Abstract
Fe type clay minerals, Fe–montmorillonite, are expected to form in the nuclear waste repositories over a span of few years owing to the interaction of corrosion products from overpack and/or canister with bentonite consisting of montmorillonite (Mt) as the major clay mineral. Therefore, it is important to understand the properties of altered clay minerals, Fe–Mt. In the present study, the sorption behaviour of 133Ba(II), one of the high-yield fission products of uranium-based fuels and analogue of 90Sr (t1/2 = 28.5 y), on Fe(II)–Mt and Fe(III)–Mt has been investigated. Retention behavior of Ba(II) on Fe–Mt has been studied at varying pH (3–9), ionic strength (0.001 M–1 M) and Ba(II) concentration (10−9–10−3 M) by batch sorption method. The distribution coefficient (Kd) of Ba(II) on Fe–Mt was found to be nearly independent of pH while it decreased with increasing ionic strength indicating ion exchange as the dominant Ba(II) sorption mode on Fe–Mt. Adsorption isotherm of Ba(II) exhibited linearity in the entire Ba(II) concentration range. A comparison of Ba(II) sorption behavior on Fe–Mt and Na–Mt has been made. The Fe released from both Fe(III)–Mt and Fe(II)–Mt was measured in all the sorption experiments and was found to be much less in the case of Fe(III)–Mt (≤ 1.7 ppm) when compared to Fe(II)–Mt (~ 25 ppm). The modeling of Ba(II) sorption profiles on Fe–Mt and Na–Mt has been carried out using FITEQL 4.0.
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References
ANDRA (2005) Dossier 2005 argile—Tome—phenomenologique du stockagegeologique. Rapport Andra no. C.RP.ADS.04.0025, France
Atum G, Bascetin E (2003) Adsorption of barium on kaolinite, illite and montmorillonite at various ionic strengths. Radiochim Acta 91:223–228
Bascetina E, Atun G (2006) Adsorption behavior of strontium on binary mineral mixtures of montmorillonite and kaolinite. Appl Radiat Isot 64:957–964
Bradbury MH, Baeyens B (2000) A generalized sorption model for the concentration dependent uptake of caesium by argillaceous rocks. J Contamin Hydrol 42:141–163
Bradbury MH, Baeyens B (2002) Sorption of Eu on Na- and Ca–montmorillonites: experimental investigations and modelling with cation exchange and surface complexation. Geochim Cosmochim Acta 66:2325–2334
Brigatti MF, Galan E, Theng BKG (2006) Structures and mineralogy of clay minerals. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Oxford
Cathelineau M, Guillaume D, Mosser-Ruck R, Dubessy J, Charpentier D, Villieras F, Michau N (2005) Dissolution–crystallization processes affecting di-octahedral smectite in presence of iron metal: implication on mineral distribution in clay barriers. In: International meeting on clays in natural and engineered barriers for radioactive waste confinement. Tours, France, p 35
Cathelineau M, Mosser-Ruck R, Rousset D, Guillaume D, Charpentier D, Devineau K, Villieras F, Michau N (2007) Effects of temperature, pH, iron/clay ratio and liquid/clay ratio on the conversion of di-octahedral smectite into iron-rich clays: a review of experimental studies. In: Interantional meeting on clays in natural and engineered barriers for radioactive waste confinement. Lille, France, p 103
Chakraborty S, Bovin F, Bannerjee D, Scheinost A, Mullet M, Ehrardt JJ, Brendle J, Vidal L, Charlet L (2010) Uranium(VI) sorption and reduction by Fe(II) sorbed on montmorillonite. Environ Sci Technol 44:3779–3785
Chikkamath S, Patel MA, Kar AS, Raut V, Tomar BS, Manjanna J (2018) Sorption of Eu(III) on Fe–montmorillonite relevant to geological disposal of HLW. Radiochim Acta 106:971–983
Chikkamath S, Patel MA, Kar AS, Raut V, Tomar BS, Manjanna J (2019) Sorption and Diffusion of Cs(I) on Fe(III)–montmorillonite. Radiochim Acta 107:387–396
Chikkamath S, Patel MA, Kar AS, Raut V, Tomar BS, Manjanna J (2020) Sorption behavior of 137Cs on Fe(II)–montmorillonite and comparison with Fe(III)- and Na–Mt by modeling. Radiochim Acta (Under Review)
Eartan HH, Ksoyoglis S, Gokturk H (1998) Sorption/desorption of Cs on clay and soil fractions from various regions of Turkey. Sci Total Environ 69:229–296
Erten HN, Aksoyoglu S, Hatipoglu S, Gokturk H (1988) Sorption of Cesium and Strontium on Montmorillonite and Kaolinite. Radiochim. Acta 44(45):147–151
Eylem C, Erten HN, Goturk H (1990) Sorption–desorption behavior of Barium on clays. J Environ Radioact 11:183–200
