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Encapsulation of Phosphomolybdate Within Metal–Organic Frameworks with Dual Enzyme-like Activities for Colorimetric Detection of H2O2 and Ascorbic acid

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Abstract

Developing artificial enzyme mimetics for the detection of small biomolecules are a current research interest because natural enzymes bear some serious disadvantages, such as their catalytic activity can be easily inhibited and they can be digested by proteases. Herein, a heteropoly acids (HPA) encapsulating metal–organic framework (MOF) with metal-carbene structure, [Cu10(H3trz)4(Htrz)4][PMo12VO41] (PMA-MOF) as bifunctional enzyme-mimetic catalyst for colorimetric detection of hydrogen peroxide (H2O2) and ascorbic acid (AA) was designed and synthesized. Thanks to the good stability and the synergistic effect of PMA and MOF, PMA-MOF exhibits the lower limit of detection (0.222 μM towards H2O2 and 0.0046 μM to AA), and the smaller Km value (0.0138 mM for H2O2 and 0.136 mM for o-phenylenediamine) compared to most reported MOF- and HPA-based enzyme-mimetic catalyst, to the best our knowledge.

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Authors and Affiliations

  1. Department of pharmacy, Gaomi People’s Hospital, Shandong, China

    Deqiang Wang, Zuoji Li, Qian Zhao, Jianguo Zhang, Guang Yang & Hui Liu

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  1. Deqiang Wang
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  2. Zuoji Li
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  4. Jianguo Zhang
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Wang, D., Li, Z., Zhao, Q. et al. Encapsulation of Phosphomolybdate Within Metal–Organic Frameworks with Dual Enzyme-like Activities for Colorimetric Detection of H2O2 and Ascorbic acid. J Clust Sci 32, 1175–1183 (2021). https://doi.org/10.1007/s10876-020-01883-8

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  • DOI: https://doi.org/10.1007/s10876-020-01883-8

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