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Thiocyanate Coordination to the {Ta6I12}2+ Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6]

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Abstract

The reaction of Ta6I14 with KNCS in acetonitrile in the presence of 24-dibenzo-crown-8 leads to dissolution of the tantalum iodide cluster to form the [Ta6I12(NCS)6]4− complex. By evaporation of the solution with the subsequent treatment of the precipitate with acetone and PPh4Br, dark green single crystals of the composition [K(C24H32O8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6] CH3COCH3(1) are obtained with a yield of 29%. The product is characterized by elemental analysis, IR, and mass spectra. The crystal structure is determined by the X-ray diffraction analysis.

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Funding

The work was supported by RFBR (grant 17-03-00663).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. V. Shamshurin, T. S. Sukhikh, M. A. Mikhailov, D. G. Sheven & M. N. Sokolov

  2. Novosibirsk State University, Novosibirsk, Russia

    M. N. Sokolov

  3. Kazan (Privolzhsky) Federal University, Kazan, Republic of Tatarstan, Russia

    M. N. Sokolov

Authors
  1. M. V. Shamshurin
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  2. T. S. Sukhikh
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  3. M. A. Mikhailov
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  4. D. G. Sheven
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  5. M. N. Sokolov
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Correspondence to M. N. Sokolov.

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Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 5, pp. 768–775.

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Shamshurin, M.V., Sukhikh, T.S., Mikhailov, M.A. et al. Thiocyanate Coordination to the {Ta6I12}2+ Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6]. J Struct Chem 61, 727–733 (2020). https://doi.org/10.1134/S002247662005008X

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  • DOI: https://doi.org/10.1134/S002247662005008X

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