Abstract
Novel composite of reduced graphene oxide/zirconium hexacyanoferrate (rGO/ZrHCF) was fabricated via electrochemical deposition and used as a sensor for detecting sodium nitrite and ferulic acid. The sensor was thoroughly characterized using scanning electron microscope, DRS-UV, attenuated total reflection IR spectroscopy as well as atomic force microscopy. The rGO/ZrHCF exhibited cube-like morphology of ZrHCF on multilayered rGO sheets. Electrochemical characterization was carried out using cyclic voltammetry and square wave voltammetry for the detection of ferulic acid and sodium nitrite. Ferulic acid and sodium nitrite are used as food additives and the overdose of either of them can result in various physiological ailments and necessitates their detection. The proposed sensor could detect both sodium nitrite and ferulic acid at nanomolar levels exhibiting linearity in the range of 1.14 to 13.77 nM and 3.23 to 41.98 nM, respectively. The corresponding limit of detection was 0.38 nM and 1.39 nM. The rGO/ZrHCF-modified electrode was checked for real sample analysis by carrying out determination of sodium nitrite and ferulic acid in water and milk samples and the recovery percentages were found to be in between 96.15 and 99.80. The sensor exhibited long-term stability and reproducibility.
Similar content being viewed by others
References
B.J. Kim, L.J. Cote, J. Huang, Acc. Chem. Res. 45, 1356–1364 (2012)
S.H. Aboutalebi, A.T. Chidembo, M. Salari, K. Konstantinov, D. Wexler, H.K. Liu, S.X. Dou, Energy Environ. Sci. 4, 1855–1865 (2011)
K. Cui, G. Li, L. Wang, W. Guo, M. Pei, J. Electrochem. Soc. 167, 027508 (2020)
M. Zhou, Y. Zhai, S. Dong, Anal. Chem. 81, 5603–5613 (2009)
M. Coros, C. Socaci, S. Pruneanu, F. Pogacean, M.C. Rosu, A. Turza, L. Magerusan, Environ. Res. 182, 109047 (2020)
F. Magesa, Wu Yiyong, S. Dong, Y. Tian, G. Li, J.M. Vianney, J. Buza, J. Liu, Q. He, Biomolecules 10, 110 (2020)
M.Z. Ansari, R. Johari, W.A. Siddiqi, Mater. Res. Express 6, 055027 (2019)
S. Pei, H.-M. Cheng, Carbon 50, 3210–3228 (2012)
Y.J. Yun, J. Ju, J.H. Lee, S.-H. Moon, S.-J. Park, Y.H. Kim, W.G. Hong, D.H. Ha, H. Jang, G.H. Lee, H.-M. Chung, J. Choi, S.W. Nam, S.-H. Lee, Y. Jun, Adv. Funct. Mater. 27, 1701513 (2017)
C.W. Foster, M.P. Down, Y. Zhang, X. Ji, S.J. Rowley-Neale, G.C. Smith, P.J. Kelly, Sci. Rep. 7, 42233 (2017)
M. Skoda, I. Dudek, D. Szukiewicz, Carbon Nanostruct. 3–33 (2016)
Z. Zhu, Nano-Micro Lett. 9, 1–24 (2017)
I.A.R.B. Dias, W.M. Costa, P. Cervini, E.T.G. Cavalheiro, A.L.B. Marques, Electroanalysis 28, 2136–2142 (2016)
G. Kasiri, R. Trocoli, F. La Mantia, Electrochim. Acta 222, 74–83 (2016)
G.-Y. Wen-RongCai, DanShan TaoSong, Electrochim. Acta 198, 32–39 (2016)
C.-J. Shen-MingChen, Electrochim. Acta 50, 115–125 (2004)
P.R. Oliveira, A.F. Schibelbain, E.G.C. Neiva, A.J.G. Zarbin, M.F. Bergamini, Sens. Actuators B 260, 816–823 (2018)
H. Peng, M. Zhou, J. Peng, F. Anal, Methods 9, 942–949 (2016)
S.-Q. Liu, Y. Chen, H.-Y. Chen, Electroanalysis 14, 2 (2002)
Z. Almasvandi, A. Vahidinia, A. Heshmati, M.M. Zangeneh, H.C. Goicoechea, A.R. Jalalvand, RSC Adv. 10, 14422–14430 (2020)
A.D. van den Brand, M. Beukers, M. Niekerk, G. van Donkersgoed, M. van der Aa, B. van de Ven, Food Addit. Contamin. 37, 568–582 (2020)
M. Srinivasan, A.R. Sudheer, V.P. Menon, J. Clin. Biochem. Nutr. 40, 92–100 (2007)
Y.-Y. Yua, Q.-S. Wua, X.-G. Wang, Y.-P. Ding, Russ. J. Electrochem. 45, 170–174 (2009)
Z. Xia, Y. Zhang, Q. Li, H. Du, G. Gui, G. Zhao, Int. J. Electrochem. Sci. 15, 559 (2020)
X. Li, Na Zou, Z. Wang, Y. Sun, H. Li, C. Gao, T. Wang, X. Wang, Chem. Pap. 74, 441 (2020)
