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1,3-Di(4-Pyridyl)Triazene: A New Ligand for the Synthesis of Coordination Polymers

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Abstract

4,4′-(Triaz-1-ene-1,3-diyl)dipyridine (L) and the first transition metal complex with it are synthesized. It is found that the solid phase of isolated solvate [Cu(hfac)2L]·0.5MePh, where hfac is hexafluoroacetylacetonate, consists of polymer chains inside which L acts as a bridge, linking together Cu(hfac)2 moieties by N atoms of pyridine rings. The chains, in turn, are arranged into layers by H bonds. The result shows that L can be a bridging ligand in the synthesis of new coordination polymers.

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Acknowledgments

G.V. Romamenko is grateful to RFBR for supporting the structural research (grant 18-29-04002); S.E. Tolstikov is grateful to the Siberian Branch of the Russian Academy of Sciences for providing physicochemical measurements (grant II.1.60.3).

Funding

The study was supported by the Russian Science Foundation (18-13-00380).

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Correspondence to G. V. Romanenko.

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The authors declare that they have no conflict of interests.

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Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 5, pp. 748–752.

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Romanenko, G.V., Tolstikov, S.E., Fursova, E.Y. et al. 1,3-Di(4-Pyridyl)Triazene: A New Ligand for the Synthesis of Coordination Polymers. J Struct Chem 61, 707–711 (2020). https://doi.org/10.1134/S0022476620050054

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  • DOI: https://doi.org/10.1134/S0022476620050054

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