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“Golden Age” of Homogeneous Catalysis Chemistry of Alkynes: Dimerization and Oligomerization of Alkynes

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Abstract

History of the development and use of homogeneous metal complex catalysts in the chemistry of acetylene and its derivatives is considered. Achievements of the catalytic chemistry of alkynes in the creation of affective catalytic systems (based on Groups 3—11 and 13 of the Periodic Table) for alkyne dimerization, capable of producing desired dimeric isomers possessing high chemo-, stereo- and regioselectivity are analyzed. The nature of elementary stages in four mechanisms of dimerization and the relations of the nature of organometallic intermediates to the nature of catalyst (metal and ligand), substrate, and type of mechanism, and, hence, to the selectivity of dimerization process are discussed.

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ACKNOWLEDGMENTS

The author is grateful to Karen Egiazaryan, student of the MIREA – Russian Technological University (Moscow), for his help in graphical presentation of this review.

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  1. MIREA—Russian Technological University, M.V. Lomonosov Moscow State University of Fine Chemical Technology, 119571, Moscow, Russia

    O. N. Temkin

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  1. O. N. Temkin
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Correspondence to O. N. Temkin.

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Dedicated to “Kinetika i Kataliz” journal on its 60 Years Edition Anniversary, and to academician I.I. Moiseev, one of the creators of modern catalysis with metal complexes, on his 90th birthday

Translated by P. Pozdeev

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Temkin, O.N. “Golden Age” of Homogeneous Catalysis Chemistry of Alkynes: Dimerization and Oligomerization of Alkynes. Kinet Catal 60, 689–732 (2019). https://doi.org/10.1134/S0023158419060120

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  • DOI: https://doi.org/10.1134/S0023158419060120

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