Skip to main content
SpringerLink
Log in

Synthesis and Electrochemical Properties of 2,5-Disubstituted Derivatives of 1,4-Bis(4,5-diphenylidimidazol-2-yl)benzene

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The data on the synthesis and electrochemical properties of 2,5-disubstituted derivatives of 1,4-bis(4,5-diphenyldimidazol-2-yl)benzene are reported. The effect of substituents on redox properties has been comprehensively investigated. The electrochemical reduction of quinones into the biradical occurs at positive potentials and is a result of two stages of single-electron transfer, through the stage of the monoradical formation. The correlation between the reduction potentials and the salts structure has been found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme
Scheme
Fig. 1.
Scheme
Scheme
Fig. 2.
Fig. 3.
Scheme

Similar content being viewed by others

REFERENCES

  1. Lu, N.-N., Yoo, S.J., Li, L.-J., Zeng, C.-C., and Little, R.D., Electrochim. Acta, 2014, vol. 142, p. 254. https://doi.org/10.1016/j.electacta.2014.07.105

    Article  CAS  Google Scholar 

  2. Francke, R. and Little, R.D., J. Am. Chem. Soc., 2014, vol. 136, p. 427. https://doi.org/10.1021/ja410865z

    Article  CAS  PubMed  Google Scholar 

  3. Zeng, C.-C., Zhang, N.-T., Lam, C.M., and Little, R.D., Org. Lett., 2012, vol. 14, p. 1314. https://doi.org/10.1021/ol300195c

    Article  CAS  PubMed  Google Scholar 

  4. Englander, F., US Patent 4465865, 1984.

  5. Naylor, J.R., J. Chem. Soc., 1952, p. 4078. https://doi.org/10.1039/JR9520004839

  6. Bard, A.J. and Faulkner, L.R. Electrochemical Methods: Fundamentals and Applications, New York: John Wiley, 2001.

  7. Xia, C. and Advincula, R.C., Macromol., 2001, vol. 34, p. 6922. https://doi.org/10.1021/ma0100192

    Article  CAS  Google Scholar 

  8. Maeda, K., Sakaino, Y., and Hayashi, T., Nippon Kagaku Kaishi, 1972, p. 100. https://doi.org/10.1246/nikkashi.1972.100

  9. Sakaino, Y., Kakisawa, H., Kusumi, T., and Maeda, K., J. Org. Chem., 1979, vol. 44, p. 1241. https://doi.org/10.1021/jo01322a010

    Article  CAS  Google Scholar 

Download references

Funding

This study was financially supported by the Ministry of Science and Higher Education of the Russian Federation as a part of the government task in the field of research (project no. 4.4566.2017/8.9).

Author information

Authors and Affiliations

  1. N.P. Ogarev Mordovian National Research University, 430005, Saransk, Russia

    A. V. Dolganov, O. Yu. Gants, S. G. Kostryukov, A. V. Balandina, M. K. Pryanichnikova, A. Sh. Kozlov, Yu. I. Lyukshin, A. A. Akhmatova, V. O. Zhirnova, A. D. Yudina & A. S. Timonina

Authors
  1. A. V. Dolganov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. Yu. Gants
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. G. Kostryukov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Balandina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. K. Pryanichnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. Sh. Kozlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yu. I. Lyukshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. A. Akhmatova
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. V. O. Zhirnova
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. A. D. Yudina
    View author publications

    You can also search for this author in PubMed Google Scholar

  11. A. S. Timonina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Dolganov.

Ethics declarations

No conflict of interest was declared by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dolganov, A.V., Gants, O.Y., Kostryukov, S.G. et al. Synthesis and Electrochemical Properties of 2,5-Disubstituted Derivatives of 1,4-Bis(4,5-diphenylidimidazol-2-yl)benzene. Russ J Gen Chem 90, 961–967 (2020). https://doi.org/10.1134/S1070363220060055

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363220060055

Keywords:

Search

Navigation