Galambos M, Rosskopfova O, Kufcakova J, Rajec P (2011) Utilization of Slovak bentonites in deposition of high-level radioactive waste and spent nuclear fuel. J Radioanal Nucl Chem 288(3):765–777
Galambos M, Osacky M, Rosskopfova O, Krajvak A, Rajec P (2012a) Comparative study of strontium adsorption on dioctahedral and trioctahedral smectites. J Radioanal Nucl Chem 293(3):889–897
Galambos M, Suchanek P, Rosskopfova O (2012b) Sorption of anthropogenic radionuclides on natural and synthetic inorganic sorbents. J Radioanal Nucl Chem 293(2):613–633
Gaustafsson JP (2012) Visual Minteq Ver 3.1., KTH, Seed, Stockholm, Sweden
Grutter A, Von Gunten HR, Rossler E, Keil R (1992) Sorption of barium on unconsolidated glaciofluvial deposits and clay minerals. Radiochim Acta 58(59):259–265
Guillaume D, Neaman A, Cathelineau M, Mosser-Ruck R, Pfeiffert C, Abdeloula M, Dubessy J, Villeras F, Baronnet A, Michau N (2003) Experimental synthesis of chlorite from smectite at 300 °C in the presence of metallic Fe. Clay Miner 38:281–302
Guillaume D, Neaman A, Cathelineau M, Mosser-Ruck R, Pfeiffert C, Abdelmoula M, Dubessy J, Villieras F, Michau N (2004) Experimental study of the transformation of smectite at 80 and 300 °C in the presence of Fe oxides. Clay Miner 39:17–34
Hatipoglu S, Eylem C, Goktork H, Erten HN (1989) Sorption of strontium and barium on clays and soil fractions. In: Proceedings of the 9th international clay conference, Strasbourg, Vol II: surface chemistry. structure and mixed layering of clays. Strasbourg: Institut de Geologie—Universite Louis-Pasteur (1990) pp 79–86. (Sciences Geologiques. Memoire, 86)
Helm L, Merbach AE (1999) Water exchange on metal ions: experiments and simulations. Coord Chem Rev 187:151–181
Herbelin A, Westall J (1994) FITEQL—a computer program for determination of chemical equilibrium constants from experimental data. Oregon State University, Corvallis
Idemitsu K, Yano S, Xia X, Kikuchi Y, Inagaki Y, Arima T (2003) Migration behaviour of iron in compacted bentonite under reducing condition using electromigration. Mater Res Soc Symp Proc 757:II3.7.1–II3.7.8
Jaisi DP, Liu C, Dong H, Blake RE, Fein JB (2008) Fe2+ sorption onto nontronite (NAu-2). Geochim Cosmochim Acta 72:5361–5371
Japan Nuclear Cycle Development Institute 2000 H12: Project to establish the scientific and technical basis for HLW disposal in Japan: Project overview report, supporting report 1, 2 and 3, JNC TN1410 2000–2001, 2000–2002, 2000–2003, 2000–2004
Kamei G, Oda C, Mitsui S, Shibata M, Shinozaki T (1999) Fe(II)-Na ion exchange at interlayers of smectite: adsorption-desorption experiments and a natural analogue. Eng Geol 54:15–20
Khan SA, Rehman R, Khan MA (1995) Sorption of strontium on bentonite. Waste Manag 15(8):641–650
Kozai N, Ohnuki T, Matsumoto J, Banba T, Ito Y (1996) A study of specific sorption of Neptunium(V) on smectite in low pH solution. Radiochim Acta 75:149–158
Kozai N, Adachi Y, Kawamura S, Inda K, Kozaki T, Sato S, Ohashi T, Banba T (2001) Characterization of Fe–montmorillonite: a simulant of buffer materials accommodating overpack corrosion product. J Nucl Sci Technol 38(12):1141–1143
Lambe TW, Whitman RV (1969) Soil mechanics. Wiley, New York
Lee J, Park S, Jeon E, Baek K (2017) Selective and irreversible adsorption mechanism of cesium on illite. Appl Geochem 85:188–193
Low PF (1992) Inter particle forces in clay suspensions: flocculation, viscous flow, and swelling. In: CMS workshop lectures, vol. 4: clay–water interface and its rheological implications, pp 158–190
Lu S, Tan X, Yu S, Ren X, Chen C (2016) Characterization of Fe(III)-saturated montmorillonite and evaluation its sorption behavior for U(VI). Radiochim Acta 104:481–490
Manjanna J (2008) Preparation of Fe(II)–montmorillonite by reduction of Fe(III)–montmorillonite with ascorbic acid. Appl Clay Sci 42:32–38
Manjanna J, Kozaki T, Sato S (2009) Fe(III)–montmorillonite: basic properties and diffusion of tracers relevant to alteration of bentonite in deep geological disposal. Appl Clay Sci 43:208–217
Marcus Y (1994) A simple empirical model describing the thermodynamics of hydration of ions of widely varying charges, sizes, and shapes. Biophys Chem 51:111–127
Martell AL, Smith RM (2003) NIST standard reference database, 46.7, NIST Critically selected constants of metal complexes. National Institutes of Standards & Technology Gaithersburg, MD, USA
Mishra SP, Tiwary D (1999) Ion exchangers in radioactive waste management. Part XI. Removal of barium and strontium ions from aqueous solutions by hydrous ferric oxide. Appl Radiat Isot 51:359–366
