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Model Medium with the Thermal and Transport Properties of Liquid Water

  • RADIOSPECTROMETRIC METHODS IN SCIENCES OF LIFE
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Abstract

A model of a Frenkel gas–solid system that consists of H2O molecules and H3O+ and OH– ions and has the same density and particle concentration as liquid water has been considered. Particles execute thermal vibrational–diffusion motion, in the course of which they collide, exchange protons, and interconvert. Under the assumption that the medium persists owing to ion–dipole forces, it has been shown that enthalpy of vaporization H, heat capacity C, and the transport parameters of the medium (self-diffusion coefficient D, viscosity η, and thermal conductivity θ) are close to reference values for liquid water throughout the temperature interval of its existence (250–600 K).

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REFERENCES

  1. L. G. M. Pettersson, R. H. Henchman, and A. Nilsson, Chem. Rev. 116, 7459 (2016). https://doi.org/10.1021/acs.chemrev.6b00363

    Article  Google Scholar 

  2. J. L. Aragones, J. Phys. Chem. A 115, 5745 (2011). https://doi.org/10.1021/jp105975c

    Article  Google Scholar 

  3. A. A. Volkov, V. G. Artemov, and A. V. Pronin, Eur. Phys. Lett. 106, 46004 (2014). https://doi.org/10.1209/0295-5075/106/46004

    Article  ADS  Google Scholar 

  4. A. A. Volkov, V. G. Artemov, A. A. Volkov, Jr., and N. N. Sysoev, J. Mol. Liq. 248, 564 (2017). https://doi.org/10.1016/j.molliq.2017.10.071

    Article  Google Scholar 

  5. J. I. Frenkel, Kinetic Theory of Liquids (Dover, New York, 1955).

    MATH  Google Scholar 

  6. D. Eisenberg and W. Kauzmann, The Structure and Properties of Water (Oxford Univ. Press, New York, 1969).

  7. G. G. Malenkov, J. Struct. Chem. 47, S1 (2006). https://doi.org/10.1007/s10947-006-0375-8

    Article  Google Scholar 

  8. J. O’M. Bockris and A. K. N. Reddy, Modern Electrochemistry. 1. Ionics (Plenum, New York, 1998).

    Google Scholar 

  9. N. Agmon, J. Phys. Chem. 100, 1072 (1996). https://doi.org/10.1021/jp9516295

    Article  Google Scholar 

  10. L. D. Landau and E. M. Lifshitz, Course of Theoretical Physics. Vol. 8: Electrodynamics of Continuous Media, 2nd ed. (Pergamon, Oxford, 1984).

    Google Scholar 

  11. A. A. Volkov, A. A. Vasin, and A. A. Volkov, Jr., Bull. Russ. Acad. Sci.: Phys. 84 (1), 48 (2020). https://doi.org/10.3103/S1062873820010281

    Article  Google Scholar 

  12. J. Stepisnik, A. Mohoric, and I. Sersa, arXiv:1010.1175v1 (2010).

  13. A. A. Volkov, A. A. Vasin, and A. A. Volkov, Jr., Ferroelectrics 538, 83 (2019). https://doi.org/10.1080/00150193.2019.1569989

    Article  Google Scholar 

  14. The International Association for the Properties of Water and Steam (IAPWS), Releases. http://www.iapws.org/release.html

  15. K. Okada, M. Yao, Y. Hiejima, H. Kohno, and Y. Kajihara, J. Chem. Phys. 110, 3026 (1999). https://doi.org/10.1063/1.477897

    Article  ADS  Google Scholar 

  16. Ph. L. Geissler, C. Dellago, D. Chandler, J. Hutter, and M. Parrinello, Science 291, 2121 (2001). https://doi.org/10.1126/science.1056991

    Article  ADS  Google Scholar 

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Funding

This study was supported by the Russian Foundation for Basic Research, grant no. 19-0200446-A.

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Authors and Affiliations

  1. Prokhorov General Physics Institute, Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Vasin & A. A. Volkov

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  1. A. A. Vasin
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  2. A. A. Volkov
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Correspondence to A. A. Volkov.

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Translated by V. Isaakyan

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Vasin, A.A., Volkov, A.A. Model Medium with the Thermal and Transport Properties of Liquid Water. Tech. Phys. 65, 1411–1415 (2020). https://doi.org/10.1134/S1063784220090285

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