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New Cr, Mo, W, and Fe Metal Complexes with Potentially Heptadentate (S3N4) Tripodal Schiff Base Ligand: Synthesis, Characterization, and Antibacterial Activity

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Abstract

Reactions of Cr, Mo, W, and Fe metal carbonyls with potentially heptadentate (S3N4) tripodal Schiff base ligand, (thio)3tren, have been studied. The Schiff base (thio)3tren has been prepared by condensation of thiophene-2-carboxaldehyde with tris(2-aminoethyl)amine. The Schiff base and its metal complexes have been characterized by IR, UV-Vis, 1H and 13C NMR spectra, TGA, and elemental analysis. According to the spectroscopic data, (thio)3tren is coordinated to the metal centers as a potentially heptadentate ligand. The products have been tested in vitro against the bacterial species, Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, and Bacillus cereus by the disc diffusion and micro-broth dilution methods, and characterized by antibacterial activity higher than that of the ligand. The lowest MIC was determined for Fe complex against Bacillus cereus and the highest for Mo complex against Escherichia coli.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Faculty of Chemistry, Tehran North Branch, Islamic Azad University, 1651153311, Tehran, Iran

    F. Dashti Rahmatabadi, R. Ranjineh Khojasteh, H. Kabiri Fard & F. Tadayon

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  1. F. Dashti Rahmatabadi
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  2. R. Ranjineh Khojasteh
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Correspondence to R. Ranjineh Khojasteh.

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Rahmatabadi, F.D., Khojasteh, R.R., Fard, H.K. et al. New Cr, Mo, W, and Fe Metal Complexes with Potentially Heptadentate (S3N4) Tripodal Schiff Base Ligand: Synthesis, Characterization, and Antibacterial Activity. Russ J Gen Chem 90, 1317–1321 (2020). https://doi.org/10.1134/S1070363220070191

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