequence of ionic dissociation on the surface of nanoparticles at their optimal configuration.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. V. Yudina, G. R. Baymuratova, G. Z. Tulibaeva, A. L. Litvinov, A. F. Shestakov & O. V. Yarmolenko

  2. Faculty of Fundamental Physical and Chemical Engineering, M. V. Lomonosov Moscow State University, Build. 51, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    A. F. Shestakov

Authors
  1. A. V. Yudina
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  2. G. R. Baymuratova
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  3. G. Z. Tulibaeva
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  4. A. L. Litvinov
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  5. A. F. Shestakov
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  6. O. V. Yarmolenko
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Corresponding author

Correspondence to O. V. Yarmolenko.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1455–1462, August, 2020.

This work was carried out as part of the State Assignment (State Registration No. AAAA-A19-119071190044-3).

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Yudina, A.V., Baymuratova, G.R., Tulibaeva, G.Z. et al. Conductivity increase effect in nanocomposite polymer gel electrolytes: manifestation in the IR spectra. Russ Chem Bull 69, 1455–1462 (2020). https://doi.org/10.1007/s11172-020-2923-3

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  • DOI: https://doi.org/10.1007/s11172-020-2923-3

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