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Secondary Coordination in the Structures of Zinc(II) and Manganese(II) Oxalatopalladates(II)

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Abstract

New coordination compounds, namely, zinc(II) dioxalatopalladate tetrahydrate [{Zn(H2O)3(Pd(C2O4)2)}2(μ-H2O)2]·4H2O and manganese(II) dioxalatopalladate monohydrate {(μ-C2O4)Pd(μ-C2O4)Mn(H2O)3}n·μH2O are synthesized. The compounds are characterized by IR spectroscopy, elemental analysis, and single crystal X-ray diffraction. The crystallographic data for the complex with Zn are as follows: a = 7.2812(4) Å, b = 9.0258(5) Å, c = 10.2468(6) Å, a = 81.0335(1)°, β = 80.5341(2)°, γ = 75.9627(1)°, space group \(\overline 1 \), Z = 2, ρcafc = 2.367 g/cm3. The crystallographic data for the complex with Mn are as follows: a = 6.3605(4) Å, b = 8.8464(5) Å, c = 18.7382(1) Å, β = 98.398(2)°, space group P21/c, Z = 2, ρcalc = 2.607 g/cm3. The complexes crystallize in different structural motifs: an oligomer in the case of Zn and a chain in the case of Mn. In both structures, oxalatopalladate(II) is coordinated by terminal oxygen atoms to the base metal.

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Acknowledgments

The authors are grateful to N.I. Alferova for recording IR spectra and to A.P. Zubereva for carrying out the elemental analysis.

Funding

The work was supported by RFBR (No. 17-03-00693a).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    I. A. Garkul, A. V. Zadesenets, I. V. Korolkov, I. A. Baidina & S. V. Korenev

  2. Novosibirsk State University, Novosibirsk, Russia

    I. A. Garkul, A. V. Zadesenets, I. V. Korolkov & S. V. Korenev

Authors
  1. I. A. Garkul
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  2. A. V. Zadesenets
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  3. I. V. Korolkov
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  4. I. A. Baidina
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  5. S. V. Korenev
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Correspondence to I. A. Garkul.

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Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 5, pp. 760–767.

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Garkul, I.A., Zadesenets, A.V., Korolkov, I.V. et al. Secondary Coordination in the Structures of Zinc(II) and Manganese(II) Oxalatopalladates(II). J Struct Chem 61, 719–726 (2020). https://doi.org/10.1134/S0022476620050078

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  • DOI: https://doi.org/10.1134/S0022476620050078

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