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Protective Effect of TEA on Templated-SAPO-34 Structure During Aqueous Zn Modification Process

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Abstract

Zn-modified SAPO-34 zeolites with different SAPO-34 intermediates were prepared by an impregnation method, and their catalytic performance in MTO reaction was systematically studied. The physicochemical properties of all samples were characterized by XRD, SEM, N2 adsorption-desorption, NH3-TPD, FTIR, and XRF. The results show that the template, here TEA, has a protective effect on Templated-SAPO-34 structure during aqueous Zn modification process, which affects the structural integrity of Zn/Temp.-SAPO-34 zeolite and thus determines its product distribution. The prepared Zn/Temp.-SAPO-34 zeolite is a highly selective catalyst for ethene production from methanol, with the highest reported ethene to propene ratio of 2.00.

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Acknowledgements

This work is supported by China University of Petroleum for Postgraduate Technology Innovation Project (YCX2019036).

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Authors and Affiliations

  1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, 266580, China

    Huiwen Huang, Mengyun Yu, Qiang Zhang & Chunyi Li

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  1. Huiwen Huang
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  2. Mengyun Yu
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  3. Qiang Zhang
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  4. Chunyi Li
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Correspondence to Qiang Zhang or Chunyi Li.

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Huang, H., Yu, M., Zhang, Q. et al. Protective Effect of TEA on Templated-SAPO-34 Structure During Aqueous Zn Modification Process. Catal Lett 150, 3269–3275 (2020). https://doi.org/10.1007/s10562-020-03211-1

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