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Synthesis of Pt@MAF-6 as a Steric Effect Catalyst for Selective Hydrogenation of Cinnamaldehyde

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Abstract

Pt@MAF-6 was designed as a highly selective catalyst for cinnamaldehyde hydrogenation. The aperture of Pt@MAF-6 acted to sterically confine cinnamaldehyde, and 94% selectivity to cinnamic alcohol was obtained at a high conversion of 95%. Steric confinement was inefficient in trans-2-pentenal hydrogenation, showing that encapsulating active sites within a commensurate porous support is important for a steric effect catalyst.

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Acknowledgement

This work was supported by the National Natural Science Foundation of China (no. 21676155), PetroChina Innovation Foundation (2016D-5007–0507), China Postdoctoral Science Foundation (2019M660660), and Shuimu Tsinghua Scholar program.

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Authors and Affiliations

  1. Beijing Key Laboratory of Green Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing, 100084, China

    Kaizhen Xue, Xiaocheng Lan, Jinfu Wang & Tiefeng Wang

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  1. Kaizhen Xue
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  2. Xiaocheng Lan
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  3. Jinfu Wang
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  4. Tiefeng Wang
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Correspondence to Tiefeng Wang.

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Xue, K., Lan, X., Wang, J. et al. Synthesis of Pt@MAF-6 as a Steric Effect Catalyst for Selective Hydrogenation of Cinnamaldehyde. Catal Lett 150, 3234–3242 (2020). https://doi.org/10.1007/s10562-020-03212-0

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  • DOI: https://doi.org/10.1007/s10562-020-03212-0

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