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Synthesis, Characterization, and Properties of Highly Hydrophilic Polyaniline Sulfonic Acid

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Abstract

A hollow spherical highly hydrophilic polyaniline sulfonic acid catalyst has been successfully prepared by emulsion polymerization and SO3 liquid sulfonation using modified polystyrene microspheres (PS) as a template. Acid value of the solid acid catalyst is 2.516 mmol/g. Morphology, structure and thermal stability of the catalyst have been studied by XRD, SEM, TEM, FT-IR, X-ray photoelectron spectroscopy (XPS), and TGA. It has been proven that doping and sulfonation of PANI and SO3 lead to new molecule that retains the PANI matrix material. In view of close structure-activity relationship, it has been applied to the efficient synthesis of bis(indolyl)methanes (BIMs) in water-ethanol phase.

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Funding

This work was financially supported by the Major Innovation Projects for Building First-class Universities in China’s Western Region (no. ZKZD 2017003), the National First-rate Discipline Construction Project of Ningxia (no. NXYLXK2017A04) and the National Natural Science Foundation of China (no. 21862013).

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Authors and Affiliations

  1. State Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, 750021, Yinchuan, China

    Zhiqiang Wu, Gang Wang, Shuo Yuan, Haijuan Zhan, Wanyi Liu, Shuxian Bi, Heping Li, Baojun Ma & Yanyan Sun

Authors
  1. Zhiqiang Wu
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  2. Gang Wang
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  3. Shuo Yuan
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  4. Haijuan Zhan
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Correspondence to Wanyi Liu.

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Wu, Z., Wang, G., Yuan, S. et al. Synthesis, Characterization, and Properties of Highly Hydrophilic Polyaniline Sulfonic Acid. Russ J Gen Chem 90, 1055–1061 (2020). https://doi.org/10.1134/S1070363220060195

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  • DOI: https://doi.org/10.1134/S1070363220060195

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