Missana T, Garcia-Gutierrez M, Alonso U (2008) Sorption of strontium onto illite/smectite mixed clays. Phys Chem Earth 33:S156–S162
Mosser-Ruck R, Cathelineau M, Guillaume D, Charpentier D, Rousset D, Barres O, Michau N (2010) Effects of temperature, ph, and iron/clay and liquid/clay ratios on experimental conversion of dioctahedral smectite to berthierine, chlorite, vermiculite, or saponite. Clays Clay Miner 58(2):280–291
Nightingale ER (1959) Phenomenological theory of ion solvation. Effective radii of hydrated ions. J Phys Chem 63(9):1381–1387
ONDRAF/NIRAS (2013) Research, development and demonstration (RD & D) plan for the geological disposal of high-level and/or long-lived radioactive waste including irradiated fuel if considered as waste. State-of-the-art report as of December 2012. ONDRAF/NIRAS, report NIROND-TR 2013-12 E
Palascak MW, Shields GC (2004) Accurate experimental values for the free energies of hydration of H+, OH−, and H3O+. J Phys Chem A 108:3692–3694
Patel MA, Kar AS, Garg D, Kumar S, Tomar BS, Bajpai RK (2017) Sorption studies of radionuclides on argillaceous clays of Cuddapah system. J Radioanal Nucl Chem 313(3):1–9
Sajih M, Bryan ND, Livens FR, Vaughan DJ, Descostes MV, Phrommavanh J, Morris NK (2014) Adsorption of radium and barium on goethite and ferrihydrite: a kinetic and surface complexation modelling study. Geochim Cosmochim Acta 146:150–163
Schulz RK (1965) Soil chemistry of radionuclides. Health Phys 11:1317–1324
Schwertmann U (1991) Solubility and dissolution of iron oxides. Plant Soil 130:1–25
Sidhu PS, Gilkes RJ, Cornell RM, Posner AM, Quirk JP (1981) Dissolution of iron oxides and oxyhydroxides in hydrochloric and perchloric acids. Clays Clay Miner 29:269–276
Siroux B, Beaucaire C, Tabarant M, Benedetti MF, Reiller PE (2017) Adsorption of strontium and caesium onto an Na–MX80 bentonite: experiments and building of a coherent thermodynamic modelling. Appl Geochem 87:167–175
Soderlund M, Ervanne H, Muuri E, Lehto J (2019) The sorption of alkaline earth metals on biotite. Geochem J 53:223–234
Soltermann D, Marques Fernandes M, Baeyens B, Daahn R, Miehee-Brendlee J, Wehrli B, Bradbury MH (2013) Fe(II) sorption on a synthetic montmorillonite. A combined macroscopic and spectroscopic study. Environ Sci Technol 47:6978–6986
Vinoda BM, Manjanna J (2014) Dissolution of iron in salicylic acid and cation exchange between Fe(II)–salicylate and Na–montmorillonite to form Fe(II)–montmorillonite. Appl Clay Sci 97–98:78–83
Wersin P, Kiczka M, Rosch D (2014) Safety case for the disposal of spent nuclear fuel at Olkiluoto, radionuclide solubility limits and migration parameters for the canister and the buffer. Posiva Report 2012-39. Posivaoy, Eurajoki, Finland
Wilson J, Cressey G, Cressey B, Cuadros J, Ragnarsdottir KV, Savage D, Shibata M (2006a) The effect of iron on montmorillonite stability. (I) Experimental investigations. Geochim Cosmochim Acta 70:323–336
Wilson J, Savage D, Cuadros J, Shibata M, Ragnarsdottir KV (2006b) The effect of iron on bentonite stability: (I) background and thermodynamic considerations. Geochim Cosmochim Acta 70:306–322
Yu S, Mei H, Chen X, Tan X, Ahmad B, Alsaedi A, Hayat T, Wang X (2015) Impact of environmental conditions on the sorption behavior of radionuclide 90Sr(II) on Na–montmorillonite. J Mol Liq 203:39–46
Zhong C, Deng Y, Hu W, Qiao J, Zhang L, Zhang J (2015) A review of electrolyte materials and compositions for electrochemical super capacitors. Chem Soc Rev 44:7484–7539
Acknowledgements
Authors greatly acknowledge the financial support from Board of Research in Nuclear Sciences/Department of Atomic Energy (BRNS/DAE) [No. 37 (2)/14/20/2015/BRNS, Dt: 27/07/2015] and Department Of Science and Technology—Fund for Improvement of S&T Infrastructure in Higher Educational Institutions (DST-FIST), Ministry of Science and Technology [No. SR/FST/CSI-273/2016], Govt. of India. Dr. B.S. Tomar acknowledges the support from Department of Atomic Energy toward Raja Ramanna Fellowship.
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Chikkamath, S., Patel, M.A., Kar, A.S. et al. Experimental and Modeling Studies on Sorption Behaviour of 133Ba(II) on Fe–Montmorillonite Clay Minerals. Aquat Geochem 27, 31–47 (2021). https://doi.org/10.1007/s10498-020-09389-5
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DOI: https://doi.org/10.1007/s10498-020-09389-5