Abstract
A new extractant, {[2-(2-diphenylphosphoryl)-4-ethylphenoxy]ethyl}diphenylphosphine oxide, has been synthesized, and its solutions in 1,2-dichloroethane and a ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, have been used to extract HNO3, uranium(VI), thorium(IV), and trivalent rare earths from nitric acid solutions. The stoichiometry of the extracted complexes has been determined, and the effects of the extractant structure and HNO3 concentration in the aqueous phase on the extraction efficiency have been studied. The extraction efficiency has been found to significantly increase when ionic liquid is present in the organic phase.
Similar content being viewed by others
REFERENCES
Myasoedov, B.F., Kalmykov, S.N., Kulyako, Yu.M., and Vinokurov, S.E., Geochem. Int., 2016, vol. 54, no. 13, p. 1156. https://doi.org/10.1134/S0016702916130115
Alyapychev, M.Yu., Babain, V.A., and Ustynyuk, Yu.A., Russ. Chem. Rev., 2016, vol. 85, no. 9, p. 943. https://doi.org/10.1070/RCR4588
Leoncini, A., Huskens, J., and Verboom, W., Chem. Soc. Rev., 2017, vol. 46, p. 7229. https://doi.org/10.1039/C7CS00574A
Rozen, A.M., Nikolotova, Z.I., and Kartasheva, N.A., Radiokhimiya, 1986, vol. 28, no. 3, p. 407.
Chmutova, M.K., Litvina, M.N., Pribylova, G.A. Ivanova, L.A., Smirnov, I.V., Shadrin, A.Yu., and Myasoedov, B.F., Radiokhimiya, 1999, vol. 41, no. 4, p. 331.
Narita, H., Yaita, T., Tamura, K., and Tachimori, S., Radiochim. Acta, 1998, vol. 81, p. 223. https://doi.org/10.1524/ract.1998.81.4.223
Sasaki, Y., Sugo, Y., Suzuki, S., and Tachimori, S., Solvent Extr. Ion Exch., 2001, vol. 19, p. 91. https://doi.org/10.1081/SEI-100001376
Zhui, Z.-X, Sasaki, Y., Suzuki, S., and Kimura, T., Anal. Chim. Acta, 2004, vol. 527, p. 163. https://doi.org/10.1016/j.aca.2004.09.023
Sasaki, Y., Sugo, Y., Morita, K., and Nash, K.L., Solvent Extr. Ion Exch., 2015, vol. 33, p. 625. https://doi.org/10.1080/07366299.2015.1087209
Campbell, E., Holfeltz, V.E., Hall, G.B., Nash, K.L., Lumetta, G.J., and Levitskaia, T.G., Solvent Extr. Ion Exch., 2018, vol. 36, p. 331. https://doi.org/10.1080/07366299.2018.1447261
Ansari, S.A., Mohapatra, P.K., Leoncini, A., Ali, S.M., Singhadeb, A., Huskens, J., and Verboom, W., Dalton Trans., 2017, vol. 46, p. 11355. https://doi.org/10.1039/C7DT03831C
Turanov, A.N., Karandashev, V.K., Evseeva, N.K., Baulin, V.E., and Ushakova, A.P., Radiokhimiya, 1999, vol. 41, no. 3, p. 219.
Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Solvent Extr. Ion Exch., 1999, vol. 17, p. 1423. https://doi.org/10.1080/07366299908934656
Turanov, A.N., Karandashev, V.K., Baulin, V.E., Yarkevich, A.N., and Safronova, Z.V., Solvent Extr. Ion Exch., 2009, vol. 27, p. 551. https://doi.org/10.1080/07366290903044683
Rozen, A.M., Nikolotova, Z.I., Kartasheva, N.A., and Yudina, K.S., Dokl. Akad. Nauk SSSR, 1975, vol. 222, no. 5, p. 1151.
Rozen, A.M. and Krupnov, B.V., Russ. Chem. Rev., 1996, vol. 65, no. 11. p. 973. https://doi.org/10.1070/RC1996v065n11ABEH000241
Kabachnik, M.I., Myasoedov, B.F., Mastryukova, T.A., Polikarpov, Yu.M., Chmutova, M.K., and Nesterova, N.P., Russ. Chem. Bull., 1996, vol. 45, no. 11, p. 2484. https://doi.org/10.1007/BF01431100
Tsvetkov, E.N., Evreinov, V.I., Bondarenko, N.A., and Safronova, Z.V., Russ. J. Gen. Chem., 1996, vol. 66, no. 7, p. 1054.
Demin, S.V., Zhilov, V.I., Nefedov, S.E. Baulin, V.E., and Tsivadze, A.Yu., Russ. J. Inorg. Chem., 2012, vol. 57, no. 6, p. 897. https://doi.org/10.1134/S0036023612060095
Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Radiokhimiya, 1998, vol. 40, no. 1, p. 36.