M.D.A. Rashed, M. Faisa, F.A. Harraz, M. Jalalah, M. Alsaiari, M.S. Al-Assiri, J. Taiwan Inst. Chem. Eng. (2020)
F.J. Jency, R. Manikandan, S.S. Narayanan, P.N. Deepa, J. Chem. Sci. 131, 11 (2019)
Z. Yin, S. Wu, X. Zhou, X. Huang, Q. Zhang, F. Boey, H. Zhang, Small. 6, 307 (2010)
M.K. Ramos, A.J.G. Zarbin, Appl. Surf. Sci. 515, 146000 (2020)
S. Saranya, J.J. Feminus, B. Geetha, P.N. Deepa, Ionics 25, 5537–5550 (2019)
S. Yanga, G. Li, G. Wang, J. Zhao, Z. Qiao, Qu Lingbo, Sens. Actuators B 206, 126–132 (2015)
G.-Y. Zhang, S.-Y. Deng, W.-R. Cai, S. Cosnier, X.-J. Zhang, D. Shan, Anal. Chem. 87(17), 9093–9100 (2015)
S.-Q. Liu, Y. Chen, H.-Y. Chen, J. Electroanal. Chem. 502, 197–203 (2001)
J.X. Dong, N.B. Li, H.Q. Luo, Anal. Methods. 5, 5541 (2013)
S. Saranya, R. Agneeswaran, P.N. Deepa, ACS Omega. 5(2), 1040–1051 (2020)
K. Giribabu, R. Suresh, R. Manigandan, S. Munusamy, S.P. Kumar, S. Muthamizh, V. Narayanan, Analyst 138, 5811–5818 (2013)
R.M. Abdel Hameed, S.S. Medany, Microchem. J. 145, 354–366 (2019)
L. Liu, Y. Gou, X. Gao, P. Zhang, W. Chen, S. Feng, Hu Fangdi, Y. Li, Mater. Sci. Eng. C 42, 227–233 (2014)
G. Liu, M. Qi, Y. Zhang, C. Cao, E.M. Goldys, Anal. Chim. Acta 909, 1–8 (2016)
T.R. Silva, D. Brondani, E. Zapp, I. Cruz Vieira, Electroanalysis 27(2), 465–472 (2015)
R. Manikandan, V.K. Ponnusamy, S.N. Sangilimuthu, Environ. Sci. Pollut. Res. 27, 17481–17491 (2020)
R. Mo, X. Wang, Q. Yuan, X. Yan, Su Tiantian, Y. Feng, L. Lv, C. Zhou, P. Hong, S. Sun, Z. Wang, C. Li, Sensors. 18(7), 1986 (2018)
A.D. Arulraj, E. Sundaram, V.S. Vasantha, B. Neppolian, N. J. Chem. 42, 3748–3757 (2018)
R. Settu, S.-M. Chen, T.-W. Chen, G. Sharmila, J. Colloid Interface Sci. 524, 417–426 (2018)
J. Hu, J. Zhang, Z. Zhao, J. Liu, J. Shi, G. Li, P. Li, W. Zhang, K. Lian, S. Zhuiykov, Ionics 24, 577–587 (2018)
K.N. Nithyayini, M.N.K. Harish, K.L. Nagashree, Electrochim. Acta 317, 701–710 (2019)
Z. Fan, Z. Ding, X. Zhang, S. Wu, M. Wang, Z. Tong, Mater. Lett. 253, 281–284 (2019)
B.P. Suma, M. Pandurangappa, J. Solid State Electrochem. 24, 69–79 (2020)
G. Kaladevi, P. Wilson, K. Pandian, J. Electrochem. Soc. 167, 027514 (2020)
X. Yue, X. Luo, Z. Zhou, Wu Yongmei, Y. Bai, New J. Chem. 43, 4947–4958 (2019)
H. Chen, T. Yang, F. Liu, W. Li, Sens. Actuators B. 286, 401–407 (2019)
Yu Zhi Xia, Q.L. Zhang, Du Haijun, G. Gui, G. Zhao, Int. J. Electrochem. Sci. 15, 559–566 (2020)
T. Zabihpour, S.-A. Shahidi, H. Karimi-Maleh, A.G.-H. Saraei, Microchem. J. 154, 104572 (2020)
T. Zabihpour, S.-A. Shahidi, H.K. Maleh, A.G.-H. Saraei, Euras. Chem. Commun. 2, 362–373 (2019)
A.T.E. Vilian, S.M. Chen, Microchim. Acta 182, 1103–1111 (2015)
V. Erady, R.J. Mascarenhas, A.K. Satpati, S. Detriche, Z. Mekhalif, J. Dalhalle, A. Dhason, J. Electroanal. Chem. 806, 22–31 (2017)
R. Abdel-Hamid, E.F. Newair, Nanomaterials. 5(4), 1704–1715 (2015)
Y. Zhang, Y. Liu, Z. Yang, Y. Yang, P. Pang, Y. Gao, Hu Qiufen, Anal. Methods 5, 3834–3839 (2013)
L. Luo, X. Wang, Q. Li, Y. Ding, J. Jia, D. Deng, Anal. Sci. 26, 907–911 (2010)
M. Moreno, A.S. Arribas, E. Bermejo, A. Zapardiel, M. Chicharro, Electrophoresis 32, 877–883 (2011)
X.-G. Wang, J. Li, Y.-J. Fan, X. Zhang, Russ. J. Electrochem. 48, 1160–1165 (2012)
Funding
This work has not been supported by any funding agencies.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Saranya, S., Deepa, P.N. Evolution of novel rGO/ZrHCF composite and utility in electrocatalysis towards nanomolar detection of sodium nitrite and ferulic acid. J Mater Sci: Mater Electron 31, 18923–18936 (2020). https://doi.org/10.1007/s10854-020-04430-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-020-04430-3