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Lanthanide Coordination Polymers Based on Dicyanamide Ligand

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Abstract

The use of dicyanamide and chelating phenanthroline ligands resulted in the synthesis of organometallic europium and neodymium coordination polymers [Ln(Phen)2{N(CN)2}3–xClx(CH3OH)](CH3OH)y]∞ (Ln = Eu (I), Nd (II)) in which the dicyanamide ligand forms 1D chains, while the phenanthroline ligand provides packing of the 1D polymer in the crystal lattice. Under similar conditions, the binuclear complex [Gd(Phen)2(μ-OH){N(CN)2}(H2O)]2Cl2 (III) was obtained for gadolinium, with the dicyanamide ligands being coordinated to only one gadolinium ion without forming a polymer chain (CCDC CIF files nos. 1936378 (I), 1936379 (II), 1936377 (III)).

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Funding

This work was supported by the Russian Foundation for Basic Research (project no. 18-29-04029).

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    D. M. Roitershtein

  2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

    D. M. Roitershtein

  3. Kotel’nikov Institute of Radio Engineering and Electronics, Russian Academy of Sciences, Moscow, Russia

    L. N. Puntus

  4. Lebedev Physical Institute, Russian Academy of Sciences, Moscow, Russia

    E. A. Varaksina & I. V. Taidakov

  5. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    I. V. Taidakov & K. A. Lysenko

  6. Moscow State University, Moscow, Russia

    K. A. Lysenko

Authors
  1. D. M. Roitershtein
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  2. L. N. Puntus
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  3. E. A. Varaksina
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  4. I. V. Taidakov
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  5. K. A. Lysenko
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Corresponding authors

Correspondence to D. M. Roitershtein or K. A. Lysenko.

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The authors declare that they have no conflicts of interest.

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Translated by Z. Svitanko

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Roitershtein, D.M., Puntus, L.N., Varaksina, E.A. et al. Lanthanide Coordination Polymers Based on Dicyanamide Ligand. Russ J Coord Chem 46, 15–22 (2020). https://doi.org/10.1134/S1070328420010066

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  • DOI: https://doi.org/10.1134/S1070328420010066

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