Koel, M., Crit. Rev. Anal. Chem., 2005, vol. 35, p. 177. https://doi.org/10.1080/10408340500304016
Kolarik, Z., Solvent Extr. Ion Exch., 2013, vol. 31, p. 24. https://doi.org/10.1080/07366299.2012.700589
Billard, I., Handbook on the Physics and Chemistry of Rare Earths, Bünzli, J.-C.G. and Pecharsky, V.K., Eds., 2013, vol. 43, chap. 256, p. 213. https://doi.org/10.1016/B978-0-444-59536-2.00003-9
Mohapatra, P.K., Chem. Prod. Process Model., 2015, vol. 10, p. 135.
Nakashima, K., Kubota, F., Maruyama, T., and Goto, M., Anal. Sci., 2003, vol. 19, p. 1097. https://doi.org/10.2116/analsci.19.1097
Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Russ. J. Inorg. Chem., 2008, vol. 53, no. 6, p. 970. https://doi.org/10.1134/S0036023608060272
Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Radiochemistry, 2008, vol. 50, no. 3, p. 266. https://doi.org/10.1134/S1066362208030090
Shimojo, K., Kurahashi, K., and Naganava, H., Dalton Trans., 2008, vol. 37, p. 5083. https://doi.org/10.1039/B810277P
Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Solvent Extr. Ion Exch., 2008, vol. 26, p. 77. https://doi.org/10.1080/07366290801904871
Panja, S., Mohapatra, P.K., Tripathi, S.C., Gandhi, P.M., and Janardan, P., Sep. Purif. Technol., 2012, vol. 96, p. 289. https://doi.org/10.1016/j.seppur.2012.06.015
Turanov, A.N., Karandashev, V.K., Baulin, D.V., Baulin, V.E., and Tsivadze, A.Yu., Russ. J. Inorg. Chem., 2019, vol. 64, no. 3, p. 407. https://doi.org/10.1134/S0036023619030203
Rozen, A.M., Berkman, Z.A., Bertina, L.E., Denisov, D.A., Zarubin, A.I., Kossykh, V.G., Nikolotova, Z.I., Pisareva, S.A., and Yudina, K.S., Radiokhimiya, 1976, vol. 18, no. 4, p. 493.
Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Radiochemistry, 2001, vol. 43, no. 1, p. 72. https://doi.org/10.1023/A:1012830323836
Yatsimirskii, K.B., Kostromina, N.A., Sheka, Z.A., Davidenko, K., Kriss, E.E., and Ermolenko, V.I., Khimiya kompleksnykh soedinenii redkozemel’nykh metallov (Chemistry of Coordination Compounds of Rare Earths), Kiev: Naukova Dumka, 1966.
Vlasov, V.S. and Rozen, A.M., Radiokhimiya, 1988, vol. 30, no. 1, p. 146.
Turanov, A.N., Karandashev, V.K., and Yarkevich, A.N., Radiochemistry, 2018, vol. 60, no. 2, p. 170. https://doi.org/10.1134/S1066362218020078
Gaillard, C., Boltoeva, M., Billard, I. Georg, S., Mazan, V., Ouadi, A., Ternova, D., and Hennig, C., ChemPhysChem, 2015, vol. 16, p. 2653. https://doi.org/10.1002/cphc.201500283
Binnemans, K., Chem. Rev., 2007, vol. 107, p. 2593. https://doi.org/10.1021/cr050979c
Shuvaev, S., Kotova, O., Utochnikova, V., Vaschenko, A., Puntus, L., Baulin, V., Kuzmina, N., and Tzivadze, A., Inorg. Chem. Commun., 2012, vol. 20, p. 73. https://doi.org/10.1016/j.inoche.2012.02.020
Bonhote, P., Dias, A.P., Papageorgiou, N., Kalyanasundaram, K., and Grätzel, M., Inorg. Chem., 1996, vol. 35, p. 1168. https://doi.org/10.1021/ic951325x
ACKNOWLEDGMENTS
The authors thank Sorbent-Tekhnologii Ltd. for providing a sample of 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide.
Funding
This study was performed in the framework of state tasks to the Institute of Solid State Physics, Institute of Problems of Microelectronics Technology and High-Purity Materials, Frumkin Institute of Physical Chemistry and Electrochemistry, and Institute of Physiologically Active Substances (Russian Academy of Sciences) under partial financial support by the Russian Foundation for Basic Research (project no. 18-29-24069_mk).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
No conflict of interest was declared by the authors.
Rights and permissions
About this article
Cite this article
Turanov, A.N., Karandashev, V.K., Baulin, D.V. et al. Extraction of Uranium(VI), Thorium(IV), and Trivalent Rare Earths from Nitric Acid Solutions with {[2-(2-Diphenylphosphoryl)-4-ethylphenoxy]ethyl}diphenylphosphine Oxide. Russ J Gen Chem 90, 1012–1019 (2020). https://doi.org/10.1134/S1070363220060122
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363220060122