A highly stable octa-coordinated energetic complex

Wenchao Tong; Mei Bian; Yongan Feng; Tonglai Zhang; Shuangqi Hu; Li Yang

doi:10.1039/D0CE01008A

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A highly stable octa-coordinated energetic complex†

Wenchao Tong,^a Mei Bian,^a Yongan Feng,

*^b Tonglai Zhang,

^a Shuangqi Hu^b and Li Yang

*^a

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* Corresponding authors

^a State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
E-mail: yanglibit@bit.edu.cn

^b School of Environmental and Safety Engineering, North University of China, Taiyuan 030051, China
E-mail: fengyongan0918@126.com

Abstract

The quest for high-energy-density materials (HEDMs) based on transition metal complexes is focused on low-coordinate species. High-coordinate analogues are extremely rare. Here, the first example of a highly energetic complex (HEC) with the highest coordination number of eight in 3d metal coordination chemistry is reported. Its structure was confirmed by single crystal X-ray diffraction. Its remarkably high stability has also been investigated.

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DOI: https://doi.org/10.1039/D0CE01008A
Article type: Communication
Submitted: 13 Jul 2020
Accepted: 10 Sep 2020
First published: 14 Sep 2020

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CrystEngComm, 2020,22, 6591-6595

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A highly stable octa-coordinated energetic complex

W. Tong, M. Bian, Y. Feng, T. Zhang, S. Hu and L. Yang, CrystEngComm, 2020, 22, 6591 DOI: 10.1039/D0CE01008A

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CrystEngComm

A highly stable octa-coordinated energetic complex†

Abstract

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Article information

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A highly stable octa-coordinated energetic complex

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