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Mössbauer Study of the Effect of Cation Substitutions on the Magnetic Phase Transitions in BiFe1 – xCrxO3 and (1 – x)BiFeO3–xPbFe0.5Sb0.5O3 Solid Solutions

  • PROCEEDINGS OF THE XV INTERNATIONAL CONFERENCE “MÖSSBAUER SPECTROSCOPY AND ITS APPLICATIONS”
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Abstract—

The concentration dependences of the magnetic phase transition temperature TN, determined based on the changes in Mössbauer spectra, were investigated for a BiFeO3 solid solution with ordered perovskite PbFe0.5Sb0.5O3 and for a disordered BiFe1 – xCrxO3 solid solution. It is established that the magnetic-order type in BiFe1 – xCrxO3 changes from antiferromagnetic to spin-glass at a higher degree of Fe-sublattice dilution in comparison with the PbFe0.5Nb0.5O3-based solid solutions presumably because of the smaller BiFeO3 lattice parameter. Due to the local ordering of Fe3+ and Sb5+ ions, the TN value decreases more rapidly (as compared to BiFe1 – xCrxO3) with a decrease in the Fe3+ content in the lattice of (1 – x)BiFeO3– xPbFe0.5Sb0.5O3 solid solutions.

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Funding

This study was supported in part by the Russian Foundation for Basic Research (project no. 18-52-00029 Bel_a), Belarusian Republican Foundation for Basic Research (project no. T18R-048), Ministry of Science and Higher Education of the Russian Federation (project nos. 3.1649.2017/4.6 and 3.5346.2017/8.9), and a scholarship of the President of the Chinese Academy of Sciences (project no. 2018VEA0011).

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Authors and Affiliations

  1. Research Institute of Physics, Southern Federal University, 344090, Rostov-on-Don, Russia

    S. P. Kubrin, V. V. Titov & M. A. Malitskaya

  2. Faculty of Physics, Southern Federal University, 344006, Rostov-on-Don, Russia

    I. P. Raevski & S. I. Raevskaya

  3. Scientific and Practical Materials Research Centre, National Academy of Sciences of Belarus, 220076, Minsk, Belarus

    N. M. Olekhnovich, A. V. Pushkarev & Yu. V. Radyush

  4. Shanghai Institute of Ceramics, Chinese Academy of Sciences, 200050, Shanghai, China

    Guorong Li

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  1. S. P. Kubrin
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  2. I. P. Raevski
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  3. N. M. Olekhnovich
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  4. A. V. Pushkarev
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  5. Yu. V. Radyush
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  6. V. V. Titov
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  7. M. A. Malitskaya
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  8. Guorong Li
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  9. S. I. Raevskaya
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Correspondence to S. P. Kubrin.

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Translated by Yu. Sin’kov

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Kubrin, S.P., Raevski, I.P., Olekhnovich, N.M. et al. Mössbauer Study of the Effect of Cation Substitutions on the Magnetic Phase Transitions in BiFe1 – xCrxO3 and (1 – x)BiFeO3–xPbFe0.5Sb0.5O3 Solid Solutions. Crystallogr. Rep. 65, 338–342 (2020). https://doi.org/10.1134/S1063774520030165

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  • DOI: https://doi.org/10.1134/S1063774520030165

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