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Two-Dimensional Coordination Polymer {[Bi(Рyz)I3]}: Structure and Analysis of the Packing Using the Hirshfeld Surface Method

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Abstract

The reaction of BiI3 with pyrazine in tetrahydrofuran affords the two-dimensional coordination polymer {[Bi(Pyz)I3]} (I), whose structure is determined by X-ray diffraction analysis (СIF file ССDС no. 1904990). The contributions of various interatomic contacts to the crystal packing of compound I are studied using the Hirshfeld surface analysis performed for the elementary unit of compound I. The interatomic distances I···H make the largest contribution to the crystal packing of compound I.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. N. Usoltsev, S. A. Adonin, M. N. Sokolov & V. P. Fedin

  2. Tyumen Industrial University, Tobolsk Industrial Institute, Tobolsk, Russia

    S. A. Adonin

  3. Novosibirsk National Research University, 630090, Novosibirsk, Russia

    S. A. Adonin, M. N. Sokolov & V. P. Fedin

  4. Southern Ural State University, Chelyabinsk, Russia

    S. A. Adonin

  5. St. Petersburg State University, 199164, St. Petersburg, Russia

    A. S. Novikov

  6. Butlerov Institute of Chemistry, Kazan (Volga region) Federal University, Kazan, Russia

    M. N. Sokolov

Authors
  1. A. N. Usoltsev
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  2. S. A. Adonin
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  3. A. S. Novikov
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  4. M. N. Sokolov
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  5. V. P. Fedin
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Corresponding author

Correspondence to S. A. Adonin.

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Translated by E. Yablonskaya

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Usoltsev, A.N., Adonin, S.A., Novikov, A.S. et al. Two-Dimensional Coordination Polymer {[Bi(Рyz)I3]}: Structure and Analysis of the Packing Using the Hirshfeld Surface Method. Russ J Coord Chem 46, 23–27 (2020). https://doi.org/10.1134/S107032842001008X

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  • DOI: https://doi.org/10.1134/S107032842001008X

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