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Synthesis, Structure, and Properties of Co2+ and Ni2+ Complexes with the Product of Condensation of 2-(7-Bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)acetohydrazide and 1H-Indole-2,3-dione

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Abstract

[Co(HydrHIz)] and [Ni(HydrHIz)]∙2H2O (М = Co, Ni) complexes have been obtained via the reaction of M(CH3COO)2 with 2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)acetohydrazide (Hydr) and 1H-indole-2,3-dione (НIz). Structure and composition of the complexes have been confirmed by elemental analysis, thermogravimetry, IR spectroscopy, and mass spectrometry data. The electrical conductivity and magnetic susceptibility of the complexes have been determined. The local atomic structure of coordination centers has been established by X-ray absorption spectroscopy.

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Funding

X-ray spectral studies were financially supported by Southern Federal University (internal research grant of SFU, project no. VnGr/2020-01-IF).

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Authors and Affiliations

  1. I.I. Mechnikov Odessa National University, 65082, Odessa, Ukraine

    I. I. Seifullina, L. S. Skorokhod & A. V. Pulya

  2. Research Institute of Physics, Southern Federal University, 344090, Rostov-on-Don, Russia

    V. G. Vlasenko

  3. National Research Center “Kurchatov Institute”, 123182, Moscow, Russia

    A. L. Trigub

  4. Odessa National Polytechnic University, 65044, Odessa, Ukraine

    I. M. Rakipow

Authors
  1. I. I. Seifullina
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  2. L. S. Skorokhod
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  3. A. V. Pulya
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  4. V. G. Vlasenko
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  5. A. L. Trigub
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  6. I. M. Rakipow
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Corresponding author

Correspondence to L. S. Skorokhod.

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Seifullina, I.I., Skorokhod, L.S., Pulya, A.V. et al. Synthesis, Structure, and Properties of Co2+ and Ni2+ Complexes with the Product of Condensation of 2-(7-Bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)acetohydrazide and 1H-Indole-2,3-dione. Russ J Gen Chem 90, 1298–1303 (2020). https://doi.org/10.1134/S1070363220070166

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